公开(公告)号：US20100160485A1

公开(公告)日：2010-06-24

申请号：US12583860

申请日：2009-08-27

申请人： Joachim Klee ,  Uwe Walz ,  Uwe Lehman

发明人： Joachim Klee ,  Uwe Walz ,  Uwe Lehman

IPC分类号： A61K6/00

CPC分类号： A61K6/0023 ,  C08L33/00

摘要： An aqueous one-pack self-etching and self-priming dental adhesive composition having a pH of at most 2, which comprises: (i) a polymerizable N-substituted alkylacrylic or acrylic acid amide monomer which optionally contains an inorganic acidic moiety selected from a phosphonic acid moiety or a sulfonic acid moiety, and (ii) a curing system.

摘要翻译： 一种pH值至多为2的含水单组份自蚀刻和自吸牙科粘合剂组合物，其包含：（i）可聚合的N-取代烷基丙烯酸或丙烯酸酰胺单体，其任选地含有选自以下的无机酸性部分： 膦酸部分或磺酸部分，和（ii）固化体系。

公开(公告)号：US20070293642A1

公开(公告)日：2007-12-20

申请号：US10596747

申请日：2004-12-15

申请人： Joachim Klee ,  Uwe Lehmann ,  Uwe Walz

发明人： Joachim Klee ,  Uwe Lehmann ,  Uwe Walz

IPC分类号： C07F9/09 ,  A61K6/00 ,  C08F30/02 ,  A61K6/083

CPC分类号： A61K6/0023 ,  C07F9/091 ,  C08L33/00 ,  C08L43/02

摘要： One-part self-etching, self-priming dental adhesive composition having a pH of at most 2, which comprises (a) a polymerizable acidic phosphoric acid ester monomer (b) one or more polymerizable acidic monomers (c) a polymerizable N-substituted alkylacrylic or acrylic acid amide monomer; (d) optionally an organic and/or inorganic acid; (e) an organic water soluble solvent and/or water; and (f) polymerization initiator, inhibitor and stabilizer.

摘要翻译： 一部分自蚀刻自粘牙科粘合剂组合物，其pH最多为2，其包含（a）可聚合酸性磷酸酯单体（b）一种或多种可聚合酸性单体（c）可聚合的N-取代的 烷基丙烯酸或丙烯酰胺单体; （d）任选的有机和/或无机酸; （e）有机水溶性溶剂和/或水; 和（f）聚合引发剂，抑制剂和稳定剂。

公开(公告)号：US20050043490A1

公开(公告)日：2005-02-24

申请号：US10938459

申请日：2004-09-10

申请人： Joachim Klee ,  Uwe Walz

发明人： Joachim Klee ,  Uwe Walz

IPC分类号： A61K6/00 ,  A61K6/083 ,  A61K6/087 ,  A61K6/09 ,  C08F283/02 ,  C08F290/06 ,  C08G18/83 ,  C08G59/10 ,  C08G59/12 ,  C08G59/14 ,  C08G59/17 ,  C08G59/42 ,  C08G63/02 ,  C08F267/04

CPC分类号： A61K6/0017 ,  A61K6/0032 ,  A61K6/083 ,  A61K6/087 ,  A61K6/09 ,  C08F283/02 ,  C08F290/06 ,  C08F290/061 ,  C08F290/064 ,  C08G18/835 ,  C08G59/10 ,  C08G59/12 ,  C08G59/1466 ,  C08G59/1494 ,  C08G59/4292 ,  C08G2270/00 ,  C08L63/00 ,  C08L33/00 ,  C08L75/16

摘要： An esterified macromonomer within the scope of the general formula: wherein Z is an organic moiety, R1 is hydrogen or a substituted or unsubstituted alkyl having from 1 to 12 carbon atoms, oxyalkyl having from 1 to 12 carbon atoms, alkenyl having from 2 to 12 carbon atoms, cycloalkyl having from 5 to 12 carbon atoms, aryl having from 6 to 12 carbon atoms or aralkyl having from 7 to 12 carbon atoms, each E independently is a hydroxyl group, an organic ester moiety or an inorganic ester containing moiety and at least one E is an ester containing moiety, n and m each independently is an integer from 2 to 12. The esterified macromonomer is obtainable by esterification of at least a portion of the —OH groups of a macromonomer having at least one terminal double bond with at least one derivative of an inorganic or organic acid which introduces pendant groups exhibiting at least one acid moiety selected from the group of consisting of —COOH, —PO3H2, —SO3H, —BO2H or salts thereof. The number of the acid moieties is chosen such that a polymer obtained by polymerizing those monomers has an adhesive strength to dentine of at least 2 MPa.

