公开(公告)号：US20080296564A1

公开(公告)日：2008-12-04

申请号：US12056712

申请日：2008-03-27

申请人： Kazukuni NISHIMURA ,  Akihiko ITAMI ,  Fumitaka MOCHIZUKI ,  Hideya MIWA ,  Hidekazu KAWASAKI

发明人： Kazukuni NISHIMURA ,  Akihiko ITAMI ,  Fumitaka MOCHIZUKI ,  Hideya MIWA ,  Hidekazu KAWASAKI

IPC分类号： H01L51/46

CPC分类号： H01L51/0061 ,  H01G9/2004 ,  H01G9/2013 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0053 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0068 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/4226 ,  H01L2251/306 ,  Y02E10/542 ,  Y02E10/549

摘要： A photoelectric conversion element having a pair of electrodes, and a semiconductor layer comprising a semiconductor carrying a dye and an electrolyte layer is disclosed. The dye is represented by Formulas 1 or 2; in Formula 1, Ar1 and Ar2 are each an arylene or heterocyclic group, or a composite group of an arylene group and a heterocyclic group, each of which may have a substituent, Ar3 is an aryl or heterocyclic group or a composite group of an arylene group and a heterocyclic group, each of which may have a substituent, Ar1, Ar2 and Ar3 may form a ring by bonding with each other, X1 and X2 are each a straight chain residue having an acidic group which may have a mono-valent substituent, and one to eight saturated or unsaturated aliphatic hydrocarbon group having 5 to 30 carbon atoms are contained among Ar1, Ar2 and Ar3; in the formula, Ar11, Ar12, Ar13, Ar14 and Ar15 are each an arylene or heterocyclic group, or a composite group of an arylene group and a heterocyclic group, each of which may have a substituent, Ar11, Ar12, Ar13, Ar14 and Ar15 may form a ring by bonding with together, at least two of X11, X12, X13 and X14 are each an alkyl or alkenyl group having an acidic group which may have a mono-valent substituent and the remainders are each a hydrogen atom, and one to eight saturated or unsaturated aliphatic hydrocarbon group having 5 to 30 carbon atoms are contained among Ar11, Ar12, Ar13, Ar14 and Ar15.

摘要翻译： 公开了一种具有一对电极的光电转换元件，以及包含带有染料和电解质层的半导体的半导体层。 染料由式1或2表示; 在式1中，Ar 1和Ar 2各自为亚芳基或杂环基，或者可以具有取代基的亚芳基和杂环基的复合基，Ar 3为芳基或杂环基或亚芳基的复合基 基团和杂环基，其各自可以具有取代基，Ar1，Ar2和Ar3可以通过彼此键合形成环，X1和X2各自是具有可以具有一价取代基的酸性基团的直链残基 ，Ar 1，Ar 2，Ar 3中含有1〜8个碳原子数5〜30的饱和或不饱和脂肪族烃基。 在式中，Ar 11，Ar 12，Ar 13，Ar 14和Ar 15各自为亚芳基或杂环基，或者可以具有取代基的亚芳基和杂环基的复合基团Ar 11，Ar 12，Ar 13，Ar 14和 Ar15可以通过键合而形成环，X11，X12，X13和X14中的至少两个各自为具有可以具有一价取代基的酸性基团的烷基或烯基，余数各为氢原子， Ar11，Ar12，Ar13，Ar14和Ar15中含有1〜8个碳原子数5〜30的饱和或不饱和脂肪族烃基。

公开(公告)号：US20080173346A1

公开(公告)日：2008-07-24

申请号：US11873434

申请日：2007-10-17

申请人： Akihiko ITAMI ,  Fumitaka MOCHIZUKI ,  Kazukuni NISHIMURA

发明人： Akihiko ITAMI ,  Fumitaka MOCHIZUKI ,  Kazukuni NISHIMURA

IPC分类号： H01L31/0256 ,  H01L31/04

CPC分类号： H01L51/0059 ,  H01L51/0053 ,  H01L51/0057 ,  H01L51/006 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/4226 ,  H01L2251/306 ,  Y02E10/549

