公开(公告)号：US11091613B2

公开(公告)日：2021-08-17

申请号：US16271419

申请日：2019-02-08

申请人： Afton Chemical Corporation

发明人： Nathaniel Cain ,  John Loper ,  Lawrence Cunningham ,  Joseph W. Roos

IPC分类号： C08F10/06 ,  C08F10/02 ,  C08F210/00 ,  C08F210/16 ,  C08L23/08 ,  C08F110/00 ,  C08K3/22 ,  C08K3/38 ,  C08F4/659

摘要： A copolymer including ethylene units and units of one or more C3-10 alpha-olefins. The copolymer has a number average molecular weight of less than 5,000 g/mol, as measured by GPC. The ethylene content of the copolymer is less than 80 mol %. At least 70% of molecules of the copolymer have an unsaturated group, and at least 70% of said unsaturated groups are located in a terminal vinylidene group or a tri-substituted isomer of a terminal vinylidene group. The copolymer has a crossover temperature of −20° C. or lower and/or a certain ethylene run length. Also disclosed are a method for making the copolymer and polyolefins plasticized with 1-40 wt % of the copolymer.

公开(公告)号：US20210171678A1

公开(公告)日：2021-06-10

申请号：US16772039

申请日：2018-06-12

申请人： AFTON CHEMICAL CORPORATION

发明人： Nathaniel Cain ,  John Loper ,  Lawrence Cunningham ,  Joseph W. Roos

IPC分类号： C08F210/16

摘要： A copolymer including ethylene units and units of one or more C3-10 alpha-olefins. The copolymer has a number average molecular weight of less than 5,000 g/mol, as measured by GPC. The ethylene unit content of the copolymer is less than 80 mol %. 70 mol % or greater of the copolymer has a carbon-carbon double bond in a terminal monomer unit, and at least 70 mol % of the terminal unsaturation is vinylidene, one or more tri-substituted isomers of the vinylidene or any combination thereof. The copolymer has a crossover temperature of −20° C. or lower and/or a certain average ethylene run length. Also disclosed are a method for making the copolymer and polyolefins plasticized with 1-40 wt. % of the copolymer. The copolymers may low metal (ash) and/or fluorine contents.

公开(公告)号：US20190177518A1

公开(公告)日：2019-06-13

申请号：US15904324

申请日：2018-02-24

申请人： Afton Chemical Corporation

发明人： Nathaniel Cain ,  John Loper

IPC分类号： C08L23/08 ,  C08F210/16 ,  C08K3/38 ,  C08K3/22

摘要： A copolymer including ethylene units and units of one or more C3-10 alpha-olefins. The copolymer has a number average molecular weight of less than 5,000 g/mol, as measured by GPC. The copolymers have low metal (ash) and/or fluorine contents.The ethylene content of the copolymer is less than 80 mol %. 70 mol % or greater of the copolymer has a carbon-carbon double bond in a terminal monomer unit, and at least 70 mol % of the terminal monomer units that have a carbon-carbon double bond have a terminal group selected from a vinylidene group and a tri-substituted isomer of a vinylidene group. The copolymer has a crossover temperature of −20° C. or lower and/or a certain ethylene run length. Also disclosed are a method for making the copolymer and polyolefins plasticized with 1-40 wt. % of the copolymer as well as methods of fanctionalizing the copolymer and products made with the functionalized coploymer.

公开(公告)号：US20190177632A1

公开(公告)日：2019-06-13

申请号：US16006401

申请日：2018-06-12

申请人： AFTON CHEMICAL CORPORATION

发明人： Nathaniel Cain ,  Michel Nuckols ,  John Loper ,  Lawrence Cunningham ,  William Colucci

IPC分类号： C10L10/04 ,  C10L10/06 ,  C10L1/236 ,  F02M65/00

摘要： A fuel composition including a fuel and a fuel additive including a fuel soluble detergent selected from succinimide compounds of the Formula (I), Mannich detergents of the formulae (IIa), and amine detergents of the formulae (IIIa) and (IIIb). The fuel soluble detergents are derived from a specific class of ethylene-alpha olefin copolymers having an Mn of less than 5,000 g/mol, an ethylene unit content of more than 40 mol % to less than 90 mol %; a terminal unsaturation of 70 mol % or greater; at least 70 mol % of the unsaturation is terminal vinylidene, one or more tri-substituted isomers of the terminal vinylidene or any combination thereof, an average ethylene run length of less than 2.6; and wherein nC2,Actual>nC2,Statistical. Methods employing the fuel compositions for operating diesel and gasoline engines to reduce injector valve deposits, valve sticking and injector nozzle fouling, and a method for stabilizing a diesel fuel composition.

公开(公告)号：US10221267B2

公开(公告)日：2019-03-05

申请号：US15377152

申请日：2016-12-13

申请人： Afton Chemical Corporation

发明人： Nathaniel Cain ,  John Loper ,  Lawrence Cunningham ,  Joseph W. Roos

IPC分类号： C08F210/16

摘要： A copolymer including ethylene units and units of one or more C3-10 alpha-olefins. The copolymer has a number average molecular weight of less than 5,000 g/mol, as measured by GPC. The ethylene content of the copolymer is less than 80 mol %. At least 70% of molecules of the copolymer have an unsaturated group, and at least 70% of said unsaturated groups are located in a terminal vinylidene group or a tri-substituted isomer of a terminal vinylidene group. The copolymer has a crossover temperature of −20° C. or lower and/or a certain ethylene run length. Also disclosed are a method for making the copolymer and polyolefins plasticized with 1-40 wt % of the copolymer.

