公开(公告)号：US20040043895A1

公开(公告)日：2004-03-04

申请号：US10642933

申请日：2003-08-18

Applicant: AGFA-GEVAERT

Inventor： Frank Louwet ,  Geert Van Dyck ,  Johan Loccufier ,  Bert Groenendaal ,  Hieronymus Andriessen

IPC: B01J031/00

CPC classification number: C08G61/126 ,  C08L25/08 ,  C08L2666/06 ,  C09J165/00 ,  H01G11/48 ,  H01G11/56 ,  Y02E60/13 ,  Y10S428/917

Abstract: A layer configuration on a support, the layer configuration comprising a layer containing a polymer containing optionally substituted 3,4-alkylenedioxythiophene structural units, in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, and a compound selected from the group consisting of polyphosphoric acids, polyphosphoric acid salts, thia-alkanedicarboxylic acids, cyclohexadiene compounds and polyhydroxy-compounds selected from the group consisting of tetronic acid derivatives; ortho-dihydroxybenzene compounds with at least one sulpho group, compounds according to formula (I): HOnullCH2nullCH(OH)null(CH2)mnullSnullCH2nullC(R1)(R2)nullCH2nullSnull(CH2)nnullCH(OH)nullCH2nullOH nullnull(I) wherein R1 and R2 are independently H, nullOH or alkyl, and n and m are independently 1, 2 or 3; compounds according to formula (II): HOnull(CH2)pnullSnullCH2nullSnull(CH2)qnullOH nullnull(II) wherein p and q are independently 2, 3 or 4; compounds hydrolyzable to tetronic acid derivatives; compounds hydrolyzable to compounds according to formula (I); and sulpho-substituted 2-thia-alkyl-benzimidazole compounds.

Abstract translation: 在支撑体上的层构型，该层构型包括含有含有任选取代的3,4-亚烷基二氧噻吩结构单元的聚合物的层，其中两个烷氧基可以相同或不同，或一起代表任选取代的氧基 - 桥，以及选自多磷酸，多磷酸盐，硫杂烷二羧酸，环己二烯化合物和选自由以下组成的组的多羟基化合物的化合物：四氢酸衍生物; 具有至少一个磺基的邻二羟基苯化合物，式（I）化合物：HO-CH 2 -CH（OH） - （CH 2）m S-CH 2 -C（R 1）（R 2）-CH 2 -S-（CH 2）n -CH（OH）-CH 2 -OH（I）其中R 1和R 2独立地为H，-OH或烷基，n和m独立地为1,2或3; 根据式（II）的化合物：HO-（CH 2）p -S-CH 2 -S-（CH 2）q -OH（II）其中p和q独立地为2,3或4; 可水解成四氢酸衍生物的化合物; 可水解成根据式（I）的化合物的化合物的化合物; 和磺基取代的2-硫代 - 烷基 - 苯并咪唑化合物。

公开(公告)号：US20030215571A1

公开(公告)日：2003-11-20

申请号：US10309879

申请日：2002-12-04

Applicant: AGFA-GEVAERT

Inventor： Jean-Pierre Tahon ,  Roger Van den Bogaert ,  Bert Groenendaal ,  Frank Louwet

IPC: B05D005/00

CPC classification number: C08G61/126 ,  C08G2261/122 ,  C08G2261/1424 ,  C08G2261/1426 ,  C08G2261/1452 ,  C08G2261/3223 ,  C08G2261/43 ,  C08G2261/51 ,  C08G2261/794 ,  C09D165/00 ,  H01G9/028 ,  H01G11/48 ,  Y02E60/13 ,  Y10T428/31533 ,  C08L25/18

Abstract: A method for preparing a composition containing between 0.08 and 3.0% by weight of polymer or copolymer of a 3,4-dialkoxythiophene in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, a polyanion and at least one non-aqueous solvent from a dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion in water which is prepared in the substantial absence of oxygen, comprising in the following order the steps of: i) mixing at least one of the non-aqueous solvents with the aqueous dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion; and ii) evaporating water from the mixture prepared in step i) until the content of water therein is reduced by at least 65% by weight; a printing ink, printing paste or coating composition, capable of yielding layers with enhanced conductivity at a given transparency, prepared according to the above-described method; a coating process with the coating composition thereby producing a layer with enhanced conductivity at a given transparency; and a printing process with the printing ink or paste thereby producing a layer with enhanced conductivity at a given transparency.

