公开(公告)号：US4831002A

公开(公告)日：1989-05-16

申请号：US79247

申请日：1987-07-29

申请人： Teh C. Ho ,  Larry E. McCandlish ,  Archie R. Young, II ,  Edward J. Osterhuber

发明人： Teh C. Ho ,  Larry E. McCandlish ,  Archie R. Young, II ,  Edward J. Osterhuber

IPC分类号： B01J23/85 ,  B01J27/047 ,  B01J31/16 ,  B01J31/18 ,  B01J37/20 ,  C10G45/04 ,  C10G45/08

CPC分类号： B01J31/1616 ,  B01J23/85 ,  B01J27/047 ,  B01J31/1805 ,  B01J37/20 ,  C10G45/04 ,  C10G45/08 ,  B01J2531/62

摘要： Self-promoted molybdenum and tungsten sulfide hydrotreating catalysts are prepared by heating one or more water soluble catalyst precursors in a non-oxidizing atmosphere in the presence of sulfur at a temperature of at least about 200.degree. C. The precursors are (Cr.sub.x M.sub.1-x L)[Mo.sub.y W.sub.1-y O.sub.4 ].sub.1+.5x wherein M is a divalent promoter metal selected from the group consisting of Mn, Fe, Co, Ni, Cu, Zn and mixtures thereof, x is any value from about 0.2 to 1, y is any value from 0 to 1, and wherein L is a nitrogen-containing, neutral multidentate, chelating ligand. In a preferred embodiment the lligand L will comprise one or more chelating alkyl di- or triamines and the non-oxidizing atmosphere will comprise H.sub.2 S.

摘要翻译： 通过在至少约200℃的温度下在硫的存在下在非氧化性气氛中加热一种或多种水溶性催化剂前体来制备自促进的钼和硫化钨加氢处理催化剂。前体是（CrxM1-xL） [MoyW1-yO4] 1 + .5x其中M是选自Mn，Fe，Co，Ni，Cu，Zn及其混合物的二价促进剂金属，x是约0.2至1的任何值，y是任何 值为0至1，并且其中L为含氮中性多齿螯合配体。 在优选的实施方案中，配体L将包含一种或多种螯合烷基二胺或三胺，非氧化性气氛将包含H 2 S。

公开(公告)号：US4632747A

公开(公告)日：1986-12-30

申请号：US687538

申请日：1984-12-28

申请人： Teh C. Ho ,  Archie R. Young, II ,  Allan J. Jacobson ,  Russell R. Chianelli

发明人： Teh C. Ho ,  Archie R. Young, II ,  Allan J. Jacobson ,  Russell R. Chianelli

IPC分类号： C10G45/08 ,  B01J23/85 ,  B01J27/047 ,  B01J27/049 ,  B01J31/22 ,  C10G47/20 ,  C10G49/04 ,  C10G71/00 ,  C10G45/04

CPC分类号： B01J27/0515 ,  B01J23/85 ,  B01J27/049 ,  C10G49/04

摘要： This invention relates to the preparation and use of catalysts useful for hydroprocessing processes, such as hydrotreating, wherein said catalysts are formed by heating, at elevated temperature, in the presence of sulfur and under oxygen-free conditions, a composite of support material and one or more catalyst precursor salts containing a thiometallate anion of Mo, W or mixture thereof and a cation comprising one or more divalent promoter metals at least one of which is iron, wherein said promoter metal or metals are chelated by at least one neutral, nitrogen-containing polydentate ligand, and wherein said additional divalent promoter metal, if any, is selected from the group consisting of Ni, Co, Mn, Zn, Cu and mixture thereof.