摘要： A photoelectric conversion element comprising a pair of electrodes containing therebetween a compound represented by Formula (1) or Formula (2):

摘要翻译： 一种光电转换元件，包括一对电极，其间包含由式（1）或式（2）表示的化合物：

公开(公告)号：US20080115826A1

公开(公告)日：2008-05-22

申请号：US11867464

申请日：2007-10-04

申请人： Kazukuni NISHIMURA ,  Akihiko ITAMI ,  Fumitaka MOCHIZUKI

发明人： Kazukuni NISHIMURA ,  Akihiko ITAMI ,  Fumitaka MOCHIZUKI

IPC分类号： H01L31/04 ,  H01L31/18

CPC分类号： H01L51/0059 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0053 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0065 ,  H01L51/0068 ,  H01L51/4226 ,  H01L2251/306 ,  Y02E10/542 ,  Y02E10/549 ,  Y02P70/521

摘要： A photoelectric conversion element comprising an electrically conductive support having thereon an oxide semiconductor electrode comprising an oxide semiconductor which is adsorbed with a dye, and a counter electrode facing the oxide semiconductor electrode through a charge transfer layer, wherein the dye is represented by Formula (1):

摘要翻译： 一种光电转换元件，包括其上具有氧化物半导体电极的导电支撑体，所述氧化物半导体电极包含吸附有染料的氧化物半导体，以及通过电荷转移层与所述氧化物半导体电极相对的对置电极，其中所述染料由式 ）：

公开(公告)号：US20100263726A1

公开(公告)日：2010-10-21

申请号：US12759474

申请日：2010-04-13

申请人： Hidekazu KAWASAKI ,  Akihiko ITAMI ,  Kazuya ISOBE ,  Hideya MIWA ,  Kazukuni NISHIMURA ,  Mayuko USHIRO

发明人： Hidekazu KAWASAKI ,  Akihiko ITAMI ,  Kazuya ISOBE ,  Hideya MIWA ,  Kazukuni NISHIMURA ,  Mayuko USHIRO

IPC分类号： H01L31/00

CPC分类号： H01L51/0072 ,  C09B21/00 ,  C09B23/14 ,  C09B57/008 ,  C09B57/02 ,  H01G9/2004 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0067 ,  H01L51/0073 ,  H01L51/4226 ,  Y02E10/542 ,  Y02E10/549

摘要： Provided is a photoelectric conversion element for which a novel compound (dye) exhibiting excellent adsorption to an oxide semiconductor and exhibiting high photoelectric conversion efficiency is used, and also provided is a solar cell employing the photoelectric conversion element. Disclosed is a dye-sensitizing type photoelectric conversion element possessing at least a pair of facing electrodes, a semiconductor layer possessing a semiconductor and a sensitizing dye supported on the semiconductor, and a charge transport layer, wherein the semiconductor layer and the charge transport layer are provided between the facing electrodes, and wherein the sensitizing dye comprises a compound represented by the following Formula (1).

摘要翻译： 提供了一种光电转换元件，其使用对氧化物半导体具有优异吸附性和显示高光电转换效率的新型化合物（染料），并且还提供了采用该光电转换元件的太阳能电池。 公开了一种染料敏化型光电转换元件，其具有至少一对面对电极，具有负极半导体的半导体和敏化染料的半导体层和电荷输送层，其中半导体层和电荷输送层为 提供在所述面对电极之间，并且其中所述敏化染料包含由下式（1）表示的化合物。

公开(公告)号：US20100294368A1

公开(公告)日：2010-11-25

申请号：US12779284

申请日：2010-05-13

申请人： Mayuko USHIRO ,  Akihiko ITAMI ,  Kazuya ISOBE ,  Hideya MIWA ,  Kazukuni NISHIMURA ,  Hidekazu KAWASAKI

