Inorganic nano sheet-enabled lithium-exchanging surface-mediated cells
    3.
    发明授权
    Inorganic nano sheet-enabled lithium-exchanging surface-mediated cells 有权
    无机纳米片锂交换表面介导的细胞

    公开(公告)号:US08790814B2

    公开(公告)日:2014-07-29

    申请号:US13385366

    申请日:2012-02-16

    IPC分类号: H01M10/05

    摘要: An inorganic material based surface-mediated cell (SMC) comprising (a) a cathode comprising a non-carbon-based inorganic cathode active material having a surface area to capture and store lithium thereon; (b) an anode comprising an anode current collector alone or both an anode current collector and an anode active material; (c) a porous separator; (d) a lithium-containing electrolyte in physical contact with the two electrodes, wherein the cathode has a specific surface area no less than 100 m2/g which is in direct physical contact with said electrolyte to receive lithium ions therefrom or to provide lithium ions thereto; and (e) a lithium source. This inorganic SMC provides both high energy density and high power density not achievable by supercapacitors and lithium-ion cells.

    摘要翻译: 一种基于无机材料的表面介质电池(SMC),其包含(a)阴极,其包含具有在其上捕获和存储锂的表面积的非碳基无机阴极活性材料; (b)阳极,其包含单独的阳极集电器和阳极活性材料; (c)多孔分离器; (d)与两个电极物理接触的含锂电解质,其中所述阴极具有不小于100m 2 / g的比表面积,其与所述电解质直接物理接触以接收锂离子或提供锂离子 到; 和(e)锂源。 该无机SMC提供了超级电容器和锂离子电池不能实现的高能量密度和高功率密度。

    Supercapacitor with a meso-porous nano graphene electrode
    4.
    发明申请
    Supercapacitor with a meso-porous nano graphene electrode 有权
    具有中孔多孔纳米石墨烯电极的超级电容器

    公开(公告)号:US20120026643A1

    公开(公告)日:2012-02-02

    申请号:US12804911

    申请日:2010-08-02

    IPC分类号: H01G9/00

    摘要: A supercapacitor comprising a two electrodes, a porous separator disposed between the two electrodes, and an ionic liquid electrolyte in physical contact with the two electrodes, wherein at least one of the two electrodes comprises a meso-porous structure being formed of a plurality of nano graphene platelets and multiple pores having a pore size in the range of 2 nm and 25 nm, wherein the graphene platelets are not spacer-modified or surface-modified platelets. Preferably, the graphene platelets are curved, not flat-shaped. The pores are accessible to ionic liquid molecules, enabling the formation of large amounts of electric double layer charges in a supercapacitor, which exhibits an exceptionally high specific capacitance and high energy density.

    摘要翻译: 一种超级电容器,包括两个电极,设置在所述两个电极之间的多孔隔离体和与所述两个电极物理接触的离子液体电解质,其中所述两个电极中的至少一个包括由多个纳米颗粒形成的中孔多孔结构 石墨烯血小板和孔径在2nm和25nm范围内的多个孔,其中石墨烯血小板不是间隔子改性的或表面改性的血小板。 优选地,石墨烯片晶是弯曲的,不是平坦的。 离子液体分子可以获得孔隙,使得能够在超级电容器中形成大量的双电层电荷,其表现出非常高的比电容和高能量密度。

    Spacer-modified graphene electrode for supercapacitor
    5.
    发明授权
    Spacer-modified graphene electrode for supercapacitor 有权
    用于超级电容器的间隔改性石墨烯电极

    公开(公告)号:US08947854B2

    公开(公告)日:2015-02-03

    申请号:US13573844

    申请日:2012-10-09

    IPC分类号: H01G9/00 H01G11/36 B82Y30/00

    摘要: A spacer-modified nano graphene platelet electrode, comprising: (a) multiple nano graphene platelets or sheets having an average thickness smaller than 10 nm; and (b) discrete, non-metallic nano-scaled particles that are disposed between two graphene platelets or sheets to serve as a spacer. In such a spacer-modified graphene electrode, large amounts of electrolyte-accessible pores are formed, enabling the formation of large amounts of electric double layer charges in a supercapacitor, which exhibits an exceptionally high specific capacitance.

