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    METAL COMPLEXES AND A PROCESS OF PREPARING THEM
    1.
    发明申请
    METAL COMPLEXES AND A PROCESS OF PREPARING THEM 审中-公开

    公开(公告)号：US20180022770A1

    公开(公告)日：2018-01-25

    申请号：US15556268

    申请日：2016-03-08

    Applicant: XiMo AG

    Inventor： Georg Frater ,  Henrik Gulyas ,  Levente Ondi

    IPC: C07F11/00 ,  C08G61/02

    CPC classification number: C07F11/00 ,  C08F4/69034 ,  C08G61/02 ,  C08G61/08 ,  C08G2261/11 ,  C08G2261/3325 ,  C08G2261/418

    Abstract: A compound of the formula II (I) in which X is substituted pyrrolide with the general structure of (II) in which Ra-Rd are independently selected from H, C1-C4 alkyl, C1-C4 alkoxy, aryl, aryloxy, dialkylamino, diarylamino, halogen, trifluoromethyl, cyano, nitro, sulfonyl and sulfinyl. Y is C1-C6 alkoxy, C1-C10 aryloxy, optionally substituted; R1 is selected from H, C1-C12 alkyl and 5- to 18-membered aryl, optionally substituted; R2 is selected from C1-C12-alkyl, 5- to 18-membered aryl, optionally substituted; R3 is selected from C1-C12 alkyl, 5- to 18-membered aryl, optionally substituted; and 15 124-R11 are independently selected from H, C1-C4 alkyl and halogen. The compounds are particularly effective precursors of metathesis catalysts for the polymerisation of dicyclopentadiene.

    COMPOUNDS AND THE USE THEREOF IN METATHESIS REACTIONS
    2.
    发明申请
    COMPOUNDS AND THE USE THEREOF IN METATHESIS REACTIONS 审中-公开

    公开(公告)号：US20190119311A1

    公开(公告)日：2019-04-25

    申请号：US16167250

    申请日：2018-10-22

    Applicant: XiMo AG

    Inventor： Florian Toth ,  Georg Frater ,  Levente Ondi

    IPC: C07F11/00 ,  B01J31/22 ,  C07C67/475 ,  C07D321/00 ,  C07C6/04 ,  C07C67/333

    Abstract: The disclosure provides Group 6 complexes, which, in some embodiments, are useful for catalyzing olefin metathesis reactions. In some embodiments, the compounds are compounds of the following formula: wherein: M is a Group 6 metal atom; X is an oxygen atom, ═N—R5, ═N—N(R5)(R5′) or ═N—O—R5, R5 and R5′ independently being various substituents, such as aryl or heteroaryl, each optionally substituted; n is 0 or 1; Rz is a neutral ligand; R1 is hydrogen or an organic substituent; R2 is an aryl or heteroaryl group, each optionally substituted; R3 is an anionic ligand; and R4 is an anionic ligand, such as a pyrrolide, a pyrazolide, an imidazolide, an indolide, an azaindolide, or an indazolide, each optionally substituted.

    Compounds and the use thereof in metathesis reactions
    3.
    发明授权
    Compounds and the use thereof in metathesis reactions 有权

    公开(公告)号：US10106566B2

    公开(公告)日：2018-10-23

    申请号：US15303089

    申请日：2015-04-09

    Applicant: XiMo AG

    Inventor： Florian Toth ,  Georg Frater ,  Levente Ondi

    IPC: C07F11/00 ,  B01J31/12 ,  B01J31/22 ,  C07C67/475 ,  C07D321/00 ,  C07C67/333 ,  C07C6/04

    Abstract: The disclosure provides Group 6 complexes, which, in some embodiments, are useful for catalyzing olefin metathesis reactions. In some embodiments, the compounds are compounds of the following formula (I) wherein: M is a Group 6 metal atom; X is an oxygen atom, ═N—R5, ═N—N(R5)(R5′) or ═N—O—R5, R5 and R5′ independently being various substituents, such as aryl or heteroaryl, each optionally substituted; n is 0 or 1; Rz is a neutral ligand; R1 is hydrogen or an organic substituent; R2 is an aryl or heteroaryl group, each optionally substituted; R3 is an anionic ligand; and R4 is an anionic ligand, such as a pyrrolide, a pyrazolide, an imidazolide, an indolide, an azaindolide, or an indazolide, each optionally substituted.

    COMPOUNDS AND THE USE THEREOF IN METATHESIS REACTIONS
    4.
    发明申请
    COMPOUNDS AND THE USE THEREOF IN METATHESIS REACTIONS 审中-公开
    化合物及其在金属反应中的应用

    公开(公告)号：US20170037069A1

    公开(公告)日：2017-02-09

    申请号：US15303089

    申请日：2015-04-09

    Applicant: XiMo AG

    Inventor： Florian Toth ,  Georg Frater ,  Levente Ondi

    IPC: C07F11/00 ,  C07C6/04 ,  B01J31/22 ,  C07C67/475

    CPC classification number: C07F11/00 ,  B01J31/2265 ,  B01J2231/543 ,  B01J2531/64 ,  B01J2531/66 ,  C07C6/04 ,  C07C67/333 ,  C07C67/475 ,  C07C2531/22 ,  C07C2601/10 ,  C07D321/00 ,  C07C69/74 ,  C07C69/593 ,  C07C11/02 ,  C07C15/12

    Abstract: The disclosure provides Group 6 complexes, which, in some embodiments, are useful for catalyzing olefin metathesis reactions. In some embodiments, the compounds are compounds of the following formula (I) wherein: M is a Group 6 metal atom; X is an oxygen atom, ═N—R5, ═N—N(R5)(R5′) or ═N—O—R5, R5 and R5′ independently being various substituents, such as aryl or heteroaryl, each optionally substituted; n is 0 or 1; Rz is a neutral ligand; R1 is hydrogen or an organic substituent; R2 is an aryl or heteroaryl group, each optionally substituted; R3 is an anionic ligand; and R4 is an anionic ligand, such as a pyrrolide, a pyrazolide, an imidazolide, an indolide, an azaindolide, or an indazolide, each optionally substituted.

    Abstract translation: 本公开提供了第6组配合物，其在一些实施方案中可用于催化烯烃复分解反应。 在一些实施方案中，化合物是下式（I）的化合物，其中：M是第6族金属原子; X是氧原子，= N-R5，= N-N（R5）（R5'）或= N-0-R5，R5和R5独立地是各种取代基，例如芳基或杂芳基，各自任选被取代; n为0或1; Rz是中性配体; R1是氢或有机取代基; R2是芳基或杂芳基，各自任选被取代; R3是阴离子配体; 并且R 4是阴离子配体，例如吡咯烷，吡唑啉，咪唑啉，吲哚啉，氮杂吲哚，或吲唑啉，各自任选被取代。

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