公开(公告)号：US5043489A

公开(公告)日：1991-08-27

申请号：US529747

申请日：1990-05-24

申请人： Vincent Nocito ,  Louis J. Bedell ,  Mathew I. Levinson

发明人： Vincent Nocito ,  Louis J. Bedell ,  Mathew I. Levinson

IPC分类号： C07C201/12 ,  C07C205/08

CPC分类号： C07C201/12

摘要： A method of preparing a monohalogenated nitroalkane which comprises reacting equal molar quantities of an alkali metal hydroxide and a nitroalkane in a suitable medium to form a nitronate salt therein, promptly mixing the medium containing the nitronate salt with an equal molar quantity of a halogen to form a monohalogenated nitroalkane in the medium, promptly adding a material to the medium containing the monohalogenated nitroalkane to terminate any further halogenation therein, and recovering the monohalogenated nitroalkane from the medium.

摘要翻译： 一种制备单卤代硝基烷烃的方法，其包括使等摩尔量的碱金属氢氧化物和硝基烷烃在合适的介质中反应以形成其中的硝酸盐，迅速将含有硝酸盐的介质与等摩尔量的卤素混合形成 介质中的单卤代硝基烷烃，迅速向含有单卤代硝基烷烃的介质中加入一种材料，以终止其中任何进一步的卤化，并从介质中回收一卤代硝基烷烃。

公开(公告)号：US5328635A

公开(公告)日：1994-07-12

申请号：US866662

申请日：1992-04-08

申请人： Chih-Yueh Chou ,  Pattabhi K. Raman ,  Robert E. Malocha ,  Thomas L. Johnson ,  Vincent Nocito ,  Marina D. Hoffman ,  Patrick E. Brutto

发明人： Chih-Yueh Chou ,  Pattabhi K. Raman ,  Robert E. Malocha ,  Thomas L. Johnson ,  Vincent Nocito ,  Marina D. Hoffman ,  Patrick E. Brutto

IPC分类号： B01D19/04 ,  C07C251/08 ,  C07C251/20 ,  C07D263/04 ,  C07D263/06 ,  C07D263/52 ,  C07D498/04 ,  C08G18/08 ,  C08K5/29 ,  C08K5/353 ,  C23F11/10 ,  C23F11/14 ,  C09K3/00

CPC分类号： C07D263/52 ,  B01D19/0413 ,  C07C251/08 ,  C07C251/20 ,  C07D263/04 ,  C07D263/06 ,  C08G18/0885 ,  C08K5/29 ,  C08K5/353 ,  C23F11/10 ,  C23F11/146 ,  C23F11/149

摘要： Methods of using a mixture as a corrosion inhibitor, moisture or formaldehyde scavenger, reactive diluent, rheological modifier, thermoplastic foam inhibitor, antifreezing agent, decolorizing agent, or drying agent. The mixture consists of from 0 to 100 mole percent of an iminoalcohol compound: ##STR1## wherein: R.sub.1 is a methyl or methylol group, an ethyl or ethylol group, a branched or straight chain alkyl or alkanol group, a cycloalkyl group, or an aryl group; R.sub.2 is a hydrogen atom, a methyl or methylol group, an ethyl or ethylol group, a straight chain or branched chain alkyl or alkanol group, a cycloalkyl group, or an aryl group, or R.sub.1 and R.sub.2 are fused together with the attached carbon to form a cycloalkane ring; R.sub.3, R.sub.4 and R.sub.5 are, individually, a hydrogen atom, a methyl or methylol group, an ethyl or ethylol group, or a straight chain or branched chain alkyl or alkanol group; R.sub.6 is a hydrogen atom, a methyl group, an ethyl group, or a straight chain or branched chain alkyl group; and R.sub.7 is a hydrogen atom, a methyl or methylol group, an ethyl or ethylol group, a straight chain or branched chain alkyl or alkanol group, a cycloalkyl group, an acyl group, an aryl group, an ester containing group, or an amino containing group; and from 0 to 100 mole percent of an oxazolidine compound having the structure: ##STR2##

摘要翻译： 使用混合物作为腐蚀抑制剂，水分或甲醛清除剂，反应性稀释剂，流变改性剂，热塑性泡沫抑制剂，防冻剂，脱色剂或干燥剂的方法。 该混合物由0至100摩尔％的亚氨基醇化合物组成：其中：R1为甲基或羟甲基，乙基或羟基，支链或直链烷基或链烷醇基，环烷基或 芳基; R2是氢原子，甲基或羟甲基，乙基或羟基，直链或支链烷基或链烷醇基，环烷基或芳基，或者R1和R2与连接的碳稠合在一起 形成环烷环; R 3，R 4和R 5分别为氢原子，甲基或羟甲基，乙基或羟基，或直链或支链烷基或链烷醇基团; R6是氢原子，甲基，乙基或直链或支链烷基; R 7为氢原子，甲基或羟甲基，乙基或羟基，直链或支链烷基或链烷醇基，环烷基，酰基，芳基，含酯基或氨基 含有组; 和0至100摩尔％的具有以下结构的恶唑烷化合物：