Abstract translation: 一种制备含有0.08至3.0重量％的3,4-二烷氧基噻吩的聚合物或共聚物的组合物的方法，其中两个烷氧基可以相同或不同，或一起代表任选取代的氧 - 亚烷基 - 氧桥， 聚阴离子和至少一种非水溶剂，其由（3,4-二烷氧基噻吩）的聚合物或共聚物和聚阴离子在水中的分散体组成，其在基本上不存在氧的情况下制备，包括以下步骤： i）将至少一种非水溶剂与（3,4-二烷氧基噻吩）和聚阴离子的聚合物或共聚物的水分散体混合; 和ii）从步骤i）中制备的混合物蒸发水，直到其中的水含量降低至少65重量％; 印刷油墨，印刷浆料或涂料组合物，其能够产生根据上述方法制备的在给定透明度下具有增强的导电性的层; 所述涂料组合物由此在给定的透明度下产生具有增强的导电性的层; 以及具有印刷油墨或糊料的印刷方法，从而在给定的透明度下产生具有增强的导电性的层。

公开(公告)号：US20040126719A1

公开(公告)日：2004-07-01

申请号：US10737552

申请日：2003-12-16

Applicant: AGFA-GEVAERT

Inventor： Ingrid Geuens ,  Frank Louwet ,  Peter Michiels

IPC: G03C001/498 ,  G03C001/76

CPC classification number: G03C1/4989 ,  G03C1/49827 ,  G03C1/49872 ,  G03C2001/7635 ,  G03C2200/35 ,  G03C2200/47 ,  Y10S430/162 ,  Y10S430/165 ,  Y10S430/166

Abstract: A substantially light-insensitive black and white monosheet thermographic recording material has a support and on one side of the support comprises a thermosensitive element, a barrier layer and an outermost protective layer, the thermosensitive element being exclusive of a high contrast agent and containing at least one substantially light-insensitive silver salt of a carboxylic acid, at least one reducing agent therefor in thermal working relationship therewith, at least one toning agent and at least one binder, wherein the at least one reducing agent is an ortho-dihydroxy-benzene derivative and the barrier layer comprises a copolymer comprising vinyl chloride units and vinyl acetate and/or vinyl alcohol units, a copolymer comprising styrene units and acrylonitrile units, a copolymer comprising cationic units and/or a copolymer comprising styrene units and maleic acid units.

Abstract translation: 基本上不透光的黑色和白色单片热成像记录材料具有支撑体，并且在支撑体的一侧包括热敏元件，阻挡层和最外面的保护层，热敏元件不包括高造影剂并至少包含 一种基本上不光敏的羧酸银盐，至少一种与其热处理关系的还原剂，至少一种调色剂和至少一种粘合剂，其中至少一种还原剂是邻二羟基苯衍生物 并且阻挡层包括含有氯乙烯单元和乙酸乙烯酯和/或乙烯醇单元的共聚物，包含苯乙烯单元和丙烯腈单元的共聚物，包含阳离子单元的共聚物和/或包含苯乙烯单元和马来酸单元的共聚物。

公开(公告)号：US20030055130A1

公开(公告)日：2003-03-20

申请号：US10104266

申请日：2002-03-22

Applicant: AGFA-GEVAERT

Inventor： Lambertus Groenendaal ,  Frank Louwet ,  Gianni Zotti

IPC: C08G075/00 ,  C07D495/02

CPC classification number: C07D495/04 ,  C08G61/126 ,  H01G11/48 ,  H01G11/56 ,  Y02E60/13