摘要翻译： 本发明涉及可用于加氢处理方法（例如加氢处理）的催化剂的制备和用途，其中所述催化剂通过在高温下在硫的存在下和在无氧条件下加热形成，载体材料和一种 或更多的催化剂前体盐，其含有Mo，W或其混合物的硫代金属阴离子和包含一种或多种二价助催化剂金属的阳离子，其至少一种是铁，其中所述助催化剂金属或金属由至少一种中性， 含有多齿配体，并且其中所述另外的二价助催化剂金属（如果有的话）选自Ni，Co，Mn，Zn，Cu及其混合物。

公开(公告)号：US4591429A

公开(公告)日：1986-05-27

申请号：US656132

申请日：1984-09-28

申请人： Teh C. Ho ,  Archie R. Young, II ,  Russell R. Chianelli ,  Allan J. Jacobson

发明人： Teh C. Ho ,  Archie R. Young, II ,  Russell R. Chianelli ,  Allan J. Jacobson

IPC分类号： C10G45/04 ,  B01J27/047 ,  B01J31/22 ,  C10G45/08 ,  C10G49/04

CPC分类号： B01J27/047 ,  C10G49/04

摘要： Supported, hydroprocessing catalysts comprising a sulfide of (i) trivalent chromium, (ii) Mo, W or mixture thereof and (iii) at least one metal selected from the group consisting of Ni, Co, Mn, Cu, Zn and mixture thereof and mixture thereof with Fe. These catalysts are made by compositing a preselected quantity of support material with a precursor comprising a mixture of (i) hydrated oxide of trivalent chromium and (ii) a salt containing a thiometallate anion of Mo or W and a cation comprising at least one divalent promoter metal chelated by at least one, neutral, nitrogen-containing polydentate ligand and heating the composite in the presence of sulfur and hydrogen in an oxygen-free atmosphere. These catalysts have been found to be useful hydrotreating catalysts having nitrogen removal activity superior to that of commercial catalysts such as sulfided cobalt-molybdate on alumina.

摘要翻译： 含有（i）三价铬，（ii）Mo，W或其混合物的硫化物的负载型加氢处理催化剂和（iii）选自Ni，Co，Mn，Cu，Zn及其混合物中的至少一种金属和 与Fe的混合物。 这些催化剂通过将预选量的载体材料与包含（i）三价铬的水合氧化物和（ii）含有Mo或W的金属硫酸盐阴离子的盐的混合物和包含至少一种二价助催化剂的阳离子 金属由至少一种中性的含氮多齿配体螯合，并在无氧气氛中在硫和氢的存在下加热复合物。 已经发现，这些催化剂是具有优于氮化钼 - 钼酸盐在商业催化剂上的脱氮活性的有用的加氢处理催化剂。

公开(公告)号：US4705619A

公开(公告)日：1987-11-10

申请号：US7765

申请日：1987-01-28

申请人： Larry E. McCandlish ,  Teh C. Ho

发明人： Larry E. McCandlish ,  Teh C. Ho

IPC分类号： B01J37/08 ,  C10G45/04 ,  C10G45/08 ,  C10G45/50 ,  C10G47/04 ,  C10G47/12

CPC分类号： C10G45/04 ,  B01J37/086

摘要： Hydrocarbon feeds are upgraded by contacting same, at elevated temperature and in the presence of hydrogen, with a self-promoted catalyst prepared by heating one or more water soluble catalyst precursors in a non-oxidizing atmosphere in the presence of sulfur at a temperature of at least about 200.degree. C. The precursors will be one or more compounds of the formula ML(Mo.sub.y W.sub.1-y O.sub.4) wherein M is one or more promoter metals selected from the group consisting essentially of Mn, Fe, Co, Ni, Cu, Zn and mixtures thereof, wherein O.ltoreq.y.ltoreq.1 and wherein L is a nitrogen containing, neutral multidentate, chelating ligand. In a preferred embodiment the ligand L will comprise one or more chelating alkyl di or triamines and the non-oxidizing atmosphere and to form the catalyst will comprise H.sub.2 S.