摘要翻译： 在通式范围内的酯化大分子单体：其中Z是有机部分，R 1是氢或具有1至12个碳原子的取代或未取代的烷基，具有1至12个碳原子的烷氧基，具有2至12个的烯基 碳原子，具有5至12个碳原子的环烷基，具有6至12个碳原子的芳基或具有7至12个碳原子的芳烷基，每个E独立地是羟基，有机酯部分或含无机酯的部分， 至少一个E是含酯部分，n和m各自独立地为2至12的整数。酯化的大分子单体可通过至少一部分具有至少一个末端双键的大分子单体的-OH基团酯化得到 引入具有至少一个选自-COOH，-PO 3 H 2，-SO 3 H，-BO 2 H或其盐的至少一个酸基部分的侧基的无机或有机酸的至少一种衍生物。 选择酸部分的数目使得通过聚合这些单体获得的聚合物对牙本质的粘合强度至少为2MPa。

公开(公告)号：US06734223B2

公开(公告)日：2004-05-11

申请号：US09925174

申请日：2001-08-09

申请人： Uwe Walz ,  Joachim E. Klee

发明人： Uwe Walz ,  Joachim E. Klee

IPC分类号： A61K608

CPC分类号： A61K6/0038 ,  A61K6/083 ,  A61K6/087 ,  C08L33/00 ,  C08L79/02

摘要： Dental compositions comprising at least a polymerizable monomer and/or at least a polyaminoester that are prepared by reaction of bis- or polyacrylic esters and amines, pigments, organic and/or inorganic fillers, initiators and stabilizers.

摘要翻译： 至少包含通过双 - 或聚丙烯酸酯和胺，颜料，有机和/或无机填料，引发剂和稳定剂的反应制备的可聚合单体和/或至少一种聚氨酯的牙科组合物。

公开(公告)号：US06503084B2

公开(公告)日：2003-01-07

申请号：US09930743

申请日：2001-08-02

申请人： Markus Evers ,  Uwe Walz ,  Andreas E. Grützner ,  Joachim E. Klee

发明人： Markus Evers ,  Uwe Walz ,  Andreas E. Grützner ,  Joachim E. Klee

IPC分类号： A61C504

CPC分类号： A61C5/66 ,  A61C5/62

摘要： A method of venting during sealing the cartridge. The cartridge body has an external wall, a generally cylindrical internal chamber wall having an internal chamber wall diameter and enclosing a cartridge chamber, and at least one channel wall forming a channel (or groove) in the chamber wall. The piston has a generally cylindrical plug wall positioned adjacent to the generally cylindrical internal chamber wall. The cylindrical plug wall has a diameter substantially equal to the diameter of the cylindrical internal chamber wall. Dental material is conveyed into the cartridge chamber. The piston is pressed into the cartridge chamber while venting gas from the cartridge chamber through the channel prior to forming a hermetic seal around the dental material in the cartridge chamber.

摘要翻译： 在密封墨盒期间排气的方法。 盒主体具有外壁，具有内室壁直径并且包围盒室的大致圆柱形的内室壁，以及在室壁中形成通道（或凹槽）的至少一个通道壁。 活塞具有邻近大致圆柱形的内部室壁定位的大致圆柱形的塞子壁。 圆柱形塞壁的直径基本上等于圆柱形内腔壁的直径。 牙科材料被输送到药筒室。 在盒室内的牙科材料周围形成气密密封之前，活塞被压入暗盒室，同时从暗盒室通过通道排出气体。

公开(公告)号：US06372816B1

公开(公告)日：2002-04-16

申请号：US09498004

申请日：2000-02-04

申请人： Uwe Walz ,  Kai P. Pflug ,  Ralf Wilner ,  Markus Evers

发明人： Uwe Walz ,  Kai P. Pflug ,  Ralf Wilner ,  Markus Evers

IPC分类号： A61K6083

CPC分类号： A61C5/66 ,  A61C2202/02 ,  B65D2565/387 ,  Y02W30/806

摘要： The invention provides a storage stable dental composition comprising a volatile organic solvent and a polymerizable material enclosed by a package, which includes a closure, such as a cover or plug and a container made of a copolymer of a cycloolefin and an open chain olefin. In accordance with an embodiment of the invention is provided a stored packaged dental product by the process including: enclosing a dental composition in a package with at least a substantial portion of an injection molded thermoplastic copolymer of a cycloolefin and an open chain olefin, and storing the dental composition in the package for at least 1 week.

