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公开(公告)号：US5229057A
公开(公告)日：1993-07-20
申请号：US633955
申请日：1990-12-26
摘要： High-strength polyvinyl alcohol fiber is provided by extruding a polyvinyl alcohol dope solution through a spinneret into a coagulating bath, the spinneret being located such that substantially only its dope-extruding surface contacts the coagulating bath. This process can produce stably and at a low cost polyvinyl alcohol fibers with excellent strength.
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公开(公告)号：US6048641A
公开(公告)日：2000-04-11
申请号：US237810
申请日：1999-01-27
申请人： Akio Ohmory , Hayami Yoshimochi , Tomoyuki Sano , Satoru Kobayashi , Syunpei Naramura , Masahiro Satoh
发明人： Akio Ohmory , Hayami Yoshimochi , Tomoyuki Sano , Satoru Kobayashi , Syunpei Naramura , Masahiro Satoh
摘要： A fiber of sea-islands phase separation wherein the sea component comprises a vinyl alcohol based polymer with high orientation and great crystallinity and the islands component comprises a water-insoluble cellulose based polymer with excellent absorptivity of alkaline solutions, thermal resistance and heat fusion resistance, and wherein the size of the islands is 0.03 to 10 .mu.m and the strength is 3 g/d or more, is readily disintegrated into a fibril of a diameter of 0.05 to 8 .mu.m when a mechanical stress is imposed onto the fiber wet in water. From the fibril with good hydrophilicity, high strength, great particle captivity and excellent reinforcing performance, and additionally with good absorptivity of alkaline solutions and great thermal resistance and heat fusion resistance, none of the fiber components therein is solubilized during fibrillation. Neither a beating process nor a beating solution causes foaming or environmental pollution. The fibril is extremely useful for use in separator sheets for alkaline batteries, reinforcing fibers of cement slate plates, reinforcing fibers of frictional materials and the like.
摘要翻译： 海岛相分离纤维，其中海组分包含具有高取向和高结晶度的乙烯醇基聚合物，岛组分包括具有优异的碱溶液吸收性，耐热性和耐热熔性的水不溶性纤维素基聚合物， 并且其中岛的尺寸为0.03〜10μm，强度为3g / d以上时，当对纤维进行机械应力湿润时，容易分解成直径为0.05〜8μm的原纤维 水。 从具有良好亲水性，高强度，巨大的颗粒俘获和优异的增强性能的原纤维，另外具有良好的碱溶液吸收性和高耐热性和耐热熔性，其中纤维成分在原纤维化过程中不溶解。 打浆过程和打浆液都不会引起起泡或环境污染。 原纤维非常适用于碱性电池用隔板，水泥板状板的增强纤维，摩擦材料的增强纤维等。
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公开(公告)号：US5972501A
公开(公告)日：1999-10-26
申请号：US983133
申请日：1998-01-20
申请人： Akio Ohmory , Hayami Yoshimochi , Tomoyuki Sano , Satoru Kobayashi , Syunpei Naramura , Masahiro Satoh
发明人： Akio Ohmory , Hayami Yoshimochi , Tomoyuki Sano , Satoru Kobayashi , Syunpei Naramura , Masahiro Satoh
CPC分类号： D01F8/10 , D01F8/02 , Y10T428/2924 , Y10T428/2929
摘要： A fiber of sea-islands phase separation wherein the sea component comprises a vinyl alcohol based polymer with high orientation and great crystallinity and the islands component comprises a water-insoluble cellulose based polymer with excellent absorptivity of alkaline solutions, thermal resistance and heat fusion resistance, and wherein the size of the islands is 0.03 to 10 .mu.m and the strength is 3 g/d or more, is readily disintegrated into a fibril of a diameter of 0.05 to 8 .mu.m when a mechanical stress is imposed onto the fiber wet in water.From the fibril with good hydrophilicity, high strength, great particle captivity and excellent reinforcing performance, and additionally with good absorptivity of alkaline solutions and great thermal resistance and heat fusion resistance, none of the fiber components therein is solubilized during fibrillation. Neither a beating process nor a beating solution causes foaming or environmental pollution.The fibril is extremely useful for use in separator sheets for alkaline batteries, reinforcing fibers of cement slate plates, reinforcing fibers of frictional materials and the like.
