公开(公告)号：US08703899B2

公开(公告)日：2014-04-22

申请号：US14014977

申请日：2013-08-30

Applicant: Asahi Glass Company, Limited

Inventor： Jumpei Nomura ,  Hidekazu Okamoto ,  Atsushi Fujimori ,  Takashi Okazoe

IPC: C08G63/02 ,  C08G63/00

CPC classification number: C08G63/195 ,  C07C67/14 ,  C07C69/80 ,  C07C69/82 ,  C08G63/183 ,  C08G63/78

Abstract: The present invention relates to a method for producing a polyester, containing conducting a transesterification reaction of at least one compound selected from compounds represented by the following formulae (1) to (3) with a diol compound in the presence of a catalyst: wherein Ar is a divalent aromatic hydrocarbon group or the like; R1 is CX1Y1R4; R2 is a hydrogen atom or CX2Y2R5; R3 is a hydrogen atom or CX3Y3R6; R7 is a perfluoroalkylene group having 1 to 5 carbon atoms; X1 to X3 are a hydrogen atom, a fluorine atom or Rf; Y1 to Y3 are a fluorine atom or Rf; R4 to R6 are a fluorine atom, Rf, ORf or the like; and Rf is a fluoroalkyl group having 1 to 4 carbon atoms.

Abstract translation: 本发明涉及一种聚酯的制造方法，其特征在于，在催化剂存在下，含有选自下述式（1）〜（3）表示的化合物中的至少一种化合物与二醇化合物的酯交换反应：其中Ar 是二价芳香族烃基等; R1为CX1Y1R4; R2是氢原子或CX2Y2R5; R3是氢原子或CX3Y3R6; R7是碳原子数为1〜5的全氟亚烷基; X 1至X 3为氢原子，氟原子或R f; Y1〜Y3为氟原子或Rf; R4〜R6是氟原子，Rf，ORf等; Rf为碳原子数1〜4的氟代烷基。

公开(公告)号：US09796655B2

公开(公告)日：2017-10-24

申请号：US14730432

申请日：2015-06-04

Applicant: Asahi Glass Company, Limited

Inventor： Hidekazu Okamoto ,  Atsushi Fujimori ,  Takashi Okazoe

IPC: C07C68/00

CPC classification number: C07C68/00 ,  C07C69/96

Abstract: The present invention relates to a production process capable of selectively producing various kinds of carbonate compounds without restraint in high yields without using toxic compounds such as phosgene and crown ethers, without producing corrosive gases such as hydrogen chloride as a by-product, and without necessity of removing the chloroform as a by-product by distillation, and to a method for producing a carbonate compound, containing reacting compound (1) with a compound having an OH group in the presence of a metal salt and 0.2 to 4.0 mol of compound (2) per mol of the metal salt to obtain a carbonate compound, in which m is an integer of 1-10, Q is an alkylene group having 1 to 4 carbon atoms, etc, and R10 and R11 are alkyl groups having 1 to 5 carbon atoms, etc.

公开(公告)号：US09617379B2

公开(公告)日：2017-04-11

申请号：US15233981

申请日：2016-08-11

Applicant: Asahi Glass Company, Limited

Inventor： Takashi Okazoe ,  Masayuki Miyazaki ,  Kazuya Oharu ,  Tomoyuki Fujita ,  Shinji Wada ,  Koichi Murata ,  Naoko Shirota

IPC: C08G63/02 ,  C08G64/00 ,  C08G64/30 ,  C07C29/38 ,  C07C67/00 ,  C07C67/14 ,  C07C67/317 ,  C07C68/00 ,  C07C68/06 ,  C07C45/63 ,  C07C49/16 ,  C07C51/16 ,  C07C51/377 ,  C07C57/04 ,  C07C17/361 ,  C08G64/06

CPC classification number: C08G64/307 ,  C07C17/361 ,  C07C29/38 ,  C07C45/63 ,  C07C49/16 ,  C07C51/16 ,  C07C51/377 ,  C07C57/04 ,  C07C67/00 ,  C07C67/14 ,  C07C67/317 ,  C07C68/00 ,  C07C68/06 ,  C08G64/00 ,  C08G64/06 ,  C07C69/96 ,  C07C31/36 ,  C07C69/63 ,  C07C69/54