摘要翻译： 本发明提供一种储存稳定的牙科用组合物，其包含挥发性有机溶剂和由包装封闭的可聚合材料，其包括封闭物，例如盖子或塞子以及由环烯烃和开链烯烃的共聚物制成的容器。 根据本发明的一个实施方案提供了一种通过该方法的储存的包装牙科产品，其包括：将至少大部分注射成型的环烯烃和开链烯烃的热塑性共聚物的牙科组合物封装在包装中，并存储 包装中的牙齿组合物至少1周。

公开(公告)号：US08026295B2

公开(公告)日：2011-09-27

申请号：US12002550

申请日：2007-12-18

申请人： Uwe Walz ,  Joachim E. Klee

发明人： Uwe Walz ,  Joachim E. Klee

IPC分类号： A61K6/083 ,  C08K5/34

CPC分类号： A61K6/083 ,  C07D211/94 ,  C08F265/04 ,  C08F290/00 ,  C08F290/06 ,  C08F291/00 ,  C08F293/005 ,  C08K5/3435 ,  C08L51/003 ,  C08L53/00 ,  C08L25/00

摘要： Dental composition having an improved light and thermal stability, including a mixture of at least a polymerizable resin, at least a polymerizable monomer, at least a polymerization initiator and/or a sensitizer and stabilizer, and at least an organic and/or inorganic filler and pigments in a content of 0 to 90 percent and at least one of the stable radicals.

摘要翻译： 具有改善的光和热稳定性的牙科组合物，包括至少可聚合树脂，至少可聚合单体，至少聚合引发剂和/或敏化剂和稳定剂的混合物，以及至少一种有机和/或无机填料和 含量为0至90％的颜料和至少一种稳定的基团。

公开(公告)号：US20100022681A1

公开(公告)日：2010-01-28

申请号：US12586789

申请日：2009-09-28

申请人： Uwe Walz ,  Joachim E. Klee

发明人： Uwe Walz ,  Joachim E. Klee

IPC分类号： A61K6/083

CPC分类号： A61K6/0835 ,  A61K6/0038 ,  A61K6/083 ,  A61K6/087 ,  C08L33/26 ,  C08L79/02

摘要： The invention concerns a dental composition comprising bisacrylamides that are polymerizable by free-radical polymerization and by Michael-addition polymerization with amines. The application of polymerization and addition polymerization with amines opens the possibility to completely reacted materials that have no oxygen inhibited layers. The claimed bisacrylamides have an improved hydrolytic stability.

摘要翻译： 本发明涉及包含可通过自由基聚合和通过与胺进行迈克尔加成聚合的双丙烯酰胺的牙科用组合物。 聚合和加成聚合与胺的应用开启了不具有抑氧层的完全反应的材料的可能性。 要求保护的双丙烯酰胺具有改进的水解稳定性。

公开(公告)号：US20070129458A1

公开(公告)日：2007-06-07

申请号：US11699597

申请日：2007-01-29

申请人： Uwe Walz ,  Joachim Klee

发明人： Uwe Walz ,  Joachim Klee

IPC分类号： A61K6/083

CPC分类号： A61K6/0835 ,  A61K6/0038 ,  A61K6/083 ,  A61K6/087 ,  C08L33/26 ,  C08L79/02

摘要： The invention concerns a dental composition comprising bisacrylamides that are polymerizable by free-radical polymerization and by Michael-addition polymerization with amines. The application of polymerization and addition polymerization with amines opens the possibility to completely reacted materials that have no oxygen inhibited layers. The claimed bisacrylamides have an improved hydrolytic stability.

摘要翻译： 本发明涉及包含可通过自由基聚合和通过与胺进行迈克尔加成聚合的双丙烯酰胺的牙科用组合物。 聚合和加成聚合与胺的应用开启了不具有抑氧层的完全反应的材料的可能性。 要求保护的双丙烯酰胺具有改进的水解稳定性。

公开(公告)号：US06767936B2

公开(公告)日：2004-07-27

申请号：US10308564

申请日：2002-12-03

申请人： Uwe Walz ,  Joachim E. Klee

发明人： Uwe Walz ,  Joachim E. Klee

IPC分类号： A61K610

CPC分类号： A61K6/0038 ,  C08L33/00

摘要： The invention concerns a dental composition comprising bisacrylamides that are polymerizable by free-radical polymerization and by Michael-addition polymerization with amines. The application of polymerization and addition polymerization with amines opens the possibility to completely reacted materials that have no oxygen inhibited layers. The claimed bisacrylamides have an improved hydrolytic stability.