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公开(公告)号：US4211210A
公开(公告)日：1980-07-08
申请号：US882438
申请日：1978-03-01
CPC分类号： F24J2/07 , C04B35/26 , C09D5/32 , F24J2/487 , Y02E10/41 , Y10S126/908 , Y10T428/12611 , Y10T428/12618
摘要： Improved coatings for high temperature solar collectors comprise thermally stable inorganic oxides selected from ferrites, metal oxides and mixtures thereof having solar absorptances greater than 0.9 at wavelengths ranging from about 0.35 to 3.0 microns. The coatings can be applied to a heat transfer surface by painting an organic silicate dispersion of the optically active material onto the substrate and thereafter curing the silicate binder.
摘要翻译： 用于高温太阳能收集器的改进的涂层包括选自铁氧体，金属氧化物及其混合物的热稳定的无机氧化物，其在约0.35至3.0微米的波长范围内具有大于0.9的太阳能吸收率。 可以通过将光学活性材料的有机硅酸盐分散体涂布在基材上，然后固化硅酸盐粘合剂，将涂层施加到传热表面。
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公开(公告)号：US4268319A
公开(公告)日：1981-05-19
申请号：US107363
申请日：1979-12-26
摘要： Improved coatings for high temperature solar collectors comprise thermally stable inorganic oxides selected from ferrites, metal oxides and mixtures thereof having solar absorptances greater than 0.9 at wavelengths ranging from about 0.35 to 3.0 microns. The coatings can be applied to a heat transfer surface by painting an organic silicate dispersion of the optically active material onto the substrate and thereafter curing the silicate binder.
摘要翻译： 用于高温太阳能收集器的改进的涂层包括选自铁氧体，金属氧化物及其混合物的热稳定的无机氧化物，其在约0.35至3.0微米的波长范围内具有大于0.9的太阳能吸收率。 可以通过将光学活性材料的有机硅酸盐分散体涂布在基材上，然后固化硅酸盐粘合剂，将涂层施加到传热表面。
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公开(公告)号：US4831002A
公开(公告)日：1989-05-16
申请号：US79247
申请日：1987-07-29
CPC分类号： B01J31/1616 , B01J23/85 , B01J27/047 , B01J31/1805 , B01J37/20 , C10G45/04 , C10G45/08 , B01J2531/62
摘要： Self-promoted molybdenum and tungsten sulfide hydrotreating catalysts are prepared by heating one or more water soluble catalyst precursors in a non-oxidizing atmosphere in the presence of sulfur at a temperature of at least about 200.degree. C. The precursors are (Cr.sub.x M.sub.1-x L)[Mo.sub.y W.sub.1-y O.sub.4 ].sub.1+.5x wherein M is a divalent promoter metal selected from the group consisting of Mn, Fe, Co, Ni, Cu, Zn and mixtures thereof, x is any value from about 0.2 to 1, y is any value from 0 to 1, and wherein L is a nitrogen-containing, neutral multidentate, chelating ligand. In a preferred embodiment the lligand L will comprise one or more chelating alkyl di- or triamines and the non-oxidizing atmosphere will comprise H.sub.2 S.