Abstract: A thiophene compound represented by formula (I): 1 in which: A represents a C2-C5 alkylene bridge; R represents a stereoselectively substituted, linear or branched C2-C24 alkyl, C3-C18 cycloalkyl, C1-C18 alkoxy or polyethyleneoxide group, optionally substituted with at least one substituent selected from the group consisting of an alcohol, amide, ether, ester or sulfonate group; or an optionally substituted aryl group having at least one chiral centre substituted at said C2-C5 alkylene bridge; polymers derived therefrom; a process for polymerizing a thiophene according to formula (I), optionally chemically or electrochemically; and dispersions, pastes and layers containing polymers derived therefrom.

Abstract translation: 由式（I）表示的噻吩化合物：其中：A表示C2-C5亚烷基桥; R表示立体选择性取代的直链或支链C 2 -C 24烷基，C 3 -C 18环烷基，C 1 -C 18烷氧基或聚环氧乙烷基团，任选被至少一个选自醇，酰胺，醚，酯或磺酸盐的取代基取代 组; 或在所述C 2 -C 5亚烷基桥上具有至少一个手性中心取代的任选取代的芳基; 衍生自其的聚合物; 根据式（I）聚合噻吩的方法，任选化学或电化学方法; 以及含有由其衍生的聚合物的分散体，糊剂和层。

公开(公告)号：US20040097741A1

公开(公告)日：2004-05-20

申请号：US10649761

申请日：2003-08-27

Applicant: AGFA-GEVAERT

Inventor： Bert Groenendaal ,  Frank Louwet ,  Hieronymus Andriessen

IPC: C07D495/02 ,  C08G075/32

CPC classification number: C07D495/04 ,  C08G61/126 ,  H01G11/48 ,  Y02E60/13

Abstract: A 3,4-alkylenedioxythiophenedioxide compound represented by formula 1 in which: A represents a C1-5-alkylene bridge; R represents an optionally substituted C1-24-alkyl, C3-18-cycloalkyl, C1-18-alkoxy or polyethylene oxide group (optionally with at least one substituent selected from the group consisting of an alcohol, amide, ether, ester or sulphonate group) or an optionally substituted aryl group; a polymer comprising monomeric units represented by formula (I); an aqueous dispersion of a polymer comprising monomeric units corresponding to at least one compound according to formula (I) and a polyanion; a chemical polymerization process for preparing the aqueous dispersion comprising the steps of: (i) providing a solution of a polyanion; (ii) adding a compound according to formula (I) and a thiophene or pyrrole compound to the solution provided in step (i); and (iii) adding an oxidizing or reducing system to the mixture provided in step (ii); a printable paste containing the aqueous dispersion; an electroconductive layer containing the polymer; the use of the electroconductive layer in a light emitting diode; an antistatic layer containing the polymer; and an electroconductive pattern and a process for preparing the electroconductive pattern.

Abstract translation: 由式表示的3,4-亚烷基二氧基噻吩二氧化物化合物，其中：A表示C1-5亚烷基桥; R表示任选取代的C 1-24 - 烷基，C 3-8 - 环烷基，C 1-18 - 烷氧基或聚环氧乙烷基团（任选具有至少一个选自醇，酰胺，醚，酯或磺酸酯基团的取代基 ）或任选取代的芳基; 包含由式（I）表示的单体单元的聚合物; 包含对应于至少一种根据式（I）的化合物和聚阴离子的单体单元的聚合物的水分散体; 用于制备水分散体的化学聚合方法，包括以下步骤：（i）提供聚阴离子的溶液; （ii）将式（I）化合物和噻吩或吡咯化合物加入到步骤（i）中提供的溶液中; 和（iii）向步骤（ii）中提供的混合物中加入氧化或还原体系; 含有水分散体的可印刷浆料; 含有聚合物的导电层; 在发光二极管中使用导电层; 含有聚合物的抗静电层; 导电图案和制备导电图案的方法。

