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    Molecular imprinted nanosensors and process for producing same
    1.
    发明授权
    Molecular imprinted nanosensors and process for producing same 有权
    分子印迹纳米传感器及其制备方法

    公开(公告)号：US08313633B2

    公开(公告)日：2012-11-20

    申请号：US12510414

    申请日：2009-07-28

    申请人： Xiulan Li ,  Ranganathan Shashidhar ,  Yufeng Ma

    发明人： Xiulan Li ,  Ranganathan Shashidhar ,  Yufeng Ma

    IPC分类号： C23C28/00

    CPC分类号： G01N27/327 ,  C25D13/04 ,  G01N27/128

    摘要： A molecular recognition sensor system is provided incorporating a molecular imprinted nanosensor device formed by the process steps of: (a) fabricating using photolithography a pair of metallic electrodes separated by a microscale gap onto a first electrical insulation layer formed on a substrate; (b) applying a second electrical insulation layer on most of a top surface of said pairs of electrodes; (c) depositing additional metallic electrode material onto said electrode pairs using electrochemical deposition, thereby decreasing said microgap to a nano sized gap between said electrode pairs; (d) electrochemically polymerizing in said nanogap conductive monomers containing a target analyte, thereby forming a conducting polymer nanojunction in the gap between electrode pairs; and (e) immersing resultant sensor device in a solution which removes away the target analyte, and intermittently applying a voltage to the conducting polymer while it is immersed in said solution, thereby swelling and shrinking the conducting polymer to effect a more efficient extraction of target analyte from the conducting polymer.

    摘要翻译： 提供了一种分子识别传感器系统，其包括通过以下工艺步骤形成的分子印迹纳米传感器装置：（a）使用光刻法将由微细间隙分隔的一对金属电极制造到形成在基底上的第一电绝缘层上; （b）在所述电极对的大部分顶表面上施加第二电绝缘层; （c）使用电化学沉积将额外的金属电极材料沉积到所述电极对上，从而将所述微隙减小到所述电极对之间的纳米尺寸的间隙; （d）在含有目标分析物的纳米孔导电单体中进行电化学聚合，从而在电极对之间的间隙中形成导电聚合物纳米结; 和（e）将得到的传感器装置浸入去除目标分析物的溶液中，并且在浸入所述溶液中时间歇地向导电聚合物施加电压，从而使导电聚合物膨胀和收缩以实现目标的更有效的提取 来自导电聚合物的分析物。

    Molecular Imprinted Nanosensors And Process For Producing Same
    2.
    发明申请
    Molecular Imprinted Nanosensors And Process For Producing Same 有权
    分子印迹纳米传感器及其生产方法

    公开(公告)号：US20110024302A1

    公开(公告)日：2011-02-03

    申请号：US12510414

    申请日：2009-07-28

    申请人： Xiulan Li ,  Ranganathan Shashidhar ,  Yufeng Ma

    发明人： Xiulan Li ,  Ranganathan Shashidhar ,  Yufeng Ma

    IPC分类号： C25D5/48 ,  G01N27/26 ,  C25D5/34

    CPC分类号： G01N27/327 ,  C25D13/04 ,  G01N27/128

    摘要： A molecular recognition sensor system is provided incorporating a molecular imprinted nanosensor device formed by the process steps of: (a) fabricating using photolithography a pair of metallic electrodes separated by a microscale gap onto a first electrical insulation layer formed on a substrate; (b) applying a second electrical insulation layer on most of a top surface of said pairs of electrodes; (c) depositing additional metallic electrode material onto said electrode pairs using electrochemical deposition, thereby decreasing said microgap to a nano sized gap between said electrode pairs; (d) electrochemically polymerizing in said nanogap conductive monomers containing a target analyte, thereby forming a conducting polymer nanojunction in the gap between electrode pairs; and (e) immersing resultant sensor device in a solution which removes away the target analyte, and intermittently applying a voltage to the conducting polymer while it is immersed in said solution, thereby swelling and shrinking the conducting polymer to effect a more efficient extraction of target analyte from the conducting polymer.

    摘要翻译： 提供了一种分子识别传感器系统，其包括通过以下工艺步骤形成的分子印迹纳米传感器装置：（a）使用光刻法将由微细间隙分隔的一对金属电极制造到形成在基底上的第一电绝缘层上; （b）在所述电极对的大部分顶表面上施加第二电绝缘层; （c）使用电化学沉积将额外的金属电极材料沉积到所述电极对上，从而将所述微隙减小到所述电极对之间的纳米尺寸的间隙; （d）在含有目标分析物的纳米孔导电单体中进行电化学聚合，从而在电极对之间的间隙中形成导电聚合物纳米结; 和（e）将得到的传感器装置浸入去除目标分析物的溶液中，并且在浸入所述溶液中时间歇地向导电聚合物施加电压，从而使导电聚合物膨胀和收缩以实现目标的更有效的提取 来自导电聚合物的分析物。

    Conducting polymer nanosensor
    5.
    发明申请
    Conducting polymer nanosensor 审中-公开
    导电聚合物纳米传感器

    公开(公告)号：US20070235348A1

    公开(公告)日：2007-10-11

    申请号：US11399834

    申请日：2006-04-07

    申请人： Larry Nagahara ,  Islamshah Amlani ,  Alvaro Aguilar ,  Erica Forzani ,  Xiulan Li ,  Nongjian Tao

    发明人： Larry Nagahara ,  Islamshah Amlani ,  Alvaro Aguilar ,  Erica Forzani ,  Xiulan Li ,  Nongjian Tao

    IPC分类号： G01F1/64 ,  G01N33/487

    CPC分类号： G01N33/5438

    摘要： A method is provided for forming a thin film conducting polymer (24) for sensor applications. The method comprises forming at least one pair of electrodes (14, 16) on a substrate (12), the pair of electrodes (14, 16) having an insulating layer (18) positioned therebetween, the insulating layer (18) having a surface (20) opposed to the substrate (12), increasing OH− groups on the surface (20), binding silane molecules (22) to the surface (20), and forming the conducting polymer material (24) on the silane molecules (22) between and in electrical contact with the electrodes (14, 16).

    摘要翻译： 提供了一种用于形成用于传感器应用的薄膜导电聚合物（24）的方法。 该方法包括在衬底（12）上形成至少一对电极（14,16），所述一对电极（14,16）具有位于其间的绝缘层（18），所述绝缘层（18）具有表面 （20），与基底（12）相对，增加表面（20）上的OH基团，将硅烷分子（22）结合到表面（20），并形成导电聚合物材料（24） ）在与电极（14,16）电接触的硅烷分子（22）上。