摘要翻译： PCT No.PCT / JP96 / 01322 Sec。 371日期1998年1月20日 102（e）1998年1月20日PCT PCT 1996年5月20日PCT公布。 第WO97 / 44511号公报 日期1997年11月27日海岛相分离纤维，其中海组分包含具有高取向和高结晶度的乙烯醇基聚合物，岛组分包含具有优异的碱溶液吸收性，耐热性的水不溶性纤维素基聚合物 耐热融合性，并且岛的尺寸为0.03〜10μm，强度为3g / d以上时，当施加机械应力时容易分解为直径为0.05〜8μm的原纤维 在水中浸湿纤维。 从具有良好亲水性，高强度，巨大的颗粒俘获和优异的增强性能的原纤维，另外具有良好的碱溶液吸收性和高耐热性和耐热熔性，其中纤维成分在原纤维化过程中不溶解。 打浆过程和打浆液都不会引起起泡或环境污染。 原纤维非常适用于碱性电池用隔板，水泥板状板的增强纤维，摩擦材料的增强纤维等。
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公开(公告)号：US6124058A
公开(公告)日：2000-09-26
申请号：US237809
申请日：1999-01-27
申请人： Akio Ohmory , Hayami Yoshimochi , Tomoyuki Sano , Satoru Kobayashi , Syunpei Naramura , Masahiro Satoh
发明人： Akio Ohmory , Hayami Yoshimochi , Tomoyuki Sano , Satoru Kobayashi , Syunpei Naramura , Masahiro Satoh
CPC分类号： D01F8/02 , D01F8/10 , Y10T428/2924
摘要： A fiber of sea-islands phase separation wherein the sea component comprises a vinyl alcohol based polymer with high orientation and great crystallinity and the islands component comprises a water-insoluble cellulose based polymer with excellent absorptivity of alkaline solutions, thermal resistance and heat fusion resistance, and wherein the size of the islands is 0.03 to 10 .mu.m and the strength is 3 g/d or more, is readily disintegrated into a fibril of a diameter of 0.05 to 8 .mu.m when a mechanical stress is imposed onto the fiber wet in water.From the fibril with good hydrophilicity, high strength, great particle captivity and excellent reinforcing performance, and additionally with good absorptivity of alkaline solutions and great thermal resistance and heat fusion resistance, none of the fiber components therein is solubilized during fibrillation. Neither a beating process nor a beating solution causes foaming or environmental pollution.The fibril is extremely useful for use in separator sheets for alkaline batteries, reinforcing fibers of cement slate plates, reinforcing fibers of frictional materials and the like.
摘要翻译： 海岛相分离纤维，其中海组分包含具有高取向和高结晶度的乙烯醇基聚合物，岛组分包括具有优异的碱溶液吸收性，耐热性和耐热熔性的水不溶性纤维素基聚合物， 并且其中岛的尺寸为0.03〜10μm，强度为3g / d以上时，当对纤维进行机械应力湿润时，容易分解成直径为0.05〜8μm的原纤维 水。 从具有良好亲水性，高强度，巨大的颗粒俘获和优异的增强性能的原纤维，另外具有良好的碱溶液吸收性和高耐热性和耐热熔性，其中纤维成分在原纤维化过程中不溶解。 打浆过程和打浆液都不会引起起泡或环境污染。 原纤维非常适用于碱性电池用隔板，水泥板状板的增强纤维，摩擦材料的增强纤维等。
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公开(公告)号：US5861213A
公开(公告)日：1999-01-19
申请号：US726930
申请日：1996-10-07
申请人： Akio Ohmory , Hayami Yoshimochi , Tomoyuki Sano , Satoru Kobayashi , Syunpei Naramura , Masahiro Satoh
发明人： Akio Ohmory , Hayami Yoshimochi , Tomoyuki Sano , Satoru Kobayashi , Syunpei Naramura , Masahiro Satoh
IPC分类号： C04B16/06 , D01F6/34 , D01F6/36 , D01F6/38 , D01F8/08 , D01F8/10 , D04H1/42 , D04H13/02 , D01F6/14 , C08F16/06 , D01D5/12 , D01F6/00
CPC分类号： D01F8/10 , C04B16/0641 , D01F6/34 , D01F6/36 , D01F6/38 , D01F8/08 , D04H1/4282 , D04H1/43 , D04H1/4309 , D04H1/4382 , D04H13/02 , Y10T428/2904 , Y10T428/2905 , Y10T428/2929 , Y10T428/2931 , Y10T428/2967 , Y10T428/2973 , Y10T428/2975 , Y10T428/2976 , Y10T428/2978 , Y10T428/298