公开(公告)号：US20030149171A1

公开(公告)日：2003-08-07

申请号：US10321888

申请日：2002-12-17

Applicant: AGFA-GEVAERT

Inventor： Bert Groenendaal ,  Frank Louwet

IPC: C08K003/00

CPC classification number: C08G61/126 ,  C09D165/00

Abstract: An aqueous dispersion of a copolymer of at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25null C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25null C. of at least 2.2 g/L and a polyanion; a preparation process therefor; its use for coating; a printing ink containing the aqueous dispersion; an electro-conductive layer containing a copolymer of at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25null C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25null C. of at least 2.2 g/L and a polyanion derived from an aqueous dispersion thereof; and an antistatic layer containing a copolymer of at least one 3,4-alkylenedioxy-thiophene compound with a solubility in water at 25null C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25null C. of at least 2.2 g/L and a polyanion derived from an aqueous dispersion thereof.

Abstract translation: 至少一种3,4-二亚烷基二氧噻吩化合物在25℃下在水中的溶解度小于2.2g / L的共聚物的水分散体与至少一种在水中溶解度为25的3,4-亚烷基二氧噻吩化合物 至少2.2g / L的聚阴离子; 其准备过程; 其用于涂料; 含有水分散体的印刷油墨; 含有至少一种在25℃下在水中的溶解度低于2.2g / L的3,4-亚烷基二氧噻吩化合物与至少一种在水中溶解度的3,4-亚烷基二氧噻吩化合物的共聚物的导电层 在25℃下为至少2.2g / L，衍生自其水分散体的聚阴离子; 以及含有至少一种在25℃下在水中溶解度小于2.2g / L的3,4-亚烷基二氧基 - 噻吩化合物与至少一种具有溶解度的3,4-亚烷基二氧噻吩化合物的共聚物的抗静电层 25℃下的水至少为2.2g / L，衍生自其水分散体的聚阴离子。

公开(公告)号：US20040260016A1

公开(公告)日：2004-12-23

申请号：US10870503

申请日：2004-06-17

Applicant: AGFA-GEVAERT

Inventor： Frank Louwet ,  Etienne Van Thillo ,  Bert Groenendaal

IPC: C08K003/00

CPC classification number: H01B1/127 ,  C08G61/126 ,  C09D5/24 ,  H01G9/028 ,  H01G11/48 ,  H01G11/56 ,  H01L51/0037 ,  Y02E60/13

Abstract: An aqueous dispersion of latex particles, said latex particles containing a polymer containing monomer units according to formula (I): 1 in which R1 and R2 independently of one another represent hydrogen or a C1-5-alkyl group or together form an optionally substituted C1-5-alkylene residue and at least one polyanion compound, said latex having a primary particle size of less than 40 nm and said dispersion contains an organic compound containing a di- or polyhydroxy- and/or carboxy groups or amide or lactam group or an aprotic compound with a dielectric constant, null, null15, wherein said latex particles contain said at least one polyanion compound and said polymer in a weight ratio of at least 4; a process for preparing an electroconductive coating comprising the steps of: preparing an aqueous solution or dispersion of the above-mentioned polymer by polymerization with an initiator in a reaction medium in the presence of at least one polyanion compound under oxidizing or reducing conditions, wherein the weight ratio of the at least one polyanion compound to said structural units during the reaction is in the range of 4:1 to 20:1; preparing a first coating composition containing said polymer associated with said at least one polyanion compound and an organic compound containing a di- or polyhydroxy- and/or carboxy groups or amide or lactam group in a aqueous or non-aqueous medium; coating said first coating composition on an object thereby producing a first layer; and heating said first layer at a temperature of at least 100null C.; and a process for preparing an electroconductive coating comprising the steps of: preparing an aqueous solution or dispersion of the above-mentioned polymer by polymerization with an initiator in a reaction medium in the presence of at least one polyanion compound under oxidizing or reducing conditions, wherein the weight ratio of said at least one polyanion compound to said structural units during the reaction is in the range of 4:1 to 20:1; preparing a second coating composition containing said polymer associated with said at least one polyanion compound and an aprotic compound with a dielectric constant, null, null15 in an aqueous or non-aqueous medium; coating said second coating composition on an object thereby producing a second layer; and heating said second layer at a temperature of at least 50null C.

