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公开(公告)号:US09028976B2
公开(公告)日:2015-05-12
申请号:US13118273
申请日:2011-05-27
申请人: Akira Ebisawa , Hajime Amano , Sumiko Kitagawa , Tetsushi Inoue
发明人: Akira Ebisawa , Hajime Amano , Sumiko Kitagawa , Tetsushi Inoue
IPC分类号: H01L51/50 , C07C13/70 , C07C211/54 , C07D209/86 , C07D211/04 , C09K11/00 , C07C13/62 , C07D213/06
CPC分类号: C07D209/86 , C07C13/62 , C07C211/54 , C07C2603/24 , C07C2603/52 , C07D213/06 , C09K11/00 , H01L51/50 , H01L51/5012 , Y10S428/917
摘要: A highly stable organic EL material having the properties of both benzofluoranthene and anthracene structures is provided. The organic EL device has at least one organic compound layer containing a compound presented by the general formula (I) below: (in which L is a linking group linking any one of the positions 1 to 12 and any one of the positions 13 to 22; the unlinked positions 1 to 22 are substituted by any of a hydrogen atom, substituted or unsubstituted aryl group, substituted or unsubstituted heterocyclic group, substituted or unsubstituted alkyl group, and aromatic amino group; and L presents any of a single bond, substituted or unsubstituted arylene group, substituted or unsubstituted heterocyclic group, and substituted or unsubstituted alkylene group).
摘要翻译: 提供了具有苯并荧蒽和蒽结构两者性质的高度稳定的有机EL材料。 有机EL元件具有至少一种含有下述通式(I)表示的化合物的有机化合物层:(其中L是连接位置1至12和任一位置13至22中的任何一个的连接基团 取代或未取代的芳基,取代或未取代的杂环基,取代或未取代的烷基和芳香族氨基中的任一个取代或未取代的芳基,L表示任意的单键,取代或未取代的芳基, 未取代的亚芳基,取代或未取代的杂环基,取代或未取代的亚烷基)。
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公开(公告)号:US20110295017A1
公开(公告)日:2011-12-01
申请号:US13118273
申请日:2011-05-27
申请人: Akira EBISAWA , Hajime Amano , Sumiko Kitagawa , Tetsushi Inoue
发明人: Akira EBISAWA , Hajime Amano , Sumiko Kitagawa , Tetsushi Inoue
IPC分类号: C07C13/70 , C07C211/54 , C07D209/86 , C07D211/04
CPC分类号: C07D209/86 , C07C13/62 , C07C211/54 , C07C2603/24 , C07C2603/52 , C07D213/06 , C09K11/00 , H01L51/50 , H01L51/5012 , Y10S428/917
摘要: A highly stable organic EL material having the properties of both benzofluoranthene and anthracene structures is provided.The organic EL device has at least one organic compound layer containing a compound presented by the general formula (I) below: (in which L is a linking group linking any one of the positions 1 to 12 and any one of the positions 13 to 22; the unlinked positions 1 to 22 are substituted by any of a hydrogen atom, substituted or unsubstituted aryl group, substituted or unsubstituted heterocyclic group, substituted or unsubstituted alkyl group, and aromatic amino group; and L presents any of a single bond, substituted or unsubstituted arylene group, substituted or unsubstituted heterocyclic group, and substituted or unsubstituted alkylene group).
摘要翻译: 提供了具有苯并荧蒽和蒽结构两者性质的高度稳定的有机EL材料。 有机EL元件具有至少一种含有下述通式(I)表示的化合物的有机化合物层:(其中L是连接位置1至12和任一位置13至22中的任何一个的连接基团 取代或未取代的芳基,取代或未取代的杂环基,取代或未取代的烷基和芳香族氨基中的任一个取代或未取代的芳基,L表示任意的单键,取代或未取代的芳基, 未取代的亚芳基,取代或未取代的杂环基,取代或未取代的亚烷基)。
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公开(公告)号:US5154958A
公开(公告)日:1992-10-13
申请号:US736976
申请日:1991-07-29
CPC分类号: G11B7/2472 , C09B23/083 , G11B7/24 , G11B7/2495 , G11B7/2538 , G11B7/246 , G11B7/2542 , G11B7/2595 , Y10S428/913 , Y10S430/146 , Y10T428/24479 , Y10T428/31678
摘要: An optical recording disk comprising a grooved substrate, a dye-containing recording layer, and a reflective layer in close contact with the recording layer is recorded by directing recording light to the recording layer in the groove to form pits and reproduced by directing reproducing light to the pits. The substrate is formed of a cyclic olefin polymer. A photo-stabilized cyanine dye in the form of an indolenine cyanine dye cation-quencher anion ionic combination has relatively constant values of n and k with a variation in the wavelength of recording/reproducing light. Then the disk is resistant against light, heat and water to ensure satisfactory performance according to the CD standard.
