FREE-STANDING MOF-DERIVED HYBRID POROUS CARBON NANOFIBER MATS

    公开(公告)号:US20190020028A1

    公开(公告)日:2019-01-17

    申请号:US16069707

    申请日:2017-01-16

    Abstract: According to the present disclosure, a method of fabricating a metal-carbon fibrous structure is provided. The method comprises the steps of: (a) forming a fibrous support structure comprising composite nanocrystals and polymeric fibers, wherein each of the composite nanocrystals comprises metal ions connected by organic ligands; (b) growing the composite nanocrystals on the fibrous support structure; and (c) subjecting the fibrous support structure of step (b) to carbonization to form the metal-carbon fibrous structure, wherein the metal-carbon fibrous structure comprises metal nanoparticles derived from the composite nanocrystals comprising metal organic framework (MOF), particularly zeolitic imidazolate framework (ZIF). A metal-carbon fibrous structure comprising carbon based fibers arranged to form a porous network and the carbon based fibers are doped with metal nanoparticles, wherein the carbon based fibers have surfaces which comprise graphitic carbon, is also disclosed herein.

    Free-standing porous carbon fibrous mats and applications thereof

    公开(公告)号:US11590476B2

    公开(公告)日:2023-02-28

    申请号:US16994216

    申请日:2020-08-14

    Inventor: Xu Li Suxi Wang

    Abstract: A method of producing a porous carbon composite fibrous mats formed of a network of carbon fibers incorporated with porous carbon particles. The method includes electrospinning a polymer solution to form a porous layer of polymeric fibers and the polymeric fibers are doped with a precursor of conductive metal particles, wherein the polymer solution includes a polymer and the precursor of the conductive metal particles, electrospraying a metal organic framework suspension onto the porous layer of polymeric fibers, wherein the metal organic framework suspension includes metal organic framework particles, repeating the electrospinning and electrospraying in an alternating manner to form a porous network of polymeric fibers incorporated with the metal organic framework particles, and heating the porous network of polymeric fibers incorporated with the metal organic framework particles to form the porous carbon composite fibrous mats. The porous carbon composite fibrous mats and its applications thereof are also disclosed herein.

    FREE-STANDING MOF-DERIVED HYBRID POROUS CARBON NANOFIBER MATS

    公开(公告)号:US20210296648A1

    公开(公告)日:2021-09-23

    申请号:US17223347

    申请日:2021-04-06

    Abstract: According to the present disclosure, a method of fabricating a metal-carbon fibrous structure is provided. The method comprises the steps of: (a) forming a fibrous support structure comprising composite nanocrystals and polymeric fibers, wherein each of the composite nanocrystals comprises metal ions connected by organic ligands; (b) growing the composite nanocrystals on the fibrous support structure; and (c) subjecting the fibrous support structure of step (b) to carbonization to form the metal-carbon fibrous structure, wherein the metal-carbon fibrous structure comprises metal nanoparticles derived from the composite nanocrystals. A metal-carbon fibrous structure comprising carbon based fibers arranged to form a porous network and the carbon based fibers are doped with metal nanoparticles, wherein the carbon based fibers have surfaces which comprise graphitic carbon, is also disclosed herein.

    Thermal control system
    10.
    发明授权

    公开(公告)号:US11320212B2

    公开(公告)日:2022-05-03

    申请号:US16980946

    申请日:2019-03-15

    Abstract: A thermal control system with new phase change material (PCM) formulations that are able to maintain the system interior in a temperature range of, for example, −15 to −40° C., for a tunable working period from several hours to approximately half a day, is provided. The composition includes the inorganic and organic materials. The inorganic materials include the inorganic salts and various functional additives; while the organic materials include fatty acids, hydrocarbons and various nanostructures.

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