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    Process for producing polyacetylene
    2.
    发明授权
    Process for producing polyacetylene 失效
    生产聚乙炔的方法

    公开(公告)号：US4384090A

    公开(公告)日：1983-05-17

    申请号：US288886

    申请日：1981-07-31

    Applicant: Jurgen Hocker ,  Wolfgang Wieder ,  Rudolf Merten ,  Josef Witte

    Inventor： Jurgen Hocker ,  Wolfgang Wieder ,  Rudolf Merten ,  Josef Witte

    IPC: C08F4/00 ,  C08F4/60 ,  C08F38/00 ,  C08F38/02 ,  C08F4/68

    CPC classification number: C08F38/02

    Abstract: Process for the production of polyacetylene, wherein acetylene is polymerized in an organic diluent with the aid of an organometallic mixed catalyst based on a vanadium compound of the formula ##STR1## wherein R.sup.1 represents halogen (chlorine),R.sup.2 and R.sup.3 represent halogen (chlorine), OR.sup.5 (R.sup.5 =C.sub.1 -C.sub.20 alkyl, straight chain, cyclic or branched), wherebyR.sup.2 and R.sup.3 may be the same or different,and on an luminium alkyl compound.

    Abstract translation: 聚乙炔的制备方法，其中乙炔在有机金属混合催化剂的基础上通过有机金属混合催化剂聚合在有机稀释剂中，其中R 1表示卤素（氯），R 2和R 3表示卤素（氯） ，OR5（R5 = C1-C20烷基，直链，环状或支链的），其中R2和R3可以相同或不同，并且在发光烷基化合物上。

    Catalyst, preparation thereof and use thereof in the preparation of telomeric polybutadiene homo- or co-polymers
    4.
    发明授权
    Catalyst, preparation thereof and use thereof in the preparation of telomeric polybutadiene homo- or co-polymers 失效
    催化剂，其制备方法及其在制备端粒聚丁二烯均聚物或共聚物中的应用

    公开(公告)号：US4331823A

    公开(公告)日：1982-05-25

    申请号：US261009

    申请日：1981-05-06

    Applicant: Wolfgang Wieder ,  Josef Witte

    Inventor： Wolfgang Wieder ,  Josef Witte

    IPC: C08F4/00 ,  C08F2/38 ,  C08F4/42 ,  C08F4/46 ,  C08F36/06 ,  C07C2/02

    CPC classification number: C08F36/06

    Abstract: A catalyst comprising:(a) an organometallic compound corresponding to the following general formula: RMe wherein R represents a saturated aliphatic or aromatic hydrocarbon radical having from 2 to 8 carbon atoms; and Me represents an alkali metal;(b) a compound corresponding to the following general formula: R'OMe' wherein R' represents a saturated aliphatic or aromatic hydrocarbon radical having from 2 to 8 carbon atoms; and Me' represents an alkali metal; and(c) a tertiary aliphatic triamine.A process for the preparation of said catalyst wherein components (a), (b) and (c) are dissolved, in any order, in an aliphatic or aromatic hydrocarbon and reacted at temperatures of from 0.degree. to 100.degree. C., and its use in the preparation of telomeric polybutadiene homo- or co-polymers.

    Abstract translation: 一种催化剂，其包含：（a）对应于以下通式的有机金属化合物：其中R表示具有2至8个碳原子的饱和脂族或芳族烃基; Me表示碱金属; （b）对应于以下通式的化合物：R'OMe'其中R'表示具有2-8个碳原子的饱和脂族或芳族烃基; Me'表示碱金属; 和（c）叔脂族三胺。 一种制备所述催化剂的方法，其中组分（a），（b）和（c）以任何顺序在脂族或芳族烃中溶解并在0℃至100℃的温度下反应， 用于制备端粒聚丁二烯均聚物或共聚物。

    Alternating isoprene-ethylene copolymers and a process for the preparation thereof
    5.
    发明授权
    Alternating isoprene-ethylene copolymers and a process for the preparation thereof 失效
    交替异戊二烯 - 乙烯共聚物及其制备方法

