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    Metathesis catalysts and reactions using the catalysts
    2.
    发明授权
    Metathesis catalysts and reactions using the catalysts 有权

    公开(公告)号：US11285466B2

    公开(公告)日：2022-03-29

    申请号：US16439512

    申请日：2019-06-12

    Applicant: Ximo AG

    Inventor： Levente Ondi ,  Jeno Varga ,  Agota Bucsai ,  Florian Toth ,  Krisztian Lorincz ,  Csaba Hegedus ,  Emmanuel Robe ,  Georg Emil Frater

    IPC: B01J31/22 ,  B01J31/16 ,  B01J31/18 ,  B01J31/14 ,  C08G61/08 ,  C07C6/04 ,  C07F11/00 ,  C07C67/293 ,  C07C67/347

    Abstract: The invention relates to a method of forming an olefin from a first olefin and a second olefin in a metathesis reaction, comprising step (i): (i) reacting the first olefin with the second olefin in the presence of a compound that catalyzes said metathesis reaction such that the molar ratio of said compound to the first or the second olefin is from 1:500 or less, and the conversion of the first or the second olefin to said olefin is at least 50%, characterized in that as compound that catalyzes said metathesis reaction a compound of the following formula is used: wherein M is Mo or W; R1 is aryl, heteroaryl, alkyl, or heteroalkyl; optionally substituted; R2 and R3 can be the same or different and are hydrogen, alkyl, alkenyl, heteroalkyl, heteroalkenyl, aryl, or heteroaryl; optionally substituted; R5 is alkyl, alkoxy, heteroalkyl, aryl, heteroaryl, silylalkyl, silyloxy, optionally substituted; and R4 is a residue R6—X—, wherein X═O and R6 is aryl, optionally substituted; or X═S and R6 is aryl, optionally substituted; or X═O and R6 is (R7, R8, R9)Si; wherein R7, R8, R9 are alkyl or phenyl, optionally substituted; or X═O and R6 is (R10, R11, R12)C, wherein R10, R11, R12 are independently selected from phenyl, alkyl; optionally substituted; and to the catalysts used in the method.

    METAL COMPLEXES AND A PROCESS OF PREPARING THEM
    4.
    发明申请
    METAL COMPLEXES AND A PROCESS OF PREPARING THEM 审中-公开

    公开(公告)号：US20180022770A1

    公开(公告)日：2018-01-25

    申请号：US15556268

    申请日：2016-03-08

    Applicant: XiMo AG

    Inventor： Georg Frater ,  Henrik Gulyas ,  Levente Ondi

    IPC: C07F11/00 ,  C08G61/02

    CPC classification number: C07F11/00 ,  C08F4/69034 ,  C08G61/02 ,  C08G61/08 ,  C08G2261/11 ,  C08G2261/3325 ,  C08G2261/418

    Abstract: A compound of the formula II (I) in which X is substituted pyrrolide with the general structure of (II) in which Ra-Rd are independently selected from H, C1-C4 alkyl, C1-C4 alkoxy, aryl, aryloxy, dialkylamino, diarylamino, halogen, trifluoromethyl, cyano, nitro, sulfonyl and sulfinyl. Y is C1-C6 alkoxy, C1-C10 aryloxy, optionally substituted; R1 is selected from H, C1-C12 alkyl and 5- to 18-membered aryl, optionally substituted; R2 is selected from C1-C12-alkyl, 5- to 18-membered aryl, optionally substituted; R3 is selected from C1-C12 alkyl, 5- to 18-membered aryl, optionally substituted; and 15 124-R11 are independently selected from H, C1-C4 alkyl and halogen. The compounds are particularly effective precursors of metathesis catalysts for the polymerisation of dicyclopentadiene.