Abstract: The present invention relates to a method for producing a carbonate compound and methacrylic acid or an ester thereof, containing a step (a1) of obtaining hexachloroacetone and hydrogen chloride from acetone and chlorine molecule, a step (a2) of obtaining a dialkyl carbonate and chloroform from hexachloroacetone and an alkyl alcohol, a step (b1) of obtaining 1,1,1-trichloro-2-methyl-2-propanol from chloroform and acetone, a step (b2+b3 or b4) of obtaining methacrylic acid or an ester thereof and hydrogen chloride from 1,1,1-trichloro-2-methyl-2-propanol and water or an alcohol, and a step (c1 or c2) of obtaining chlorine molecule by reacting hydrogen chloride with oxygen molecule.

公开(公告)号：US09447235B2

公开(公告)日：2016-09-20

申请号：US14883759

申请日：2015-10-15

Applicant: ASAHI GLASS COMPANY, LIMITED

Inventor： Naoko Shirota ,  Takashi Okazoe ,  Kimiaki Kashiwagi

IPC: C08G63/02 ,  C08G64/28 ,  C08G64/30 ,  C08G64/00

CPC classification number: C08G64/28 ,  C08G64/307

Abstract: The present invention relates to a method of producing polycarbonate containing following step (a) and step (b), (a) a step of reacting a specific fluorine-containing carbonate (Compound (1), etc.) and an aromatic dihydroxy compound in the presence of a condensation catalyst, to obtain a prepolymer, and (b) a step of heating the prepolymer at a temperature which is lower than a melting temperature of the prepolymer and performing solid phase polymerization on the prepolymer while a fluorine-containing alcohol that is produced as a by-product is discharged out of a system, to obtain a polycarbonate.

公开(公告)号：US09238612B2

公开(公告)日：2016-01-19

申请号：US14636510

申请日：2015-03-03

Applicant: Asahi Glass Company, Limited

Inventor： Tomoyuki Fujita ,  Shinji Wada ,  Takashi Okazoe ,  Koichi Murata

IPC: C07C67/317 ,  C07C67/40 ,  C07C67/00 ,  C07C51/093 ,  C07C51/377

CPC classification number: C07C67/317 ,  C07C51/093 ,  C07C51/377 ,  C07C67/00 ,  C07C67/40 ,  C07C53/19 ,  C07C69/63 ,  C07C69/653

Abstract: The present invention relates to a method for producing an unsaturated acid and/or an unsaturated acid ester, containing a process A of reacting a compound (1) represented by the following formula (1) at a temperature of 0° C. to 350° C. in the presence of a Brønsted acid catalyst and/or a Lewis acid catalyst, to prepare a compound (2) represented by the following formula (2); in which each of R1, R2 and R4 independently represents a hydrogen atom, a deuterium atom or an alkyl group; each of R3 and R5 independently represents a hydrogen atom or a deuterium atom; R6 represents a hydrogen atom, a deuterium atom, or an alkyl group or an aryl group; and X represents a chlorine atom, a fluorine atom, a bromine atom, or an iodine atom.

Abstract translation: 本发明涉及一种不饱和酸和/或不饱和酸酯的制造方法，其含有将下述式（1）表示的化合物（1）在0℃〜350℃的温度下反应的方法A 在布朗斯台德酸催化剂和/或路易斯酸催化剂存在下，制备由下式（2）表示的化合物（2）; 其中R 1，R 2和R 4各自独立地表示氢原子，氘原子或烷基; R 3和R 5各自独立地表示氢原子或氘原子; R6表示氢原子，氘原子或烷基或芳基; X表示氯原子，氟原子，溴原子或碘原子。

公开(公告)号：US09260383B2

公开(公告)日：2016-02-16

申请号：US14555092

申请日：2014-11-26

Applicant: Asahi Glass Company, Limited

Inventor： Takashi Okazoe ,  Yuko Nagasaki ,  Hidekazu Okamoto

IPC: C07C271/24 ,  C07C271/20 ,  C07C263/04 ,  C07C269/04

CPC classification number: C07C271/24 ,  C07C263/04 ,  C07C269/04 ,  C07C271/20 ,  C07C2601/14 ,  C07C265/14