摘要翻译： 通过在升高的温度和在氢的存在下使其接触来提高烃进料与通过在硫的存在下在非氧化性气氛中在一定温度下加热一种或多种水溶性催化剂前体而制备的自促进催化剂 至少约200℃。前体将是一种或多种式ML（MoyW1-yO4）的化合物，其中M是一种或多种选自基本上由Mn，Fe，Co，Ni，Cu，Zn和 其混合物，其中O y为1，并且其中L为含氮中性多齿螯合配体。 在优选的实施方案中，配体L将包含一种或多种螯合烷基二或三胺，并且非氧化性气氛和形成催化剂将包含H 2 S。

公开(公告)号：US4663023A

公开(公告)日：1987-05-05

申请号：US687579

申请日：1984-12-28

申请人： Larry E. McCandlish ,  Teh C. Ho

发明人： Larry E. McCandlish ,  Teh C. Ho

IPC分类号： C10G45/08 ,  B01J27/00 ,  B01J31/00 ,  B01J37/08 ,  C10G45/04 ,  C10G45/50 ,  C10G47/04 ,  C10G47/12

CPC分类号： C10G45/04 ,  B01J37/086

摘要： Hydrocarbon feeds are upgraded by contacting same, at elevated temperature and in the presence of hydrogen, with a self-promoted catalyst prepared by heating one or more water soluble catalyst precursors in a non-oxidizing atmosphere in the presence of sulfur at a temperature of at least about 200.degree. C. The precursors will be one or more compounds of the formula ML(Mo.sub.y W.sub.1-y O.sub.4) wherein M is one or more promoter metals selected from the group consisting essentially of Mn, Fe, Co, Ni, Cu, Zn and mixtures thereof, wherein O.ltoreq.y.ltoreq.1 and wherein L is a nitrogen containing, neutral multidentate, chelating ligand. In a preferred embodiment the ligand L will comprise one or more chelating alkyl di or triamines and the non-oxidizing atmosphere and to form the catalyst will comprise H.sub.2 S.

摘要翻译： 通过在升高的温度和在氢的存在下使其接触来提高烃进料与通过在硫的存在下在非氧化性气氛中在一定温度下加热一种或多种水溶性催化剂前体而制备的自促进催化剂 至少约200℃。前体将是一种或多种式ML（MoyW1-yO4）的化合物，其中M是一种或多种选自基本上由Mn，Fe，Co，Ni，Cu，Zn和 其混合物，其中O y为1，并且其中L为含氮中性多齿螯合配体。 在优选的实施方案中，配体L将包含一种或多种螯合烷基二或三胺，并且非氧化性气氛和形成催化剂将包含H 2 S。

公开(公告)号：US4595672A

公开(公告)日：1986-06-17

申请号：US680379

申请日：1984-12-11

申请人： Teh C. Ho ,  Larry E. McCandlish

发明人： Teh C. Ho ,  Larry E. McCandlish

IPC分类号： B01J23/85 ,  B01J27/047 ,  B01J31/16 ,  B01J31/18 ,  B01J31/22 ,  B01J37/20 ,  C10G45/04 ,  C10G45/08 ,  B01J27/051 ,  B01J31/00 ,  C10G1/06

CPC分类号： B01J31/1616 ,  B01J23/85 ,  B01J27/047 ,  B01J31/1805 ,  B01J37/20 ,  C10G45/04 ,  C10G45/08 ,  B01J2531/16 ,  B01J2531/26 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847

摘要： Self-promoted molybdenum and tungsten sulfide hydrotreating catalysts are prepared by heating one or more water soluble catalyst precursors in a non-oxidizing atmosphere in the presence of sulfur at a temperature of at least about 200.degree. C. The precursors will be one or more compounds of the formula ML(Mo.sub.y W.sub.1-y O.sub.4) wherein M is one or more promoter metals selected from the group consisting essentially of Mn, Fe, Co, Ni, Cu, Zn and mixtures thereof, wherein O.ltoreq.y.ltoreq.1 and wherein L is a nitrogen containing, neutral multidentate, chelating ligand. In a preferred embodiment the ligand L will comprise one or more chelating alkyl di or triamines and the non-oxidizing atmosphere will comprise H.sub.2 S.