公开(公告)号：US5053545A

公开(公告)日：1991-10-01

申请号：US564540

申请日：1990-08-07

申请人： Thomas H. Marman ,  Vincent Nocito

发明人： Thomas H. Marman ,  Vincent Nocito

IPC分类号： C07C213/02

CPC分类号： C07C213/02

摘要： A method of preparing an amino alcohol of the formula ##STR1## where R.sub.1 is H, lower alkyl or R.sub.2, R.sub.2 is R.sub.3 CHOH in which R.sub.3 is H, alkyl or aryl. R.sub.3 preferably is hydrogen, lower alkyl or monocyclic aryl such as phenyl. The inventive method involves the reaction of halonitroalcohol with hydrogen in the presence of methanol, a suitable buffering agent such as ammonia, and a hydrogenation catalyst to form amino alcohol salt, neutralizing the amino alcohol salt, and recovering the resultant amino alcohol.

摘要翻译： 制备式为“IMAGE”的氨基醇的方法，其中R 1为H，低级烷基或R 2，R 2为R 3为CH 3，其中R 3为H，烷基或芳基。 R3优选为氢，低级烷基或单环芳基，例如苯基。 本发明的方法包括在甲醇，合适的缓冲剂如氨的存在下卤代四氢醇与氢气的反应，和加氢催化剂形成氨基醇盐，中和氨基醇盐，并回收得到的氨基醇。

公开(公告)号：US5223174A

公开(公告)日：1993-06-29

申请号：US745476

申请日：1991-08-15

申请人： Chih-Yueh Chou ,  Robert E. Malocha ,  Vincent Nocito

发明人： Chih-Yueh Chou ,  Robert E. Malocha ,  Vincent Nocito

IPC分类号： C08G18/30 ,  C07C251/08 ,  C07C251/20 ,  C07D263/04 ,  C07D263/06 ,  C07D263/52 ,  C07D498/04 ,  C08G18/08 ,  C08K5/29 ,  C08K5/34 ,  C08K5/353 ,  C08L75/00 ,  C08L75/04 ,  C09D175/00 ,  C09D175/04 ,  C09J175/00 ,  C09J175/04 ,  C09K3/00 ,  C23F11/10 ,  C23F11/14

CPC分类号： C07D263/52 ,  C07C251/08 ,  C07C251/20 ,  C07D263/04 ,  C07D263/06 ,  C08G18/0885 ,  C08K5/29 ,  C08K5/353 ,  C23F11/10 ,  C23F11/146 ,  C23F11/149

摘要： A moisture-scavenging composition including a mixture of moisture scavenging compounds, wherein the mixture consists of from 0 to 100 mole percent of an iminoalcohol compound: ##STR1## wherein: R.sub.1 is a methyl or methylol group, an ethyl or ethylol group, a branched or straight chain alkyl or alkanol group, a cycloalkyl group, or an aryl group; R.sub.2 is a hydrogen atom, a methyl or methylol group, an ethyl or ethylol group, a straight chain or branched chain alkyl or alkanol group, a cycloalkyl group, or an aryl group, or R.sub.1 and R.sub.2 are fused together with the attached carbon to form a cycloalkane ring; R.sub.3, R.sub.4 and R.sub.5 are, individually, a hydrogen atom, a methyl or methylol group, an ethyl or ethylol group, or a straight chain or branched chain alkyl or alkanol group; R.sub.6 is a hydrogen atom, a methyl group, an ethyl group, or a straight chain or branched chain alkyl group; and R.sub.7 is a hydrogen atom, a methyl or methylol group, an ethyl or ethylol group, a straight chain or branched chain alkyl or alkanol group, a cycloalkyl group, an acyl group or an aryl group; andfrom 0 to 100 mole percent of an oxazolidine compound having the structure: ##STR2##

摘要翻译： 一种除湿组合物，其包含除湿化合物的混合物，其中所述混合物由0至100摩尔％的亚氨基醇化合物组成：其中：R1是甲基或羟甲基，乙基或羟基，基团 或直链烷基或链烷醇基，环烷基或芳基; R2是氢原子，甲基或羟甲基，乙基或羟基，直链或支链烷基或链烷醇基，环烷基或芳基，或者R1和R2与连接的碳稠合在一起 形成环烷环; R 3，R 4和R 5分别为氢原子，甲基或羟甲基，乙基或羟基，或直链或支链烷基或链烷醇基团; R6是氢原子，甲基，乙基或直链或支链烷基; R 7为氢原子，甲基或羟甲基，乙基或羟基，直链或支链烷基或链烷醇基，环烷基，酰基或芳基; 和0至100摩尔％的具有以下结构的恶唑烷化合物：

公开(公告)号：US4922030A

公开(公告)日：1990-05-01

申请号：US279525

申请日：1988-12-05

申请人： Vincent Nocito ,  Louis J. Bedell ,  Matthew I. Levinson

发明人： Vincent Nocito ,  Louis J. Bedell ,  Matthew I. Levinson

IPC分类号： C07C201/12 ,  C07C205/08 ,  C07C205/26

CPC分类号： C07C201/12

摘要： A method of preparing bromonitroalcohols of the formula ##STR1## where R.sub.1 is H, lower alkyl or R.sub.2, R.sub.2 is R.sub.3 CHOH in which R.sub.3 is H, alkyl or aryl, and X is a halogen, which comprises reacting a halonitroalkane with a substantially nonaqueous solutioln of an aldehyde of the formula R.sub.3 CHO where R.sub.3 is as noted above, in the presence of an alkaline catalyst. R.sub.3 preferably is lower alkyl or monocyclic aryl such as phenyl.