摘要： By dissolving a vinyl alcohol polymer (A) and an incompatible vinyl polymer (B), preferably an acrylonitrile polymer in a common solvent to prepare a spinning stock solution of a phase separation structure wherein the polymer (B) is present at particle sizes of 2 to 50 .mu.m, and wet spinning or dry-wet spinning the resulting spinning stock solution in a solidifying bath containing a mixture of an organic solvent capable of solidifying both the polymers (A) and (B) and the solvent of the spinning stock solution at a weight ratio of 25/75 to 85/15, thereby drawing the resulting yarn by 8-fold or more, a fiber is provided; and from the fiber can be produced a fibril with good hydrophilicity, a higher strength, and excellent heat fusion resistance, along with excellent wiping performance, filtering performance, micro-particle capturing properties and reinforcing performance, readily, stably and inexpensively.
摘要翻译： 通过将乙烯醇聚合物（A）和不相容的乙烯基聚合物（B），优选丙烯腈聚合物溶解在常用溶剂中以制备相分离结构的纺丝原液，其中聚合物（B）以2的粒径存在 将得到的纺丝原液溶解在含有可固化聚合物（A）和（B）的有机溶剂与纺丝原液的溶剂的混合物的固化浴中进行湿法纺丝或干湿纺 以25/75至85/15的重量比，由此将所得纱线拉伸8倍或更多，提供纤维; 并且能够容易地，稳定且低成本地制造具有良好的亲水性，高强度，优异的耐热熔性的原纤维，以及优异的擦拭性能，过滤性能，微粒捕集性能和增强性能。
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公开(公告)号：US6066396A
公开(公告)日：2000-05-23
申请号：US319239
申请日：1999-06-07
申请人： Shinya Inada , Masahiro Satoh , Hayami Yoshimochi , Akio Ohmory , Isao Tokunaga , Akira Kubotsu , Masakazu Nishiyama , Tomoyuki Sano
发明人： Shinya Inada , Masahiro Satoh , Hayami Yoshimochi , Akio Ohmory , Isao Tokunaga , Akira Kubotsu , Masakazu Nishiyama , Tomoyuki Sano
CPC分类号： D01F6/50 , D01F1/07 , Y10T428/2924 , Y10T428/2929
摘要： A vinyl-alcohol-based polymer and vinyl-halide-based polymer are dissolved in a common organic solvent for them, a typical example of which is dimethylsulfoxide, to obtain a dope wherein a solution of the vinyl-halide-based polymer having a particle size of 1-50 .mu.m is present in the solution of the vinyl-alcohol-based polymer. This dope is spun into a low temperature solidifying bath comprising a solidifying solvent such as methanol, and the organic solvent. The resultant is subjected to extraction, drying, dry heat drawing, and optional heat shrinking or acetalization to obtain fiber. In the fiber thus obtained, the vinyl-alcohol-based polymer makes sea phases, and the vinyl-halide-based polymer makes island phases whose size is 0.1-3 .mu.m. The crystallinity degree of the vinyl-alcohol-based polymer is 65-85%.The polyvinyl-alcohol-based flame retardant fiber is useful for clothes, industrial materials, living materials and the like. It can be produced at low costs, and has excellent spinning stability and dimensional stability in hot water.