公开(公告)号：US20030211331A1

公开(公告)日：2003-11-13

申请号：US10308567

申请日：2002-12-03

Applicant: Agfa-Gevaert

Inventor： Frank Louwet ,  Bert Groenendaal

IPC: C08L001/00

CPC classification number: C08G61/126 ,  C08G2261/122 ,  C08G2261/1424 ,  C08G2261/1426 ,  C08G2261/1452 ,  C08G2261/3223 ,  C08G2261/43 ,  C08G2261/51 ,  C08G2261/794 ,  C09D165/00 ,  H01G9/028 ,  H01G11/48 ,  Y02E60/13 ,  Y10T428/31533 ,  C08L25/18

Abstract: A process for preparing an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer, containing structural units according to formula (I): 1 in which R1 and R2 independently of one another represent hydrogen or a C1-5-alkyl group or together form an optionally substituted C1-5-alkylene residue, comprising the step of: preparing the polythiophene or thiophene copolymer with an initiator in a reaction medium in the presence of polyanions under oxidizing or reducing conditions under an inert atmosphere such that when said initiator is added less than 3 mg of oxygen per litre of the reaction medium is present in the reaction medium; an aqueous or non-aqueous solution or dispersion prepared therewith; the use of an aqueous or non-aqueous dispersion or solution comprising the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer for coating an object; a printable paste containing the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer; and an electroconductive or an antistatic layer prepared using an aqueous or non-aqueous solution or dispersion comprising the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer.

Abstract translation: 制备含有根据式（I）的结构单元的聚噻吩或噻吩共聚物的水溶液或非水溶液或分散体的方法：其中R 1和R 2彼此独立地表示氢或C1 -5-烷基或一起形成任选取代的C 1-5 - 亚烷基残基，包括以下步骤：在氧化或还原条件下在惰性气氛下，在聚阴离子存在下，在反应介质中，用引发剂制备聚噻吩或噻吩共聚物 使得当反应介质中存在每升反应介质时，当所述引发剂加入小于3mg氧气时; 用其制备的水性或非水溶液或分散体; 使用包含聚噻吩或噻吩共聚物的水溶液或非水溶液或分散体的水性或非水分散体或溶液来涂覆物体; 含有聚噻吩或噻吩共聚物的水溶液或非水溶液或分散体的可印刷浆料; 以及使用包含聚噻吩或噻吩共聚物的水溶液或非水溶液或分散体的水性或非水溶液或分散体制备的导电或抗静电层。

公开(公告)号：US20030176628A1

公开(公告)日：2003-09-18

申请号：US10319976

申请日：2002-12-16

Applicant: AGFA-GEVAERT

Inventor： Bert Groenendaal ,  Frank Louwet

IPC: C08G069/10 ,  C07D333/02

CPC classification number: C07D495/04 ,  C08G61/126 ,  H01B1/127 ,  H01G11/48 ,  H05K1/095 ,  H05K3/321 ,  Y02E60/13

Abstract: A thiophene compound represented by formula (I): 1 in which A represents a C1-5-alkylene bridge; R represents a nullR1null(CnullO)nullR2 group; nullR1null represents a nullR3null or nullR4nullXnullR5null group; R2 is hydrogen, a hydroxy group, a thiol group, nullNR6R7, nullOR8 or a nullSR9 group; R3, R4 and R5 are independently an alkylene group or an arylene group; X is a nullOnull, nullSnull or nullNR10; R6 and R7 are independently hydrogen, an optionally substituted amino group or an optionally substituted alkyl group; R8 and R9 are independently an optionally substituted alkyl group (optionally with at least one substituent selected from the group consisting of an alcohol, amide, ether, ester or sulfonate group), an optionally substituted aryl group or a nullSiR11R12R13 group; R10 is an alkyl, aryl or acyl group; and R11 R12 and R13 are independently an optionally substituted alkoxy or alkyl group; polymers derived therefrom; a process for polymerizing a thiophene according to formula (I), optionally chemically or electrochemically; and solutions, dispersions, pastes and layers containing polymers derived therefrom.

