Process for preparing aqueous polymer dispersions for adhesives
    1.
    发明授权
    Process for preparing aqueous polymer dispersions for adhesives 有权
    制备胶粘剂水性聚合物分散体的方法

    公开(公告)号:US09574077B2

    公开(公告)日:2017-02-21

    申请号:US14987394

    申请日:2016-01-04

    申请人: BASF SE

    摘要: The present invention relates to aqueous polymer dispersions having a polymer content of at least 55% by weight that are suitable for pressure sensitive adhesives. The invention also relates to a process for preparing these aqueous polymer dispersions and also to the use of the aqueous polymer dispersions in pressure sensitive adhesives and, respectively, pressure sensitive adhesive compositions, especially in pressure sensitive adhesives for transparent substrates, such as plastics labels. The aqueous polymer dispersions have a polymer content of at least 55% by weight, based on the total weight of the dispersion, the polymer being composed of ethylenically unsaturated monomers M and having a glass transition temperature below −10° C., in which the dispersed polymer particles have a polymodal particle size distribution, in which at least 70% by weight have a particle diameter of below 350 nm.

    摘要翻译: 本发明涉及聚合物含量为至少55重量%的聚合物分散体,其适用于压敏粘合剂。 本发明还涉及一种制备这些含水聚合物分散体的方法,还涉及使用压敏粘合剂中的聚合物水分散体和压敏粘合剂组合物,特别是用于透明基材例如塑料标签的压敏粘合剂。 聚合物水分散体的聚合物含量至少为55重量%,基于分散体的总重量,聚合物由烯键式不饱和单体M组成并具有低于-10℃的玻璃化转变温度,其中 分散的聚合物颗粒具有多晶粒度分布,其中至少70重量%的粒径小于350nm。

    Use Of Nonionic Surfactants As Emulsifiers For Emulsion Polymerization (III)
    2.
    发明申请
    Use Of Nonionic Surfactants As Emulsifiers For Emulsion Polymerization (III) 失效
    用作乳液聚合乳化剂的非离子表面活性剂(III)

    公开(公告)号:US20120029131A1

    公开(公告)日:2012-02-02

    申请号:US13259846

    申请日:2010-03-13

    CPC分类号: C08F2/30

    摘要: The invention relates to the use of aqueous solutions of nonionic surfactants as gel phase free emulator systems for the emulsion polymerization, wherein said nonionic surfactants are chosen from the group (a) of the addition products from 1 to 40 mol ethylene and/or propylene oxide per mol of allyl alcohol, and (b) of the addition products from 1 to 40 mol ethylene and/or propylene oxide per mol of allyl alcohol, wherein the OH-group of said addition products is end-capped in the sense that it is substituted by a group OR, wherein R is an alkyl group with 1 to 20 C-atoms, which can be saturated or unsaturated, straight chained or branched.

    摘要翻译: 本发明涉及非离子表面活性剂的水溶液用作乳液聚合的无凝胶相模拟器系统,其中所述非离子表面活性剂选自1-40mol乙烯和/或环氧丙烷加成产物(a)组 每摩尔烯丙醇,和(b)每摩尔烯丙醇1至40摩尔乙烯和/或环氧丙烷的加成产物,其中所述加成产物的OH-基是在上述意义上被封端 被OR取代,其中R是具有1-20个碳原子的烷基,其可以是饱和或不饱和的,直链或支链的。

    Crosslinkable hydroxy terminated polydiene polymer coating compositions
for use on substrates and a process for preparing them
    4.
    发明授权
    Crosslinkable hydroxy terminated polydiene polymer coating compositions for use on substrates and a process for preparing them 失效
    用于底物的可交联羟基封端的聚二烯聚合物涂料组合物及其制备方法

    公开(公告)号:US5750627A

    公开(公告)日:1998-05-12

    申请号:US748291

    申请日:1996-11-13

    摘要: A crosslinkable composition for coating primed and unprimed substrates comprising from 10 to 80 percent by weight of a hydroxy functional polydiene polymer having a functionality of at least 1.3, 8 to 60 percent by weight of an amino resin crosslinking agent, and 2 to 40 percent by weight of a reinforcing agent. The invention also encompasses a process to make such compositions by partially reacting the three components for 0.5 to 10 hours at 60.degree. to 120.degree. C., optionally in the presence of a small amount of catalyst, to give phase stable compositions and subsequently completely crosslinking the composition by baking the composition on a substrate. The invention also encompasses a process for painting a substrate which comprises priming the substrate with a primer selected from the group consisting of epoxy resin primers and polyester resin primers, applying to the primed substrate a crosslinkable basecoat composition comprising from 10 to 80 percent by weight of a hydroxy functional polydiene polymer having a functionality of at least 1.3, from 8 to 60 percent by weight of an amino resin crosslinking agent, and from 2 to 40 percent by weight of a reinforcing agent, and applying over the basecoat a clearcoat selected from the group consisting of dihydroxy polydiene-based clearcoats, polyester clearcoats, and acrylic clearcoats.

    摘要翻译: 一种用于涂覆底漆和未染色底物的可交联组合物,其包含10至80重量%的官能度为至少1.3,8至60重量%的氨基树脂交联剂和2至40重量%的羟基官能聚二烯聚合物, 增强剂的重量。 本发明还包括通过在60℃至120℃,任选地在少量催化剂存在下将三种组分部分地反应0.5至10小时来制备这种组合物的方法,得到相稳定组合物,随后完全交联 该组合物通过在基材上烘烤该组合物。 本发明还包括用于涂布基材的方法,该方法包括用选自环氧树脂底漆和聚酯树脂底漆的底漆引发底物,向底漆基材施加可交联的底涂层组合物,其包含10至80重量% 具有官能度至少为1.3,羟基官能度为8至60重量%的氨基树脂交联剂和2至40重量%的增强剂的羟基官能聚二烯烃聚合物,并在底漆上涂布选自 由二羟基聚二烯系透明涂层,涤纶清漆和丙烯酸清漆组成的组。

    Developing roll
    9.
    发明授权

    公开(公告)号:US10394161B2

    公开(公告)日:2019-08-27

    申请号:US16246557

    申请日:2019-01-14

    摘要: Provided is a developing roll (R) with which it is possible to suppress toner stress in a low-temperature and low-humidity environment. A developing roll (R) for an electrophotographic device has a surface layer (1). In a surface hardness histogram (10) of the surface layer (1) measured by using an atomic force microscope (AFM), the surface hardness (H) at the top peak (P) is in the range of 10-55 MPa, and the area ratio (S) of the histogram portion corresponding to a surface hardness of 45 MPa or below in relation to the entire histogram is 65% or above.