摘要翻译： 通过在至少约200℃的温度下在硫的存在下在非氧化性气氛中加热一种或多种水溶性催化剂前体来制备自促进的钼和硫化钨加氢处理催化剂。前体是（CrxM1-xL） [MoyW1-yO4] 1 + .5x其中M是选自Mn，Fe，Co，Ni，Cu，Zn及其混合物的二价促进剂金属，x是约0.2至1的任何值，y是任何 值为0至1，并且其中L为含氮中性多齿螯合配体。 在优选的实施方案中，配体L将包含一种或多种螯合烷基二胺或三胺，非氧化性气氛将包含H 2 S。
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4.发明授权Hydrotreating process employing catalysts comprising a supported, mixed metal sulfide iron promoted Mo and W 失效使用包含负载的混合金属硫化物铁的催化剂的加氢处理方法促进Mo和W
公开(公告)号：US4632747A
公开(公告)日：1986-12-30
申请号：US687538
申请日：1984-12-28
IPC分类号： C10G45/08 , B01J23/85 , B01J27/047 , B01J27/049 , B01J31/22 , C10G47/20 , C10G49/04 , C10G71/00 , C10G45/04
CPC分类号： B01J27/0515 , B01J23/85 , B01J27/049 , C10G49/04
摘要： This invention relates to the preparation and use of catalysts useful for hydroprocessing processes, such as hydrotreating, wherein said catalysts are formed by heating, at elevated temperature, in the presence of sulfur and under oxygen-free conditions, a composite of support material and one or more catalyst precursor salts containing a thiometallate anion of Mo, W or mixture thereof and a cation comprising one or more divalent promoter metals at least one of which is iron, wherein said promoter metal or metals are chelated by at least one neutral, nitrogen-containing polydentate ligand, and wherein said additional divalent promoter metal, if any, is selected from the group consisting of Ni, Co, Mn, Zn, Cu and mixture thereof.
摘要翻译： 本发明涉及可用于加氢处理方法（例如加氢处理）的催化剂的制备和用途，其中所述催化剂通过在高温下在硫的存在下和在无氧条件下加热形成，载体材料和一种 或更多的催化剂前体盐，其含有Mo，W或其混合物的硫代金属阴离子和包含一种或多种二价助催化剂金属的阳离子，其至少一种是铁，其中所述助催化剂金属或金属由至少一种中性， 含有多齿配体，并且其中所述另外的二价助催化剂金属（如果有的话）选自Ni，Co，Mn，Zn，Cu及其混合物。
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5.发明授权Hydrotreating process employing catalysts comprising a supported mixture of a sulfide of a promoter metal, trivalent chromium and molybdenum or tungsten 失效使用包含助催化剂金属，三价铬和钼或钨的硫化物的负载混合物的催化剂的加氢处理方法
公开(公告)号：US4591429A
公开(公告)日：1986-05-27
申请号：US656132
申请日：1984-09-28
IPC分类号： C10G45/04 , B01J27/047 , B01J31/22 , C10G45/08 , C10G49/04
CPC分类号： B01J27/047 , C10G49/04
摘要： Supported, hydroprocessing catalysts comprising a sulfide of (i) trivalent chromium, (ii) Mo, W or mixture thereof and (iii) at least one metal selected from the group consisting of Ni, Co, Mn, Cu, Zn and mixture thereof and mixture thereof with Fe. These catalysts are made by compositing a preselected quantity of support material with a precursor comprising a mixture of (i) hydrated oxide of trivalent chromium and (ii) a salt containing a thiometallate anion of Mo or W and a cation comprising at least one divalent promoter metal chelated by at least one, neutral, nitrogen-containing polydentate ligand and heating the composite in the presence of sulfur and hydrogen in an oxygen-free atmosphere. These catalysts have been found to be useful hydrotreating catalysts having nitrogen removal activity superior to that of commercial catalysts such as sulfided cobalt-molybdate on alumina.
摘要翻译： 含有（i）三价铬，（ii）Mo，W或其混合物的硫化物的负载型加氢处理催化剂和（iii）选自Ni，Co，Mn，Cu，Zn及其混合物中的至少一种金属和 与Fe的混合物。 这些催化剂通过将预选量的载体材料与包含（i）三价铬的水合氧化物和（ii）含有Mo或W的金属硫酸盐阴离子的盐的混合物和包含至少一种二价助催化剂的阳离子 金属由至少一种中性的含氮多齿配体螯合，并在无氧气氛中在硫和氢的存在下加热复合物。 已经发现，这些催化剂是具有优于氮化钼 - 钼酸盐在商业催化剂上的脱氮活性的有用的加氢处理催化剂。
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