摘要翻译： 通过在至少约200℃的温度下在硫的存在下在非氧化性气氛中加热一种或多种水溶性催化剂前体来制备自促进的钼和硫化钨加氢处理催化剂。前体将是一种或多种化合物 其中M是一种或多种选自基本上由Mn，Fe，Co，Ni，Cu，Zn组成的组的助催化剂金属及其混合物，其中O y = 其中L是含氮的中性多齿螯合配体。 在优选的实施方案中，配体L将包含一种或多种螯合烷基二或三胺，非氧化性气氛将包含H 2 S。

公开(公告)号：US08609429B2

公开(公告)日：2013-12-17

申请号：US13299178

申请日：2011-11-17

申请人： Teh C. Ho ,  Glen B. Brons ,  Limin Song ,  Tahmid I. Mizan

发明人： Teh C. Ho ,  Glen B. Brons ,  Limin Song ,  Tahmid I. Mizan

IPC分类号： G01N25/20

CPC分类号： G01N17/008 ,  C10G75/00 ,  C10G2300/1033 ,  C10G2300/4075 ,  G01N25/18 ,  G01N33/2823

摘要： Methods for determining the fouling propensity of a hydrocarbon stream and for reducing fouling are provided. In one method, the fouling propensity of a hydrocarbon stream is determined by obtaining a parameter value indicative of the fouling propensity at no less than two different temperatures, and an activation energy of fouling by the hydrocarbon stream is derived therefrom. In another method, the thus obtained parameter value at no less than two different temperatures and the activation energy are used to select proper heating fluids and operating temperature and to determine whether to add an antifoulant to the hydrocarbon stream to reduce fouling at a given temperature.

摘要翻译： 提供了确定烃流的污染倾向和减少结垢的方法。 在一种方法中，通过在不少于两个不同的温度下获得指示结垢倾向的参数值来确定烃流的结垢倾向，并且由此导出烃流的结垢的活化能。 在另一种方法中，由此获得的不少于两个不同温度的参数值和活化能用于选择适当的加热流体和操作温度，并确定是否在烃流中加入防污剂以减少给定温度下的结垢。

公开(公告)号：US5897768A

公开(公告)日：1999-04-27

申请号：US808100

申请日：1997-02-28

申请人： Gary B. McVicker ,  Teh C. Ho ,  Stuart Soled ,  Michel Daage ,  Roman Krycak ,  Sabato Miseo ,  Viktor Buchholz ,  William E. Lewis

发明人： Gary B. McVicker ,  Teh C. Ho ,  Stuart Soled ,  Michel Daage ,  Roman Krycak ,  Sabato Miseo ,  Viktor Buchholz ,  William E. Lewis

IPC分类号： B01J23/88 ,  B01J27/188 ,  C10G35/06 ,  C10G35/095 ,  C10G45/04 ,  C10G45/08 ,  C10G45/60 ,  C10G45/64

CPC分类号： C10G45/04

摘要： Hydrocarbon feeds are upgraded by contact of the stream under hydrodesulfurization (HDS) conditions with a catalyst system comprising a sulfided, transition metal promoted tungsten/molybdenum HDS catalyst, e.g., Ni/Co--Mo/Al.sub.2 O.sub.3 and a solid acid catalyst which is effective for the isomerization/disproportionation/transalkylation of alkyl substituted, condensed ring heterocyclic sulfur compounds present in the feedstream, e.g. zeolite or a heteropolyacid compound. Isomerization, disproportionation and transalkylation reactions convert refractory sulfur compounds such as 4- or 4,6-alkyl dibenzothiophenes into corresponding isomers or disproportionated isomers which can be more readily desulfurized by conventional HDS catalysts to H.sub.2 S and other products.

