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    Chemical storage of radiant energy
    1.
    发明授权
    Chemical storage of radiant energy 失效
    辐射能的化学储存

    公开(公告)号：US3994675A

    公开(公告)日：1976-11-30

    申请号：US512978

    申请日：1974-10-07

    申请人： Wolfgang Hermann Fritz Sasse ,  Tsutomu Teitei

    发明人： Wolfgang Hermann Fritz Sasse ,  Tsutomu Teitei

    IPC分类号： C09K5/16 ,  F28D20/00 ,  F24J3/02

    CPC分类号： F28D20/003 ,  C09K5/16 ,  Y02E60/142

    摘要： A system for the chemical storage of radiant energy in which either:A. 1,8-diaryl-1a,2,7,7a-tetrahydro-1,2,7-metheno-1H-cyclopropa[b]naphthalenes (1) are converted on heating to 1,2-diaryl-2a,8b-dihydrocyclobuta[a]naphthalenes (2) or 8,9-diaryl-benzocyclooctatetraenes (3), with the release of heat; and exposure of either compounds (3) or compounds (2) to suitable radiation results in the photochemical synthesis of compounds (1); orB. substituted naphthalenes undergo photochemical dimerization to form 1,2,2a,7,8,12b-hexahydro-1,8,2,7-ethanedihylidenedibenzo[a,e]cyclobuta[c]cyclooctenes. On heating, the latter revert to the original naphthalenes with the release of heat.

    摘要翻译： 辐射能化学储存系统，其中：

    Radiation polymerization of triallylamines using a non-polar, non-hydroxylic solvent
    2.
    发明授权
    Radiation polymerization of triallylamines using a non-polar, non-hydroxylic solvent 失效
    使用非极性非羟基溶剂进行三烯丙基胺的辐射聚合

    公开(公告)号：US3990958A

    公开(公告)日：1976-11-09

    申请号：US423404

    申请日：1973-12-10

    申请人： Wolfgang Hermann Fritz Sasse

    发明人： Wolfgang Hermann Fritz Sasse

    IPC分类号： C08F2/00 ,  B01J41/14 ,  C08F2/04 ,  C08F2/52 ,  C08F2/54 ,  C08F26/00 ,  C08F26/02 ,  C08F1/16 ,  C08F3/84 ,  C08F15/02

    CPC分类号： C08F26/02

    摘要： A method of polymerizing a composition comprising a mixture of monomers said monomer mixture containing from 3 to 100% of amines containing two or more allyl groups which method comprises irradiating a solution of a hydrofluoride, hydrochloride or sulphate salt of said amine in a non polar and non hydroxylic solvent with electromagnetic radiation having a wavelength greater than 180 nanometers and preferably less than 800 nano meters preferably in the presence of a radiation sensitizer at a temperature in the range from -80.degree. to +120.degree. C preferably 10.degree. C to 90.degree. C and isolating the polymer so formed.

    摘要翻译： 聚合包含单体混合物的组合物的方法，所述单体混合物含有3至100％的含有两个或多个烯丙基的胺，该方法包括以非极性对所述胺的氢氟酸盐，盐酸盐或硫酸盐溶液进行照射， 具有波长大于180纳米，优选小于800纳米的电磁辐射的非羟基溶剂，优选在辐射敏化剂存在下，温度范围为-80至+ 120℃，优选10℃至90℃。 并分离如此形成的聚合物。