Abstract translation: 由式（I）表示的噻吩化合物：其中A表示C1-5亚烷基桥; R表示-R1-（C = O）-R2基团; -R1-表示-R3-或-R4-X-R5-基团; R2是氢，羟基，硫醇基，-NR6R7，-OR8或-SR9基团; R3，R4和R5独立地是亚烷基或亚芳基; X是-O - ， - S-或= NR10; R6和R7独立地为氢，任选取代的氨基或任选取代的烷基; R8和R9独立地是任选取代的烷基（任选地具有至少一个选自醇，酰胺，醚，酯或磺酸酯基的取代基），任选取代的芳基或-SiR 11 R 12 R 13基团; R 10是烷基，芳基或酰基; 和R11R12和R13独立地是任选取代的烷氧基或烷基; 衍生自其的聚合物; 根据式（I）聚合噻吩的方法，任选化学或电化学方法; 以及含有由其衍生的聚合物的溶液，分散体，糊剂和层。

公开(公告)号：US20030170454A1

公开(公告)日：2003-09-11

申请号：US10316274

申请日：2002-12-11

Applicant: AGFA-GEVAERT

Inventor： Johan Lamotte ,  Frank Louwet ,  Tom Cloots ,  Huub Van Aert

IPC: D02G003/00

CPC classification number: H05K3/105 ,  H01B1/127 ,  H01L51/0021 ,  H01L51/0036 ,  H05K3/02 ,  Y10T428/24355 ,  Y10T428/24802 ,  Y10T428/269 ,  Y10T428/2933 ,  Y10T428/2971 ,  Y10T428/31855

Abstract: A material for making a conductive pattern, the material comprising a support and a heat-differentiable element, the heat-differentiable element comprising an outermost layer containing a polyanion and an intrinsically conductive polymer and optionally a second layer contiguous with the outermost layer, characterized in that the outermost layer and/or the optional second layer contains hydrophobic thermocoagulable latex particles in a weight ratio range with respect to the intrinsically conductive polymer in the range of 20:1 to 1:5, the hydrophobic thermocoagulable latex particles are capable upon heating of increasing the conductivity of the heated parts of the outermost layer relative to the unheated parts of the outermost layer and/or changing the removability of the heated parts of the outermost layer relative to the unheated parts of the outermost layer and the heat-differentiable element does not comprise a di- or polyhydroxy organic compound or an aprotic compound with a dielectric constant, null, null15; a method of making a conductive pattern on a support therewith; and a use of the material for making a conductive pattern in making an electronic circuit in the production of an electric or semiconductor device such as a printed circuit board, an integrated circuit, a display or touch screen, an electroluminescent device or a photovoltaic cell.

Abstract translation: 一种用于制造导电图案的材料，该材料包括支撑体和可热分解的元件，该热可分离元件包括含有聚阴离子和本征导电聚合物的最外层，以及任选地与最外层邻接的第二层，其特征在于 最外层和/或任选的第二层含有相对于本征导电聚合物的重量比范围为20:1至1:5的疏水性热凝胶乳胶颗粒，疏水性热凝胶乳颗粒能够加热 增加最外层的加热部分相对于最外层的未加热部分的导电性和/或改变最外层的加热部分相对于最外层和可热分散元件的未加热部分的可去除性 不包含二 - 或多羟基有机化合物或具有夹层的非质子化合物 三次常数，epsi，> = 15; 在其上的支撑件上形成导电图案的方法; 以及在制造诸如印刷电路板，集成电路，显示器或触摸屏，电致发光器件或光伏电池的电气或半导体器件中的电子电路中制造导电图案的材料的用途。