摘要翻译： 通过加氢脱硫（HDS）条件下的物流与包含硫化的过渡金属促进的钨/钼HDS催化剂（例如Ni / Co-Mo / Al 2 O 3）和固体酸催化剂的催化剂体系接触来提高烃进料，该催化剂体系对于 在进料流中存在的烷基取代的稠环杂环硫化合物的异构化/歧化/烷基转移， 沸石或杂多酸化合物。 异构化，歧化和烷基转移反应将难溶性硫化合物如4-或4,6-烷基二苯并噻吩转化为相应的异构体或歧化异构体，这些异构体可以通过常规的HDS催化剂更容易地脱硫至H 2 S和其它产物。

公开(公告)号：US5454933A

公开(公告)日：1995-10-03

申请号：US809629

申请日：1991-12-16

申请人： David W. Savage ,  Bal K. Kaul ,  Gerald D. Dupre ,  Joseph T. O'Bara ,  William E. Wales ,  Teh C. Ho

发明人： David W. Savage ,  Bal K. Kaul ,  Gerald D. Dupre ,  Joseph T. O'Bara ,  William E. Wales ,  Teh C. Ho

IPC分类号： C10G25/12 ,  C10G67/06 ,  C10G45/00

CPC分类号： C10G25/12 ,  C10G67/06

摘要： A process for providing distillate products which are substantially sulfur free, which process comprises subjecting a distillate stream to conventional hydrodesulfurization conditions including a catalyst comprised of a Group VI metal and at least one Group VIII metal on a refractory support. The hydrodesulfurized stream is then treated with a solid adsorbent material capable of adsorbing beta and di-beta-substituted dibenzothiophene sulfur compounds.

摘要翻译： 一种用于提供实质上无硫的馏出物的方法，该方法包括使馏出物物流经历加氢脱硫条件，包括在耐火载体上包含第VI族金属和至少一种第Ⅷ族金属的催化剂。 然后用能够吸附β和二-β-取代的二苯并噻吩硫化合物的固体吸附材料处理加氢脱硫物流。

公开(公告)号：US09333497B2

公开(公告)日：2016-05-10

申请号：US14192995

申请日：2014-02-28

申请人： Teh C. Ho ,  Krishnan Kumaran ,  Richard C. Dougherty

发明人： Teh C. Ho ,  Krishnan Kumaran ,  Richard C. Dougherty

IPC分类号： B01J38/56 ,  G05B23/02 ,  B01J8/02 ,  C10G49/00 ,  C10G75/00 ,  C10G75/04

CPC分类号： B01J38/56 ,  B01J8/02 ,  B01J2208/0007 ,  B01J2208/00539 ,  B01J2208/00707 ,  B01J2219/00211 ,  B01J2219/00213 ,  B01J2219/00231 ,  C10G49/002 ,  C10G75/00 ,  C10G75/04 ,  G05B23/0254

摘要： The behavior of a monitored condition over time for a reactor or reaction system can be analyzed using groupings or windows of data to identify anomalous features in the time-average values. Anomalous features can be identified based on a threshold value generated from the analysis. Based on identification of an anomalous feature, a corrective action can be taken. For example, when the monitored condition is the pressure drop across a catalyst bed, detection of an anomaly can indicate the time to initiate a wash process for the catalyst bed before a large drop in catalyst activity occurs. By detecting an anomaly at an earlier point in time, a wash cycle can be initiated earlier so that the wash is more effective at restoring the catalyst bed to a desired condition.

摘要翻译： 可以使用数据分组或窗口来分析反应堆或反应系统的监测条件随时间的行为，以识别时间平均值中的异常特征。 可以基于从分析生成的阈值来识别异常特征。 基于异常特征的识别，可采取纠正措施。 例如，当监测条件是催化剂床上的压降时，异常的检测可以指示在催化剂活性发生大的下降之前催化剂床的启动洗涤过程的时间。 通过在较早的时间点检测异常，可以更早地启动洗涤循环，使得洗涤在将催化剂床恢复到所需条件下更有效。