发明人： Mayuko USHIRO ,  Akihiko ITAMI ,  Kazuya ISOBE ,  Hideya MIWA ,  Kazukuni NISHIMURA ,  Hidekazu KAWASAKI

IPC分类号： H01L51/46 ,  H01L51/44

CPC分类号： H01L51/4226 ,  H01L51/0051 ,  H01L51/0064 ,  H01L51/0086 ,  Y02E10/542 ,  Y02E10/549

摘要： A photoelectric conversion element having a semiconductor layer and a charge transfer layer provided between a first electrode and a second electrode is disclosed, and the semiconductor layer has light absorption in an absorption wavelength region at least 350 to 1,000 nm and has light transmission in the absorption wavelength region of the semiconductor, the charge transfer layer comprises a charge transfer complex formed by an electron-donating compound and an electron-accepting compound, and the charge-transfer complex has an absorption wavelength in the transmission wavelength of the semiconductor layer.

摘要翻译： 公开了一种具有设置在第一电极和第二电极之间的半导体层和电荷转移层的光电转换元件，并且该半导体层在至少350至1000nm的吸收波长区域中具有吸光性并且在吸收中具有透光性 电荷转移层包含由给电子化合物和受电子化合物形成的电荷转移络合物，并且电荷转移络合物在半导体层的透射波长中具有吸收波长。

公开(公告)号：US20100275988A1

公开(公告)日：2010-11-04

申请号：US12766236

申请日：2010-04-23

申请人： Hidekazu KAWASAKI ,  Akihiko ITAMI ,  Kazuya ISOBE ,  Hideya MIWA ,  Kazukuni NISHIMURA ,  Mayuko USHIRO

发明人： Hidekazu KAWASAKI ,  Akihiko ITAMI ,  Kazuya ISOBE ,  Hideya MIWA ,  Kazukuni NISHIMURA ,  Mayuko USHIRO

IPC分类号： H01L31/00

CPC分类号： H01L51/006 ,  H01G9/2031 ,  H01G9/2059 ,  H01M14/005 ,  Y02E10/542 ,  Y02E10/549

摘要： A dye-sensitized photoelectric conversion element, comprises a pair of electrodes arranged opposite to each other; a semiconductor layer including a semiconductor supporting a sensitizing dye; and an electrolyte layer. At least the semiconductor layer and the electrolyte layer are provided between the pair of electrodes, and the sensitizing dye contains a compound represented by the following Formula (1).

摘要翻译： 染料敏化光电转换元件，包括彼此相对布置的一对电极; 包含支持敏化染料的半导体的半导体层; 和电解质层。 至少半导体层和电解质层设置在该对电极之间，敏化染料含有由下式（1）表示的化合物。

公开(公告)号：US20100288360A1

公开(公告)日：2010-11-18

申请号：US12758240

申请日：2010-04-12

申请人： Hidekazu KAWASAKI ,  Akihiko ITAMI ,  Kazuya ISOBE ,  Hideya MIWA ,  Kazukuni NISHIMURA ,  Mayuko USHIRO

发明人： Hidekazu KAWASAKI ,  Akihiko ITAMI ,  Kazuya ISOBE ,  Hideya MIWA ,  Kazukuni NISHIMURA ,  Mayuko USHIRO

IPC分类号： H01L31/00 ,  G03G5/04

CPC分类号： C09B57/008 ,  C09B23/148 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0059 ,  H01L51/4226 ,  H01M14/005 ,  Y02E10/542 ,  Y02E10/549

摘要： Disclosed is a photoelectric conversion element comprising a conductive support and provided thereon, a semiconductor layer, a charge transporting layer and an opposed electrode, the semiconductor layer comprising a semiconductor with a dye, wherein the dye is a compound represented by the following formula (1).