    COMPOUNDS AND THE USE THEREOF IN METATHESIS REACTIONS
    5.
    发明申请
    COMPOUNDS AND THE USE THEREOF IN METATHESIS REACTIONS 审中-公开

    公开(公告)号：US20190119311A1

    公开(公告)日：2019-04-25

    申请号：US16167250

    申请日：2018-10-22

    Applicant: XiMo AG

    Inventor： Florian Toth ,  Georg Frater ,  Levente Ondi

    IPC: C07F11/00 ,  B01J31/22 ,  C07C67/475 ,  C07D321/00 ,  C07C6/04 ,  C07C67/333

    Abstract: The disclosure provides Group 6 complexes, which, in some embodiments, are useful for catalyzing olefin metathesis reactions. In some embodiments, the compounds are compounds of the following formula: wherein: M is a Group 6 metal atom; X is an oxygen atom, ═N—R5, ═N—N(R5)(R5′) or ═N—O—R5, R5 and R5′ independently being various substituents, such as aryl or heteroaryl, each optionally substituted; n is 0 or 1; Rz is a neutral ligand; R1 is hydrogen or an organic substituent; R2 is an aryl or heteroaryl group, each optionally substituted; R3 is an anionic ligand; and R4 is an anionic ligand, such as a pyrrolide, a pyrazolide, an imidazolide, an indolide, an azaindolide, or an indazolide, each optionally substituted.

    Compounds and the use thereof in metathesis reactions
    6.
    发明授权
    Compounds and the use thereof in metathesis reactions 有权

    公开(公告)号：US10106566B2

    公开(公告)日：2018-10-23

    申请号：US15303089

    申请日：2015-04-09

    Applicant: XiMo AG

    Inventor： Florian Toth ,  Georg Frater ,  Levente Ondi

    IPC: C07F11/00 ,  B01J31/12 ,  B01J31/22 ,  C07C67/475 ,  C07D321/00 ,  C07C67/333 ,  C07C6/04

    Abstract: The disclosure provides Group 6 complexes, which, in some embodiments, are useful for catalyzing olefin metathesis reactions. In some embodiments, the compounds are compounds of the following formula (I) wherein: M is a Group 6 metal atom; X is an oxygen atom, ═N—R5, ═N—N(R5)(R5′) or ═N—O—R5, R5 and R5′ independently being various substituents, such as aryl or heteroaryl, each optionally substituted; n is 0 or 1; Rz is a neutral ligand; R1 is hydrogen or an organic substituent; R2 is an aryl or heteroaryl group, each optionally substituted; R3 is an anionic ligand; and R4 is an anionic ligand, such as a pyrrolide, a pyrazolide, an imidazolide, an indolide, an azaindolide, or an indazolide, each optionally substituted.

    IMMOBILIZED METATHESIS TUNGSTEN CATALYSTS AND USE THEREOF IN OLEFIN METATHESIS
    8.
    发明申请
    IMMOBILIZED METATHESIS TUNGSTEN CATALYSTS AND USE THEREOF IN OLEFIN METATHESIS 审中-公开
    固定化催化剂及其在油脂中的应用

    公开(公告)号：US20160122375A1

    公开(公告)日：2016-05-05

    申请号：US14904172

    申请日：2014-07-11

    Applicant: XIMO AG

    Inventor： Christophe Coperet ,  Victor Mougel ,  Georg Emil Frater ,  Jeno Varga ,  Csaba Hegedus

    IPC: C07F11/00 ,  C07C6/04 ,  B01J31/18

    CPC classification number: C07F11/00 ,  B01J31/181 ,  B01J2231/543 ,  B01J2531/66 ,  C07B2200/11 ,  C07C6/04 ,  C07C2531/18 ,  C07C2531/22 ,  C07C11/02