摘要翻译： 其中R1是H，低级烷基或R2，R2是R3CHOH，其中R3是H，烷基或芳基，X是卤素的方法，该方法包括使卤代硝基烷烃与基本上非水溶剂 的式R3CHO的醛，其中R3如上所述，在碱性催化剂的存在下。 R3优选为低级烷基或单环芳基，例如苯基。

公开(公告)号：US5433891A

公开(公告)日：1995-07-18

申请号：US220825

申请日：1994-03-31

申请人： Chih-Yueh Chou ,  Pattabbi K. Raman ,  Robert E. Malocha ,  Thomas L. Johnson ,  Vincent Nocito ,  Marina D. Hoffman ,  Patrick E. Brutto

发明人： Chih-Yueh Chou ,  Pattabbi K. Raman ,  Robert E. Malocha ,  Thomas L. Johnson ,  Vincent Nocito ,  Marina D. Hoffman ,  Patrick E. Brutto

IPC分类号： B01D19/04 ,  C07C251/08 ,  C07C251/20 ,  C07D263/04 ,  C07D263/06 ,  C07D263/52 ,  C07D498/04 ,  C08G18/08 ,  C08K5/29 ,  C08K5/353 ,  C23F11/10 ,  C23F11/14 ,  B01D17/00 ,  C09K3/00

CPC分类号： C07D263/52 ,  B01D19/0413 ,  C07C251/08 ,  C07C251/20 ,  C07D263/04 ,  C07D263/06 ,  C08G18/0885 ,  C08K5/29 ,  C08K5/353 ,  C23F11/10 ,  C23F11/146 ,  C23F11/149

摘要： Methods of using a mixture as a corrosion inhibitor, moisture or formaldehyde scavenger, reactive diluent, rheological modifier, thermoplastic foam inhibitor, antifreezing agent, decolorizing agent, drying agent, agent for reducing bubble formation, and an agent for reducing downglossing. The mixture consists of from 0 to 100 mole percent of an iminoalcohol compound: ##STR1## wherein: R.sub.1 is a methyl or methylol group, an ethyl or ethylol group, a branched or straight chain alkyl or alkanol group, a cycloalkyl group, or an aryl group; R.sub.2 is a hydrogen atom, a methyl or methylol group, an ethyl or ethylol group, a straight chain or branched chain alkyl or alkanol group, a cycloalkyl group, or an aryl group, or R.sub.1 and R.sub.2 are fused together with the attached carbon to form a cycloalkane ring; R.sub.3, R.sub.4 and R.sub.5 are, individually, a hydrogen atom, a methyl or methylol group, an ethyl or ethylol group, or a straight chain or branched chain alkyl or alkanol group; R.sub.6 is a hydrogen atom, a methyl group, an ethyl group, or a straight chain or branched chain alkyl group; and R.sub.7 is a hydrogen atom, a methyl or methylol group, an ethyl or ethylol group, a straight chain or branched chain alkyl or alkanol group, a cycloalkyl group, an acyl group, an aryl group, an ester containing group, or an amino containing group; andfrom 0 to 100 mole percent of an oxazolidine compound having the structure: ##STR2##

摘要翻译： 使用混合物作为腐蚀抑制剂，水分或甲醛清除剂，反应性稀释剂，流变改性剂，热塑性泡沫抑制剂，防冻剂，脱色剂，干燥剂，减少气泡形成的试剂和减少下降剂的方法。 该混合物由0至100摩尔％的亚氨基醇化合物组成：其中：R1为甲基或羟甲基，乙基或羟基，支链或直链烷基或链烷醇基，环烷基 ，或芳基; R2是氢原子，甲基或羟甲基，乙基或羟基，直链或支链烷基或链烷醇基，环烷基或芳基，或者R1和R2与连接的碳稠合在一起 形成环烷环; R 3，R 4和R 5分别为氢原子，甲基或羟甲基，乙基或羟基，或直链或支链烷基或链烷醇基团; R6是氢原子，甲基，乙基或直链或支链烷基; R 7为氢原子，甲基或羟甲基，乙基或羟基，直链或支链烷基或链烷醇基，环烷基，酰基，芳基，含酯基或氨基 含有组; 和0至100摩尔％的具有以下结构的恶唑烷化合物：（II）