公开(公告)号：US20180162972A1

公开(公告)日：2018-06-14

申请号：US15377152

申请日：2016-12-13

申请人： Afton Chemical Corporation

发明人： Nathaniel Cain ,  John Loper ,  Lawrence Cunningham ,  Joseph W. Roos

IPC分类号： C08F210/16

CPC分类号： C08F210/16 ,  B01J2231/20 ,  C08F210/06 ,  C08F4/65925 ,  C08F4/65912 ,  C08F2500/02 ,  C08F2500/06

摘要： A copolymer including ethylene units and units of one or more C3-10 alpha-olefins. The copolymer has a number average molecular weight of less than 5,000 g/mol, as measured by GPC. The ethylene content of the copolymer is less than 80 mol %. At least 70% of molecules of the copolymer have an unsaturated group, and at least 70% of said unsaturated groups are located in a terminal vinylidene group or a tri-substituted isomer of a terminal vinylidene group. The copolymer has a crossover temperature of −20° C. or lower and/or a certain ethylene run length. Also disclosed are a method for making the copolymer and polyolefins plasticized with 1-40 wt % of the copolymer.

公开(公告)号：US20210070900A1

公开(公告)日：2021-03-11

申请号：US16772025

申请日：2018-06-12

申请人： AFTON CHEMICAL CORPORATION

发明人： Nathaniel Cain ,  John Loper ,  Lawrence Cunningham ,  Joseph W. Roos

IPC分类号： C08F210/06 ,  C08F210/02 ,  C08L91/00 ,  C10L1/16 ,  C10L10/14 ,  C10L1/2383 ,  C10M149/10 ,  C10M145/14 ,  C10M157/04 ,  C10M169/04

摘要： Ethylene-C3-C10 alpha olefin copolymers, dispersants and lubricating oils/fuel compositions incorporating dispersants, and related methods are generally described herein. The copolymer may comprise ethylene-derived units and C3-C10 alpha-olefin-derived units. The C3-C10 alpha-olefin-derived units may have a carbon number from three to ten. For example, the C3-C10 alpha-olefin-derived units may be propylene-derived units. The dispersants may be made from copolymers having low metal and/or fluorine contents.

公开(公告)号：US20200231892A1

公开(公告)日：2020-07-23

申请号：US16251459

申请日：2019-01-18

申请人： Afton Chemical Corporation

发明人： John Loper

IPC分类号： C10M141/06 ,  C10M133/06 ,  C10M129/64 ,  C10M129/34

摘要： Engine oil \s and methods for use in soot-producing engines. The engine oil contains a major amount of a base oil and a dispersant reaction product of A) a hydrocarbyl-dicarboxylic acid or anhydride, and B) at least one polyamine, that is post-treated with C) an aromatic carboxylic acid, an aromatic polycarboxylic acid, or an aromatic anhydride, wherein all carboxylic acid or anhydride groups of C) are attached directly to an aromatic ring. A molar ratio of carboxyl groups from components A) and C) to nitrogen atoms from component B) of from 0.9 to 1.3 is used to make the dispersant which also has a molar ratio of component C) to component B) of at least 0.4 and when component B) has an average of 4-6 nitrogen atoms per molecule, a molar ratio of A) to B) is from 1.0 to 1.6.

公开(公告)号：US11046908B2

公开(公告)日：2021-06-29

申请号：US16246030

申请日：2019-01-11

申请人： Afton Chemical Corporation

发明人： Arturo Carranza ,  Sheng Jiang ,  John Loper

IPC分类号： C10M159/12 ,  C08G73/02 ,  C08G85/00 ,  C10M137/10 ,  C10N60/00

摘要： The present disclosure relates to oxazoline modified lubricant additives that have dispersant properties and lubricating oil compositions including such dispersant lubricant additives. The disclosure also relates to the use of lubricant compositions comprising the additives of the disclosure for improving the soot or sludge handling characteristics of an engine lubricant composition while providing robust and consistent frictional performance at the same time.

公开(公告)号：US11008527B2

公开(公告)日：2021-05-18

申请号：US16251459

申请日：2019-01-18

申请人： Afton Chemical Corporation

发明人： John Loper

IPC分类号： C10M141/06 ,  C10M129/34 ,  C10M129/64 ,  C10M133/06 ,  C10M133/56 ,  C10N30/00 ,  C10N40/25 ,  C10N30/06

摘要： Engine oil \s and methods for use in soot-producing engines. The engine oil contains a major amount of a base oil and a dispersant reaction product of A) a hydrocarbyl-dicarboxylic acid or anhydride, and B) at least one polyamine, that is post-treated with C) an aromatic carboxylic acid, an aromatic polycarboxylic acid, or an aromatic anhydride, wherein all carboxylic acid or anhydride groups of C) are attached directly to an aromatic ring. A molar ratio of carboxyl groups from components A) and C) to nitrogen atoms from component B) of from 0.9 to 1.3 is used to make the dispersant which also has a molar ratio of component C) to component B) of at least 0.4 and when component B) has an average of 4-6 nitrogen atoms per molecule, a molar ratio of A) to B) is from 1.0 to 1.6.