公开(公告)号：US12240993B2

公开(公告)日：2025-03-04

申请号：US17655671

申请日：2022-03-21

Applicant: AGC Inc.

Inventor： Yusuke Tomiyori ,  Motoshi Aoyama ,  Kenji Ishizeki

IPC: C09D5/00 ,  C03C17/42 ,  C08G77/26 ,  C09D1/02 ,  C09D183/08 ,  C23C14/12 ,  C23C14/24

Abstract: To provide an article with a water and oil repellent layer, which is excellent in friction resistance.
The article with a water and oil repellent layer of the present invention comprises a substrate, a water and oil repellent layer consisting of a hydrolyzed condensation product of a compound represented by the formula [A-(OX)m-]jY1[—Si(R)nL3-n]g, and a silicon oxide layer containing alkali metal atoms that exists between the substrate and the water and oil repellent layer, wherein the average value of the concentration of alkali metal atoms in a predetermined area in the silicon oxide layer is at least a predetermined value. In the formula, X is a fluoroalkylene group, m is at least 2, j, g, and k are at least 1, and Y1 and Y2 are linking groups, R is a monovalent hydrocarbon group, L is a hydrolyzable group or hydroxy group, n is 0 to 2, A is a perfluoroalkyl group or —Y2[—Si(R)nL3-n]n. When A is —Y2[—Si(R)nL3-n]k, j is 1, and when A is a perfluoroalkyl group and j is 1, g is at least 2.

公开(公告)号：US12264257B2

公开(公告)日：2025-04-01

申请号：US17443038

申请日：2021-07-20

Applicant: AGC Inc.

Inventor： Keigo Matsuura ,  Taiki Hoshino ,  Kiyotaka Takao ,  Makoto Uno ,  Eiichiro Anraku ,  Motoshi Aoyama ,  Naoki Katsuki ,  Yusuke Tomiyori ,  Toyokazu Enta ,  Hiromasa Yamamoto

IPC: C09D183/10 ,  C09D5/00 ,  C09D7/20 ,  C09D183/12

Abstract: The composition containing a compound represented by the formula (1) and a compound represented by the formula (2), Rf1—(OX1)m1—O—Rf2—Y1—[Si(R1)n1L13-n1]g1  (1) [L23-n2(R2)n2Si]g2—Y2—Rf3—(OX2)m2—O—Rf4—Y3—[Si(R3)n3L33-n3]g3  (2), where Rf1 to Rf4, X1 to X2, Y1 to Y3, R1 to R3, L1 to L3, m1 to m2, n1 to n3, and g1 to g3 are as defined in the disclosure. An article, containing a substrate and a surface layer formed of the composition on the substrate.

公开(公告)号：US11066517B2

公开(公告)日：2021-07-20

申请号：US16282406

申请日：2019-02-22

Applicant: AGC Inc.

Inventor： Taiki Hoshino ,  Motoshi Aoyama ,  Kiyotaka Takao

IPC: C08G65/336 ,  C08G65/337 ,  C08G65/333 ,  C08G65/00 ,  C09D5/00 ,  C09D171/02

Abstract: Processes for producing a fluorinated ether compound are provided by which fluorinated ether compound capable of imparting excellent water/oil repellency, to a substrate surface or a hard coat layer can be easily produced in high yield. A process comprising reacting Rf(CF2)a—CF2OC(═O)Rf4 or Rf(CF2)a—C(═O)X1 with HN(—R1CH═CH2)2 to obtain Rf(CF2)a—C(═O)N(—R1CH2═CH2)2 and a process comprising obtaining the above product and reacting the product with HSiR2nL3-n to obtain Rf(CF2)a—C(═O)N(—R1CH2CH2SiR2nL3-n)2 wherein Rf is a linear polyfluoroalkyl group having at least two carbon atoms and at least one etheric oxygen atom between carbon atoms, Rf4 is a C1-30 perfluoroalkyl group or the like, X1 is a halogen atom, R1 is an alkylene group, a is an integer of from 1 to 5, R2 is a monovalent hydrocarbon group, L is a hydrolyzable group, and n is an integer of from 0 to 2.