摘要翻译： 公开了一种光电转换元件，其包括导电支撑体，其上设置有半导体层，电荷输送层和相对电极，所述半导体层包含具有染料的半导体，其中所述染料是由下式（1 ）。

公开(公告)号：US20100282322A1

公开(公告)日：2010-11-11

申请号：US12766493

申请日：2010-04-23

申请人： Hidekazu KAWASAKI ,  Akihiko ITAMI ,  Kazuya ISOBE ,  Hideya MIWA ,  Kazukuni NISHIMURA ,  Mayuko USHIRO

发明人： Hidekazu KAWASAKI ,  Akihiko ITAMI ,  Kazuya ISOBE ,  Hideya MIWA ,  Kazukuni NISHIMURA ,  Mayuko USHIRO

IPC分类号： H01L31/00

CPC分类号： H01L51/0059 ,  C09B23/105 ,  C09B23/12 ,  C09B23/148 ,  C09B57/008 ,  C09B57/02 ,  C09B69/008 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/4226 ,  Y02E10/52 ,  Y02E10/542 ,  Y02E10/549

摘要： Provided is a photoelectric conversion element containing a pair of opposite electrodes having therebetween: a semiconductor layer containing a sensitizing dye which is supported by a semiconductor; and a charge transport layer, wherein the sensitizing dye is a compound represented by Formula (1),

摘要翻译： 提供了一种光电转换元件，其包含一对相对电极，其间具有：包含由半导体支撑的敏化染料的半导体层; 和电荷输送层，其中所述敏化染料是由式（1）表示的化合物，

公开(公告)号：US20090250115A1

公开(公告)日：2009-10-08

申请号：US12416959

申请日：2009-04-02

申请人： Hideya MIWA ,  Akihiko ITAMI ,  Kazuya ISOBE ,  Kazukuni NISHIMURA ,  Hidekazu KAWASAKI ,  Mayuko USHIRO

发明人： Hideya MIWA ,  Akihiko ITAMI ,  Kazuya ISOBE ,  Kazukuni NISHIMURA ,  Hidekazu KAWASAKI ,  Mayuko USHIRO

IPC分类号： H01L31/0256

CPC分类号： H01L51/0059 ,  H01G9/2004 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0061 ,  H01L51/4226 ,  Y02E10/542 ,  Y02E10/549

摘要： Provided are a newly developed dye-sensitizing type photoelectric conversion element employing a highly durable sensitizing dye, exhibiting high photoelectric conversion efficiency, and a solar cell fitted with the photoelectric conversion element. Also disclosed is a photoelectric conversion element comprising a compound represented by Formula (1) between a pair of facing electrodes.

摘要翻译： 提供一种新开发的使用高度耐用的增感染料，具有高光电转换效率的染料敏化型光电转换元件和装有光电转换元件的太阳能电池。 还公开了一种光电转换元件，其包括在一对相对电极之间由式（1）表示的化合物。

公开(公告)号：US20130125987A1

公开(公告)日：2013-05-23

申请号：US13673482

申请日：2012-11-09

申请人： Hidekazu KAWASAKI ,  Kazukuni NISHIMURA ,  Hideya MIWA

发明人： Hidekazu KAWASAKI ,  Kazukuni NISHIMURA ,  Hideya MIWA

IPC分类号： H01L51/00 ,  H01L51/42

CPC分类号： H01L51/0036 ,  C09B23/005 ,  C09B23/0058 ,  C09B23/148 ,  C09B57/008 ,  H01G9/2013 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0035 ,  H01L51/0061 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/42 ,  Y02E10/542 ,  Y02E10/549

摘要： The object is to provide a photoelectric conversion element having excellent photoelectric conversion efficiency, and high durability.A photoelectric conversion element comprising a substrate, a first electrode, a photoelectric conversion layer containing a semiconductor and a sensitizing dye, a hole transport layer, and a second electrode, in which the sensitizing dye is represented by the following Chemical Formula (1):

摘要翻译： 本发明的目的是提供一种具有优异的光电转换效率和高耐久性的光电转换元件。 一种光电转换元件，包括基底，第一电极，含有半导体的光电转换层和增感染料，空穴传输层和第二电极，其中敏化染料由以下化学式（1）表示：