摘要翻译： PCT No.PCT / JP98 / 04424 Sec。 371日期1999年6月7日 102（e）日期1999年6月7日PCT提交1998年10月1日PCT公布。 公开号WO99 / 18267 日期1999年04月15日乙烯基醇类聚合物和乙烯基卤化物类聚合物溶解在普通的有机溶剂中，其典型的例子是二甲基亚砜，以获得涂料，其中乙烯基卤化物 - 乙烯醇类聚合物的溶液中存在粒径为1-50μm的聚合物。 将该纺丝液纺成包含固化溶剂如甲醇和有机溶剂的低温固化浴。 将所得物进行萃取，干燥，干热拉伸和任选的热收缩或缩醛化以获得纤维。 在由此获得的纤维中，乙烯醇系聚合物形成海相，卤化乙烯基系聚合物形成尺寸为0.1〜3μm的岛相。 乙烯醇系聚合物的结晶度为65〜85％。 聚乙烯醇类阻燃纤维可用于衣服，工业材料，生活材料等。 可以低成本生产，在热水中具有优异的纺丝稳定性和尺寸稳定性。
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7.发明授权Vinyl alcohol units-containing polymer composite fiber having resistance to hot water and wet heat and process for its production 失效含有乙烯基醇单元的聚合物复合纤维，具有耐热水和耐湿热性能及其生产工艺
公开(公告)号：US5340650A
公开(公告)日：1994-08-23
申请号：US19444
申请日：1993-02-18
申请人： Kiyoshi Hirakawa , Izumi Watadani , Kazuhiko Tanaka , Masao Kawamoto , Takaaki Tanaka , Hirohumi Sano , Hayami Yoshimochi , Masahiro Sato
发明人： Kiyoshi Hirakawa , Izumi Watadani , Kazuhiko Tanaka , Masao Kawamoto , Takaaki Tanaka , Hirohumi Sano , Hayami Yoshimochi , Masahiro Sato
IPC分类号： C08F8/42 , D06M13/503 , D02G3/00
CPC分类号： D06M13/503 , C08F8/42 , Y10T428/2929 , Y10T442/2877 , Y10T442/313 , Y10T442/608 , Y10T442/681
摘要： A fiber comprising a vinyl alcohol units-containing polymer, said polymer being modified at the oxygen atoms of its alcoholic hydroxyl groups with a group represented by the following formula I ##STR1## wherein M represents a chelate-forming metal atom and R represents an alkyl group. The fiber has excellent resistance to hot water and wet heat and does not stick, adhere or shrink even when dyed at high temperatures or treated by steam ironing, thus proving to be of markedly high commercial value.
摘要翻译： 一种包含含乙烯醇单元的聚合物的纤维，所述聚合物在其醇羟基的氧原子上被改性为具有下式I其中M表示螯合形成金属原子的基团，R表示 烷基。 该纤维具有优异的耐热水和耐湿热性，即使在高温下染色或者通过蒸汽熨烫处理也不会粘附，粘附或收缩，从而证明具有显着的商业价值。
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8.发明授权Method and device for compensating temperature-dependent characteristic change in ion-sensitive FET transducer 失效用于补偿离子敏感FET传感器温度依赖特性变化的方法和装置
公开(公告)号：US4385274A
公开(公告)日：1983-05-24
申请号：US257605
申请日：1981-04-27
IPC分类号： G01N27/414 , G01N27/00
CPC分类号： G01N27/414
摘要： An electrical circuitry for use in the measurement of the activity of ions in an electrolyte solution carried out by the use of an ion-sensitive field-effect transistor transducer having a gate or ion sensitive layer, a source and a drain. The measurement is carried out by adjusting the drain current flowing through the field-effect transistor to a predetermined value such that the temperature dependency of the electroconductivity of the channel of the transistor becomes equal to the sum of the temperature dependency of the potential at an interface between a reference electrode and the electrolyte solution and the temperature dependency of the potential at an interface between the ion-sensitive layer and the electrolyte solution.
摘要翻译： 用于测量电解质溶液中离子活性的电路，其通过使用具有栅极或离子敏感层，源极和漏极的离子敏感场效应晶体管换能器来执行。 通过将流过场效应晶体管的漏极电流调节到预定值来进行测量，使得晶体管的沟道的导电性的温度依赖性变得等于界面处的电位的温度依赖性之和 在参考电极和电解质溶液之间以及离子敏感层和电解质溶液之间的界面处的电位的温度依赖性。
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