    摘要翻译: 一种间隔物改性的纳米石墨烯片晶电极,包括:(a)平均厚度小于10nm的多个纳米石墨烯片晶或片; 和(b)分散的非金属纳米级粒子,其设置在两个石墨烯片晶片之间以用作间隔物。 在这种间隔物改性的石墨烯电极中,形成大量的电解质可接近的孔,使得能够在超级电容器中形成大量的双电层电荷,这表现出特别高的比电容。

    Rechargeable lithium cell having a chemically bonded phthalocyanine compound cathode
    7.
    发明申请
    Rechargeable lithium cell having a chemically bonded phthalocyanine compound cathode 有权
    具有化学键合的酞菁化合物阴极的可充电锂电池

    公开(公告)号:US20140072871A1

    公开(公告)日:2014-03-13

    申请号:US13573275

    申请日:2012-09-07

    IPC分类号: H01M4/60 B82Y30/00

    摘要: A rechargeable lithium cell comprising: (a) an anode comprising an anode active material; (b) a cathode comprising a hybrid cathode active material composed of an electrically conductive substrate and a phthalocyanine compound chemically bonded to or immobilized by the conductive substrate, wherein the phthalocyanine compound is in an amount of from 1% to 99% by weight based on the total weight of the conductive substrate and the phthalocyanine compound combined; and (c) electrolyte or a combination of electrolyte and a porous separator, wherein the separator is disposed between the anode and the cathode and the electrolyte is in ionic contact with the anode and the cathode. This secondary cell exhibits a long cycle life, the best cathode specific capacity, and best cell-level specific energy of all rechargeable lithium-ion cells ever reported.

    摘要翻译: 一种可再充电锂电池,包括:(a)包含阳极活性材料的阳极; (b)阴极,其包含由导电性基材和由所述导电性基材化学结合或固定的酞菁化合物构成的混合阴极活性物质,其中,所述酞菁化合物的量为1〜99重量%,基于 导电基体和酞菁化合物的总重量合并; 和(c)电解质或电解质和多孔分离器的组合,其中分离器设置在阳极和阴极之间,并且电解质与阳极和阴极离子接触。 该二次电池显示出所有可再充电锂离子电池的循环寿命长,最佳阴极比容量和最佳电池级比能。

    Rechargeable lithium cell having a chemically bonded phthalocyanine compound cathode
    8.
    发明授权
    Rechargeable lithium cell having a chemically bonded phthalocyanine compound cathode 有权
    具有化学键合的酞菁化合物阴极的可充电锂电池

    公开(公告)号:US09362555B2

    公开(公告)日:2016-06-07

    申请号:US13573275

    申请日:2012-09-07

    摘要: A rechargeable lithium cell comprising: (a) an anode comprising an anode active material; (b) a cathode comprising a hybrid cathode active material composed of an electrically conductive substrate and a phthalocyanine compound chemically bonded to or immobilized by the conductive substrate, wherein the phthalocyanine compound is in an amount of from 1% to 99% by weight based on the total weight of the conductive substrate and the phthalocyanine compound combined; and (c) electrolyte or a combination of electrolyte and a porous separator, wherein the separator is disposed between the anode and the cathode and the electrolyte is in ionic contact with the anode and the cathode. This secondary cell exhibits a long cycle life, the best cathode specific capacity, and best cell-level specific energy of all rechargeable lithium-ion cells ever reported.

    摘要翻译: 一种可再充电锂电池,包括:(a)包含阳极活性材料的阳极; (b)阴极,其包含由导电性基材和由所述导电性基材化学结合或固定的酞菁化合物构成的混合阴极活性物质,其中,所述酞菁化合物的量为1〜99重量%,基于 导电基体和酞菁化合物的总重量合并; 和(c)电解质或电解质和多孔分离器的组合,其中分离器设置在阳极和阴极之间,并且电解质与阳极和阴极离子接触。 该二次电池显示出所有可再充电锂离子电池的循环寿命长,最佳阴极比容量和最佳电池级比能。

    Supercapacitor with a meso-porous nano graphene electrode
    9.
    发明授权
    Supercapacitor with a meso-porous nano graphene electrode 有权
    具有中孔多孔纳米石墨烯电极的超级电容器

    公开(公告)号:US09053870B2

    公开(公告)日:2015-06-09

    申请号:US12804911

    申请日:2010-08-02

    摘要: A supercapacitor comprising a two electrodes, a porous separator disposed between the two electrodes, and an ionic liquid electrolyte in physical contact with the two electrodes, wherein at least one of the two electrodes comprises a meso-porous structure being formed of a plurality of nano graphene platelets and multiple pores having a pore size in the range of 2 nm and 25 nm, wherein the graphene platelets are not spacer-modified or surface-modified platelets. Preferably, the graphene platelets are curved, not flat-shaped. The pores are accessible to ionic liquid molecules, enabling the formation of large amounts of electric double layer charges in a supercapacitor, which exhibits an exceptionally high specific capacitance and high energy density.

    摘要翻译: 一种超级电容器,包括两个电极,设置在所述两个电极之间的多孔隔离体和与所述两个电极物理接触的离子液体电解质,其中所述两个电极中的至少一个包括由多个纳米颗粒形成的中孔多孔结构 石墨烯血小板和孔径在2nm和25nm范围内的多个孔,其中石墨烯血小板不是间隔子改性的或表面改性的血小板。 优选地,石墨烯片晶是弯曲的,不是平坦的。 离子液体分子可以获得孔隙,使得能够在超级电容器中形成大量的双电层电荷,其表现出非常高的比电容和高能量密度。