    Abstract: Compound of formula (I) wherein M is W; R1 is H, aryl, heteroaryl, alkyl, or heteroalkyl, optionally substituted, respectively; R2 and R3 can be the same or different and are alkyl, alkenyl, heteroalkyl, heteroalkenyl, aryl, or heteroaryl, optionally substituted, respectively, or hydrogen; R5 is a residue R6—X—, wherein R6 is alkyl, aryl, heteroalkyl, heteroaryl, optionally substituted, respectively; (R7, R8, R9)Si; wherein R7, R8, R9 are independently alkyl, alkoxy, phenyl or phenoxy, optionally substituted, respectively; (R10, R11, R12)C, wherein R10, R11, R12 are independently phenyl, alkyl, optionally substituted, respectively; X═O, S, or NR13, wherein R13 is H; or alkyl or aryl, optionally substituted, respectively; or R5 is R6—CO—NR13, wherein R6 and NR13 have the meaning as defined above, or wherein R6 and R13 taken together form a carbon chain having from 2 to 6 carbon atoms; R5 is a 4 to 8 membered N-containing carbon ring, wherein N is linked to M; and R4 is a residue O—Si(O—)3, and represents silica to which M is linked forming a M-O—Si(O—)3 moiety, preferably wherein silica is comprised in a solid support; under the proviso that a compound in which R1=2,6-diisopropylphenyl, R5 dimethylpyrrol-1-yl, R2=tBu, and R3═H is excluded.

    Abstract translation: 式（I）的化合物，其中M为W; R 1分别是H，芳基，杂芳基，烷基或杂烷基，任选被取代; R 2和R 3可以相同或不同，分别为烷基，烯基，杂烷基，杂烯基，芳基或杂芳基，分别任选被取代;或氢; R5是残基R6-X-，其中R6分别是烷基，芳基，杂烷基，杂芳基，任选取代; （R7，R8，R9）Si; 其中R 7，R 8，R 9分别独立地为烷基，烷氧基，苯基或苯氧基，任选被取代; （R 10，R 11，R 12）C，其中R 10，R 11，R 12分别独立地为苯基，烷基，任选取代; X = O，S或NR 13，其中R 13为H; 或烷基或芳基，分别任选取代; 或R 5是R 6 -CO-NR 13，其中R 6和NR 13具有如上所定义的含义，或其中R 6和R 13一起形成具有2至6个碳原子的碳链; R5是4至8元的含N的碳环，其中N与M连接; 并且R 4是残基O-Si（O-O）3，并且表示与M相连的形成M-O-Si（O-）3部分的二氧化硅，优选其中二氧化硅包含在固体载体中; 条件是排除其中R1 = 2,6-二异丙基苯基，R5二甲基吡咯-1-基，R2 = tBu和R3 = H的化合物。

    Ruthenium complexes useful for catalyzing metathesis reactions
    9.
    发明授权
    Ruthenium complexes useful for catalyzing metathesis reactions 有权

    公开(公告)号：US10688481B2

    公开(公告)日：2020-06-23

    申请号：US16333341

    申请日：2017-11-09

    Applicant: XiMo AG

    Inventor： Gabor Eros ,  Georg Emil Frater

    IPC: B01J31/22 ,  C07C67/475 ,  C07F15/00

    Abstract: Compound of formula (4) or formula (5), wherein L is a neutral ligand, preferably a nitrogen-containing heterocyclic carbene (NHC) such as carbene containing at least two nitrogen atoms, a cyclic aminoalkyl carbene (CAAC) or a bicyclic aminoalkyl carbene (BICAAC); R1, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are, independently, H, unbranched or branched C1-20 alkyl, C5-9 cycloalkyl, unbranched or branched C1-20 alkoxy, optionally bearing one or more halogen atoms, respectively; or aryl, optionally substituted with one or more of unbranched or branched C1-20 alkyl, C5-9 cycloalkyl, unbranched or branched C1-20 alkoxy, aryl, aryloxy, unbranched or branched C1-20 alkylcarbonyl, arylcarbonyl, unbranched or branched C1-20 alkoxycarbonyl, aryloxycarbonyl, heteroaryl, carboxyl, cyano, nitro, amido, aminosulfonyl, N-heteroarylsulfonyl, unbranched or branched C1-20 alkylsulfonyl, arylsulfonyl, unbranched or branched C1-20 alkylsulfinyl, arylsulfinyl, unbranched or branched C1-20 alkylthio, arylthio, sulfonamide, halogen or N(Ry)(Rz), wherein Ry and Rz are independently selected from H and C1-20 alkyl: RC is H, unbranched or branched C1-20 alkyl.

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