公开(公告)号：US11926756B2

公开(公告)日：2024-03-12

申请号：US17305605

申请日：2021-07-12

Applicant: AGC Inc.

Inventor： Motoshi Aoyama

IPC: C09D171/00 ,  C07F7/18 ,  C08G65/336 ,  C09D5/00

CPC classification number: C09D171/00 ,  C07F7/1804 ,  C08G65/336 ,  C09D5/00

Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid excellent in chemical resistance, an article having a surface layer excellent in chemical resistance and a method for producing it, and a method for producing a fluorinated ether compound excellent in chemical resistance.
A fluorinated ether compound which has a first partial structure represented by the following formula (1) and a second partial structure represented by the following formula (2), and



which has at least five first partial structures, or has at least two second partial structures:

—ORf12—  (1)

—ORf13—  (2)

wherein Rf12 is a C1-6 fluoroalkylene group, and

Rf13 is a group having a fluorinated cyclic structure which may have a hetero atom.

公开(公告)号：US20200157376A1

公开(公告)日：2020-05-21

申请号：US16774152

申请日：2020-01-28

Applicant: AGC Inc.

Inventor： Taiki HOSHINO ,  Keigo Matsuura ,  Eiichiro Anraku ,  Masahiro Ito ,  Hiromasa Yamamoto ,  Motoshi Aoyama ,  Yusuke Tomiyori ,  Yutaka Furukawa

IPC: C09D171/02 ,  C08G65/337 ,  C09D5/00 ,  C08G65/336

Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid capable of forming a surface layer excellent in initial water/oil repellency, fingerprint stain removability, abrasion resistance, light resistance and chemical resistance, an article having a surface layer, and a method for producing it.A fluorinated ether compound represented by A-O—(Rf1O)m—Rf2—Z1-Q1 (R1)b, wherein A is a C1-20 perfluoroalkyl group, Rf1 is a linear fluoroalkylene group, m is an integer of from 2 to 500, Rf2 is a linear fluoroalkylene group, Z1 is a single bond, —(CR2R3)c— (wherein R2 and R3 are a hydrogen atom, a C1-6 monovalent organic group or the like, and c is an integer of from 1 to 10), a specific bond or a bivalent organic group having a specific bond, Q1 is a group having a (b+1) valent ring, R1 is a monovalent organic group having at least one hydrolyzable silyl group, and b is an integer of at least 2.

公开(公告)号：US11542407B2

公开(公告)日：2023-01-03

申请号：US16774152

申请日：2020-01-28

Applicant: AGC Inc.

Inventor： Taiki Hoshino ,  Keigo Matsuura ,  Eiichiro Anraku ,  Masahiro Ito ,  Hiromasa Yamamoto ,  Motoshi Aoyama ,  Yusuke Tomiyori ,  Yutaka Furukawa

IPC: C09D5/00 ,  C09D171/02 ,  C08G65/336 ,  C08G65/337

Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid capable of forming a surface layer excellent in initial water/oil repellency, fingerprint stain removability, abrasion resistance, light resistance and chemical resistance, an article having a surface layer, and a method for producing it.
A fluorinated ether compound represented by A-O—(Rf1O)m—Rf2-Z1-Q1 (R1)b, wherein A is a C1-20 perfluoroalkyl group, Rf1 is a linear fluoroalkylene group, m is an integer of from 2 to 500, Rf2 is a linear fluoroalkylene group, Z1 is a single bond, —(CR2R3)c— (wherein R2 and R3 are a hydrogen atom, a C1-6 monovalent organic group or the like, and c is an integer of from 1 to 10), a specific bond or a bivalent organic group having a specific bond, Q1 is a group having a (b+1) valent ring, R1 is a monovalent organic group having at least one hydrolyzable silyl group, and b is an integer of at least 2.