Abstract: The present invention relates to a method of producing a carbamate compound, comprising reacting a fluorine-containing carbonic diester compound represented by formula (1) and a non-aromatic diamine compound represented by formula (2) without using a catalyst, to thereby produce a carbamate compound represented by formula (3), and a method of producing an isocyanate compound represented by formula (20) from the carbamate compound without using a catalyst, wherein R represents a fluorine-containing monovalent aliphatic hydrocarbon group, and A represents a divalent aliphatic hydrocarbon group, a divalent alicyclic hydrocarbon group or a divalent aromatic-aliphatic hydrocarbon group.

公开(公告)号：US20130345387A1

公开(公告)日：2013-12-26

申请号：US14014977

申请日：2013-08-30

Applicant: Asahi Glass Company, Limited

Inventor： Jumpei Nomura ,  Hidekazu Okamoto ,  Atsushi Fujimori ,  Takashi Okazoe

IPC: C08G63/195

CPC classification number: C08G63/195 ,  C07C67/14 ,  C07C69/80 ,  C07C69/82 ,  C08G63/183 ,  C08G63/78

Abstract: The present invention relates to a method for producing a polyester, containing conducting a transesterification reaction of at least one compound selected from compounds represented by the following formulae (1) to (3) with a diol compound in the presence of a catalyst: wherein Ar is a divalent aromatic hydrocarbon group or the like; R1 is CX1Y1R4; R2 is a hydrogen atom or CX2Y2R5; R3 is a hydrogen atom or CX3Y3R6; R7 is a perfluomalkylene group having 1 to 5 carbon atoms; X1 to X3 are a hydrogen atom, a fluorine atom or Rf; Y1 to Y3 are a fluorine atom or Rf; R4 to R6 are a fluorine atom, Rf, ORf or the like; and Rf is a fluoroalkyl group having 1 to 4 carbon atoms.

Abstract translation: 本发明涉及一种聚酯的制造方法，其特征在于，在催化剂存在下，含有选自下述式（1）〜（3）表示的化合物中的至少一种化合物与二醇化合物的酯交换反应：其中Ar 是二价芳香族烃基等; R1为CX1Y1R4; R2是氢原子或CX2Y2R5; R3是氢原子或CX3Y3R6; R7是具有1至5个碳原子的全亚烷基; X 1至X 3为氢原子，氟原子或R f; Y1〜Y3为氟原子或Rf; R4〜R6是氟原子，Rf，ORf等; Rf为碳原子数1〜4的氟代烷基。

公开(公告)号：US20160032046A1

公开(公告)日：2016-02-04

申请号：US14883759

申请日：2015-10-15

Applicant: ASAHI GLASS COMPANY, LIMITED

Inventor： Naoko SHIROTA ,  Takashi Okazoe ,  Kimiaki Kashiwagi

IPC: C08G64/28

CPC classification number: C08G64/28 ,  C08G64/307

Abstract: The present invention relates to a method of producing polycarbonate containing following step (a) and step (b), (a) a step of reacting a specific fluorine-containing carbonate (Compound (1), etc.) and an aromatic dihydroxy compound in the presence of a condensation catalyst, to obtain a prepolymer, and (b) a step of heating the prepolymer at a temperature which is lower than a melting temperature of the prepolymer and performing solid phase polymerization on the prepolymer while a fluorine-containing alcohol that is produced as a by-product is discharged out of a system, to obtain a polycarbonate.

Abstract translation: 本发明涉及一种生产聚碳酸酯的方法，该方法包括以下步骤（a）和（b）：（a）使特定含氟碳酸酯（化合物（1）等）与芳族二羟基化合物反应 存在缩合催化剂以获得预聚物，和（b）在低于预聚物的熔融温度的温度下加热预聚物并在预聚物上进行固相聚合的步骤，同时将含氟醇 作为副产物生产，从系统中排出，得到聚碳酸酯。