    公开(公告)号：US4288581A

    公开(公告)日：1981-09-08

    申请号：US199071

    申请日：1980-10-20

    Applicant: Wolfgang Wieder ,  Josef Witte

    Inventor： Wolfgang Wieder ,  Josef Witte

    IPC: C08F4/00 ,  C08F4/60 ,  C08F210/02 ,  C08F236/00 ,  C08F236/04 ,  C08F236/08 ,  C08F4/76

    CPC classification number: C08F210/02 ,  C08F236/08

    Abstract: The invention refers to Isoprene-ethylene copolymers having alternating monomer units in which the proportion of recurring-isoprene-ethylene-sequences is more than 80 mol %, in which the proportion of built-in isoprene in the 1,4-configuration is more than 80 mol % which consists of more than 70 mol % of a trans-arrangement, and in which less than 5 mol % of the built-in isoprene is present in the 3,4-configuration, the copolymers having a glass temperature of between -70.degree. C. and -90.degree. C., a Mooney-viscosity of between 30 and 150 [ML 1+4 (100.degree. C.)] and a viscosity number [.eta.], measured at 25.degree. C. in toluene, of between 0.5 and 6, and a process for their preparation characterized in that polymerization is carried out in solution at a temperature of between -80.degree. C. and +100.degree. C. in the presence of a catalyst system which consists of(a) a vanadium compound of the formula VO(OR).sub.2 X and(b) an organoaluminium compound of formula Al R'.sub.3, HAlR'.sub.2 or R'.sub.2 ALY whereinR represents an alkyl group containing from 1-20 carbon atoms,X represents a halogen atom,R'represents an alkyl group containing from 1 to 8 carbon atomsY represents a halogen atom; whereby the molar ratio of b:a is between 100:1 and 1:10.

    Abstract translation: 本发明涉及具有交替单体单元的异戊二烯 - 乙烯共聚物，其中重复 - 异戊二烯 - 乙烯序列的比例大于80mol％，其中1,4构型中内置异戊二烯的比例大于 80摩尔％，其由多于70摩尔％的反式排列组成，并且其中3,4构型中存在小于5摩尔％的内置异戊二烯，所述共聚物的玻璃温度介于 - 在70℃和-90℃下，在25℃在甲苯中测定的门尼粘度为30至150 [ML 1 + 4（100℃）]和粘度数η为 在0.5和6之间，其制备方法的特征在于在催化剂体系存在下，在-80℃至+ 100℃的温度下，在溶液中进行聚合，所述催化剂体系由（a） 式VO（OR）2 X的钒化合物和（b）式Al R'3，HA1R'2或R'2ALY的有机铝化合物，其中R代表 含有1-20个碳原子的烷基，X表示卤素原子，R'表示含有1至8个碳原子的烷基，Y表示卤素原子; 由此b：a的摩尔比在100:1和1:10之间。

    Foils of polyacetylene
    7.
    发明授权
    Foils of polyacetylene 失效
    聚乙炔箔

    公开(公告)号：US4408027A

    公开(公告)日：1983-10-04

    申请号：US288887

    申请日：1981-07-31

    Applicant: Jurgen Hocker ,  Wolfgang Wieder ,  Rolf Dhein

    Inventor： Jurgen Hocker ,  Wolfgang Wieder ,  Rolf Dhein

    IPC: C08F2/00 ,  C08F38/00 ,  C08F38/02 ,  C08J3/12 ,  C08J5/18

    CPC classification number: C08J5/18 ,  C08F38/02 ,  C08J2349/00

    Abstract: Process for the production of a suspension of polyacetylene in the form of particles having a diameter of from 0.01 to 1 mm and having a great number of fibrous appendices comprising introducing acetylene in an organic suspending agent under constant stirring, in the presence of an aluminum-containing organometallic mixed catalyst in an amount corresponding to 10 to 100 m moles aluminium per liter suspending agent, at temperatures of from -100.degree. to 80.degree. C., until a maximum of 10 g, preferably 1 to 3 g of polyacetylene per liter of suspending agent have been formed.

    Abstract translation: 制备直径为0.01〜1mm，具有大量纤维附着物的聚乙炔悬浮液的方法，其包括在持续搅拌下在有机悬浮剂中，在铝 - 含有有机金属混合催化剂，其数量相当于每升悬浮剂10-100摩尔铝，在-100至80℃的温度下，直到最大值为10克，优选1至3克聚乙炔/升 悬浮剂已经形成。

    Catalyst, preparation thereof and use thereof in the preparation of telomeric polybutadiene homo- or co-polymers
    8.
    发明授权
    Catalyst, preparation thereof and use thereof in the preparation of telomeric polybutadiene homo- or co-polymers 失效

    公开(公告)号：US4316820A

    公开(公告)日：1982-02-23

    申请号：US120626

    申请日：1980-02-11

    Applicant: Wolfgang Wieder ,  Josef Witte

    Inventor： Wolfgang Wieder ,  Josef Witte

    IPC: C08F4/00 ,  C08F2/38 ,  C08F4/42 ,  C08F4/46 ,  C08F36/06 ,  B01J31/12

    CPC classification number: C08F36/06

    Abstract: A catalyst comprising:(a) an organometallic compound corresponding to the following general formula: RMe wherein R represents a saturated aliphatic or aromatic hydrocarbon radical having from 2 to 8 carbon atoms; and Me represents an alkali metal;(b) a compound corresponding to the following general formula: R'OMe' wherein R' represents a saturated aliphatic or aromatic hydrocarbon radical having from 2 to 8 carbon atoms; and Me' represents an alkali metal; and(c) a tertiary aliphatic triamine.A process for the preparation of said catalyst wherein components (a), (b) and (c) are dissolved, in any order, in an aliphatic or aromatic hydrocarbon and reacted at temperatures of from 0.degree. to 100.degree. C., and its use in the preparation of telomeric polybutadiene homo- or co-polymers.

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