公开(公告)号：US20180312678A1

公开(公告)日：2018-11-01

申请号：US15769933

申请日：2016-10-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Tamon Aoki ,  Allen M. Sohlo ,  Yuta Suzuki ,  Kai H. Lochhaas ,  Florian D. Jochum ,  Klaus Hintzer ,  Tilman C. Zipplies

IPC: C08L27/18 ,  C08L15/02

CPC classification number: C08L27/18 ,  C08F214/262 ,  C08L15/02 ,  C08L2205/025 ,  C08L2205/04 ,  C08L2207/53 ,  C08K5/34924 ,  C08K5/0025 ,  C08K5/14

Abstract: A composition includes an amorphous fluoropolymer having at least one of: a segment represented by formula I: —CF(Rf)—(CX2)n—(CX2CXR)m—O—R″fOk—(CXR′CX2)p—(CX2)q—CF(R′f)— (I); or a terminal segment represented by formula III: Rf—CF(I)—(CX2)n—(CX2CXR)m—O—R″fOk—(CXR′CX2)p—(CX2)q—CF(R′f)— (III), and fluoroplastic particles having a mean particle size of less than 500 nanometers. Each X is independently F, H, or Cl; Rf and R′f are each independently F or a monovalent perfluoroalkyl having 1 to 3 carbon atoms; R is F or a partially fluorinated or perfluorinated alkyl having 1 to 3 carbon atoms; R″f is a divalent fluoroalkylene having 1 to 8 carbon atoms or a divalent fluorinated alkylene ether having 1 to 20 carbon atoms and at least one ether linkage; k is 0 or 1; and n, m, p, and q are each independently an integer from 0 to 5, with the proviso that when k is 0, n+m is at least 1 and p+q is at least 1. A method of making the composition is also provided.

公开(公告)号：US12116476B2

公开(公告)日：2024-10-15

申请号：US17413053

申请日：2019-12-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Tamon Aoki ,  Tatsuo Fukushi ,  Florian D. Jochum ,  Peter J. Scott ,  Yuta Suzuki ,  Karl D. Weilandt ,  Steffen Vowinkel

IPC: C08L27/18 ,  B29B9/08 ,  C08F214/26 ,  C08F214/28 ,  C08L19/02 ,  C08L27/20 ,  B29K19/00

CPC classification number: C08L27/18 ,  B29B9/08 ,  C08F214/262 ,  C08F214/282 ,  C08L19/02 ,  C08L27/20 ,  B29K2019/00

Abstract: Described herein is a latex blend comprising (i) an amorphous perfluoropolymer and (ii) an aqueous dispersion of semi crystalline fluoropolymer particles, wherein the particles comprise a TFE homopolymer or a TFE copolymer comprising no more than 1 wt % of a second fluorinated monomer, wherein the semi crystalline fluoropolymer particles (a) have an MFI (372° C. with 2.16 kg) of less than 50 g/10 min or (b) are not melt processible and have an SSG of less than 2.190, wherein the semi crystalline fluoropolymer particles have an average diameter greater than 100 nm.

公开(公告)号：US20220073664A1

公开(公告)日：2022-03-10

申请号：US17414280

申请日：2019-12-17

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Tatsuo Fukushi ,  Tamon Aoki ,  Qilin Chan ,  Miguel A. Guerra ,  Klaus Hintzer ,  Florian D. Jochum ,  Michael H. Mitchell ,  Allen M. Sohlo ,  Yuta Suzuki

IPC: C08F214/26

Abstract: The composition includes a curable fluoropolymer having nitrogen-containing cure sites and a curative including an organo onium cation and an anion represented by Formula (I) or Formula (II). The composition is free of metal cations or has not more than 20 parts per million metal cations and free of silicon dioxide or has less than 0.5 percent by weight silicon dioxide, based on the total weight of the composition. In some cases, the composition consists of the curable fluoropolymer and the curative. Shaped articles including the composition, a fluoroelastomer prepared by curing the composition, a method of making a fluoroelastomer article, and a process for making the composition are also described.

公开(公告)号：US10323142B2

公开(公告)日：2019-06-18

申请号：US15573848

申请日：2016-05-05

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Tamon Aoki ,  Tatsuo Fukushi ,  Yuta Suzuki ,  Noriyuki Usami

IPC: C08K3/04 ,  C08K3/22 ,  C08K3/26 ,  C08K3/34 ,  C08K3/36 ,  C08K5/14 ,  C08K5/353 ,  C08L27/12 ,  C08L27/14 ,  C08L27/18 ,  C08L27/20 ,  C08K5/3492

Abstract: Described herein is a curable composition comprising: (a) a perfluoroelastomer gum having a carboxylic acid integrated absorbance ratio of at least 0.015; and (b) a compound comprising at least one oxazole moiety, and cured articles thereof.

