Photocurable compositions having variable viscosities

    公开(公告)号:US12258449B2

    公开(公告)日:2025-03-25

    申请号:US17610738

    申请日:2020-05-15

    Abstract: Photocurable compositions comprising 20-90% by weight of a polymerizable core resin; 20-90% by weight of a diluent resin miscible with said core resin; and at least about 1% by weight of at least one rheology modifier which is distinct from said diluent resin. Rheology modifiers of the present disclosure include compounds which may form covalent bonds with the core resin or diluent resin and compounds which have a particle size of 1-200 nm. Rheology modifiers which may form covalent bonds have at least one terminal functional group selected from the group consisting of acrylates, methacrylates, epoxides, oxetanes, nitriles, alkenes and alkynes.

    PHOTOCURABLE COMPOSITIONS HAVING VARIABLE VISCOSITIES

    公开(公告)号:US20220267529A1

    公开(公告)日:2022-08-25

    申请号:US17610738

    申请日:2020-05-15

    Abstract: Photocurable compositions comprising 20-90% by weight of a polymerizable core resin; 20-90% by weight of a diluent resin miscible with said core resin; and at least about 1% by weight of at least one rheology modifier which is distinct from said diluent resin. Rheology modifiers of the present disclosure include compounds which may form covalent bonds with the core resin or diluent resin and compounds which have a particle size of 1-200 nm. Rheology modifiers which may form covalent bonds have at least one terminal functional group selected from the group consisting of acrylates, methacrylates, epoxides, oxetanes, nitriles, alkenes and alkynes.

    Photoinitiators functioned as both initiators and nanofillers

    公开(公告)号:US10711019B2

    公开(公告)日:2020-07-14

    申请号:US15752866

    申请日:2016-08-17

    Abstract: This invention relates to a photoinitiator compound comprising: a polyhedral oligomeric silsesquioxane (POSS) moiety and a photoinitiator moiety, wherein the photoinitiator compound having the structure according to formula (I): [R—SiO1.5]n (I), wherein n is 6, 8, 10 or 12 and R is independently selected from the group consisting of H, linear or branched (hetero)alkyl, linear or branched (hetero)alkenyl, (hetero)aryl, (hetero)alkyl aryl, (hetero)aryl alkyl and a photoinitiator moiety, wherein at least one R is a photoinitiator moiety and the photoinitiator compound is a nanoparticle. The present invention also relates to a method for the production of the photoinitiator compound of the invention, a photopolymerizable composition comprising the photoinitiator compound of the invention, the use of the photoinitiator compound of the invention for photopolymerization. The present invention is further related to a coated substrate comprising the photopolymerizable composition of the invention.

    RESIN FORMULATION AND USES THEREOF
    4.
    发明申请

    公开(公告)号:US20180273657A1

    公开(公告)日:2018-09-27

    申请号:US15916133

    申请日:2018-03-08

    Abstract: There is provided a resin formulation comprising a base acrylate monomer or oligomer, a solubilizing acrylate monomer or oligomer, a photoinitiator compound, a photoabsorber compound, and a photochromic dye, wherein the solubilizing acrylate monomer or oligomer comprises a functional group selected from the group consisting of hydroxyl, alkoxyl, carboxylic acid, amine, alkylamine, amide, alkylamide, alkylacrylate, acrylate, alkyl and heterocycloalkyl. There is also provided a method of preparing the resin formulation and uses of the resin formulation thereof.

    PHOTOINITIATORS FUNCTIONED AS BOTH INITIATORS AND NANOFILLERS

    公开(公告)号:US20180222929A1

    公开(公告)日:2018-08-09

    申请号:US15752866

    申请日:2016-08-17

    Abstract: This invention relates to a photoinitiator compound comprising: a polyhedral oligomeric silsesquioxane (POSS) moiety and a photoinitiator moiety, wherein the photoinitiator compound having the structure according to formula (I): [R—SiO1.5]n (I), wherein n is 6, 8, 10 or 12 and R is independently selected from the group consisting of H, linear or branched (hetero)alkyl, linear or branched (hetero)alkenyl, (hetero)aryl, (hetero)alkyl aryl, (hetero)aryl alkyl and a photoinitiator moiety, wherein at least one R is a photoinitiator moiety and the photoinitiator compound is a nanoparticle. The present invention also relates to a method for the production of the photoinitiator compound of the invention, a photopolymerizable composition comprising the photoinitiator compound of the invention, the use of the photoinitiator compound of the invention for photopolymerization. The present invention is further related to a coated substrate comprising the photopolymerizable composition of the invention.

    A THREE-DIMENSIONAL PRINTING METHOD

    公开(公告)号:US20220219385A1

    公开(公告)日:2022-07-14

    申请号:US17610729

    申请日:2020-04-30

    Inventor: Fuke Wang Fei Wang

    Abstract: A method of three-dimensional printing an object having a varying degree of transmissivity to light along an axis of the object, the method comprising the steps of (a) providing a liquefied polymer resin having a plurality of particles therein, the particles being distributed in the liquefied polymer resin based on the density of the particles; and (b) polymerizing the liquefied polymer resin under conditions to form the object layer-by-layer. There is also provided a formulation for three-dimensional printing and a three-dimensional printed object.

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