公开(公告)号：US20220033635A1

公开(公告)日：2022-02-03

申请号：US17413053

申请日：2019-12-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Tamon Aoki ,  Tatsuo Fukushi ,  Florian D. Jochum ,  Peter J. Scott ,  Yuta Suzuki ,  Karl D. Weilandt ,  Steffen Vowinkel

IPC: C08L27/18 ,  C08L27/20 ,  B29B9/08 ,  C08L19/02 ,  C08F214/26 ,  C08F214/28

Abstract: Described herein is a latex blend comprising (i) an amorphous perfluoropolymer and (ii) an aqueous dispersion of semi crystalline fluoropolymer particles, wherein the particles comprise a TFE homopolymer or a TFE copolymer comprising no more than 1 wt % of a second fluorinated monomer, wherein the semi crystalline fluoropolymer particles (a) have an MFI (372° C. with 2.16 kg) of less than 50 g/10 min or (b) are not melt processible and have an SSG of less than 2.190, wherein the semi crystalline fluoropolymer particles have an average diameter greater than 100 nm.

公开(公告)号：US20220033634A1

公开(公告)日：2022-02-03

申请号：US17279867

申请日：2019-09-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Tamon Aoki ,  Yuta Suzuki

IPC: C08L27/18

Abstract: A curable fluorine-based elastomer composite containing a curable fluorine-based polymer including a curable fluorine-based elastomer including a copolymerization unit having a curing site; a crosslinking agent that reacts with a curing site to form a crosslinking unit in the elastomer; and a crosslinking aid including an organic onium salt, in which the total content of the crosslinking agent and the crosslinking aid is about 0.5 parts by mass or more and about 3 parts by mass or less with reference to 100 parts by mass of the curable fluorine-based polymer, and the ratio between the crosslinking agent and the crosslinking aid is from about 2:8 to about 7:3.

公开(公告)号：US10557031B2

公开(公告)日：2020-02-11

申请号：US15769933

申请日：2016-10-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Tamon Aoki ,  Allen M. Sohlo ,  Yuta Suzuki ,  Kai H. Lochhaas ,  Florian D. Jochum ,  Klaus Hintzer ,  Tilman C. Zipplies

IPC: C08L15/02 ,  C08L27/18

Abstract: A composition includes an amorphous fluoropolymer having at least one of: a segment represented by formula I: —CF(Rf)—(CX2)n—(CX2CXR)m—O—R″fOk—(CXR′CX2)p—(CX2)q—CF(R′f)— (I); or a terminal segment represented by formula III: Rf—CF(I)—(CX2)n—(CX2CXR)m—O—R″fOk—(CXR′CX2)p—(CX2)q—CF(R′f)— (III), and fluoroplastic particles having a mean particle size of less than 500 nanometers. Each X is independently F, H, or Cl; Rf and R′f are each independently F or a monovalent perfluoroalkyl having 1 to 3 carbon atoms; R is F or a partially fluorinated or perfluorinated alkyl having 1 to 3 carbon atoms; R″f is a divalent fluoroalkylene having 1 to 8 carbon atoms or a divalent fluorinated alkylene ether having 1 to 20 carbon atoms and at least one ether linkage; k is 0 or 1; and n, m, p, and q are each independently an integer from 0 to 5, with the proviso that when k is 0, n+m is at least 1 and p+q is at least 1. A method of making the composition is also provided.

公开(公告)号：US20180258271A1

公开(公告)日：2018-09-13

申请号：US15573848

申请日：2016-05-05

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Tamon Aoki ,  Tatsuo Fukushi ,  Yuta Suzuki ,  Noriyuki Usami

IPC: C08L27/20 ,  C08L27/18 ,  C08L27/14 ,  C08K5/14 ,  C08K5/353 ,  C08K5/3492 ,  C08K3/04 ,  C08K3/22 ,  C08K3/26 ,  C08K3/34 ,  C08K3/36

CPC classification number: C08L27/20 ,  C08K3/04 ,  C08K3/22 ,  C08K3/26 ,  C08K3/346 ,  C08K3/36 ,  C08K5/14 ,  C08K5/34924 ,  C08K5/353 ,  C08K2003/2237 ,  C08K2003/265 ,  C08L27/14 ,  C08L27/18 ,  C08L2205/025 ,  C08L27/12

Abstract: Described herein is a curable composition comprising: (a) a perfluoroelastomer gum having a carboxylic acid integrated absorbance ratio of at least 0.015; and (b) a compound comprising at least one oxazole moiety, and cured articles thereof.