摘要翻译: 通过将记录光引导到凹槽中的记录层来记录包括沟槽基板,含染料的记录层和与记录层紧密接触的反射层的光学记录盘,以形成凹坑并通过将再现光引导到 坑。 基材由环烯烃聚合物形成。 吲哚青花青染料阳离子猝灭剂阴离子离子组合形式的光稳定花青染料具有相对恒定的n和k值,具有记录/再现光的波长的变化。 然后光盘耐光,热和水,以确保符合CD标准的令人满意的性能。
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公开(公告)号:US07097917B1
公开(公告)日:2006-08-29
申请号:US10125480
申请日:2002-04-19
申请人: Tetsuji Fujita , Sumiko Kitagawa , Tetsushi Inoue
发明人: Tetsuji Fujita , Sumiko Kitagawa , Tetsushi Inoue
IPC分类号: H05B33/14
CPC分类号: C07C13/62 , C07C211/54 , C07C211/61 , C07C2603/52 , C07D213/16 , C07D333/08 , C07D333/76 , C09K11/06 , C09K2211/1003 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , C09K2211/1092 , H01L51/0054 , H01L51/0055 , H01L51/0058 , H01L51/0059 , H01L51/006 , H01L51/0067 , H01L51/0068 , H01L51/50 , H01L2251/308 , H05B33/14 , Y10S428/917
摘要: A compound for use in organic EL devices comprising Xn—Y wherein X is a compound of the formula and Y is a linking group and R1 to R8 and a to d are hydrogen, an alkyl group, an aryl group which may be substituted, an allyl group which may be substituted, a heterocyclic group which may be substituted, an amino group, or an arylamino group which may be substituted.
摘要翻译: 用于有机EL器件的化合物,其包含<?in-line-formula description =“In-line formula”end =“lead”?> X
-Y <?in-line-formula description =“在线式”末端=“尾”→其中X是下式的化合物,Y是连接基团,R 1至R 8和 至d为氢,烷基,可被取代的芳基,可被取代的烯丙基,可被取代的杂环基,氨基或可被取代的芳基氨基。 -
公开(公告)号:US5574715A
公开(公告)日:1996-11-12
申请号:US358681
申请日:1994-12-19
IPC分类号: G11B7/246 , G11B7/2463 , G11B7/2467 , G11B7/247 , G11B7/2472 , G11B7/249 , G11B7/2492 , G11B7/2495 , G11B7/253 , G11B7/2531 , G11B7/2533 , G11B7/2534 , G11B7/254 , G11B7/2542 , G11B7/258 , G11B7/2595 , G11B7/24 , G03C1/72
CPC分类号: G11B7/2495 , G11B7/246 , G11B7/2472 , G11B7/249 , G11B2007/24612 , G11B7/2463 , G11B7/2467 , G11B7/248 , G11B7/2492 , G11B7/2531 , G11B7/2533 , G11B7/2534 , G11B7/2542 , G11B7/256 , G11B7/2595
摘要: An optical recording medium having a recording layer and a reflective layer closely stacked on a substrate, wherein recording is carried out by directing recording light to the recording layer to form pits and reproduction is carried out by directing reproducing light to the recording layer. The recording layer contains a light absorbing dye, typically cyanine dye and a bisphenylenedithiol copper complex quencher in either independent form or ionically bonded form. The quencher characterized by a low coefficient of extinction can be added in a sufficient amount to provide the recording layer with light resistance while maintaining recording/reproducing performance.
摘要翻译: 一种光记录介质,具有紧密堆叠在基板上的记录层和反射层,其中通过将记录光引导到记录层以形成凹坑进行记录,并通过将再现光引导到记录层来进行再现。 记录层含有光吸收染料,通常为花青染料和独立形式或离子键形式的双亚苯基二硫酚铜络合物猝灭剂。 可以以足够的量添加以低消光系数为特征的猝灭剂,从而为记录层提供耐光性,同时保持记录/再现性能。
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公开(公告)号:US5776656A
公开(公告)日:1998-07-07
申请号:US686658
申请日:1996-07-26
申请人: Masahiro Shinkai , Sumiko Kitagawa , Kenryo Namba , Emiko Yoshimura , Atsushi Monden , Takahiko Suzuki
发明人: Masahiro Shinkai , Sumiko Kitagawa , Kenryo Namba , Emiko Yoshimura , Atsushi Monden , Takahiko Suzuki
CPC分类号: G11B7/2495 , G11B7/241 , G11B7/2472 , G11B7/248 , G11B2007/24618 , G11B2007/2571 , G11B2007/25715 , G11B7/2467 , G11B7/2531 , G11B7/2533 , G11B7/2534 , G11B7/2536 , G11B7/2542 , G11B7/2595 , Y10S430/146
摘要: The invention provides an optical recording medium comprising at least two recording layers containing a dye. At least two layers of the recording layers have different optical constants, and at least one among these recording layers having different optical constants contains a dye which forms a thin film having an absorption spectrum whose half-value width is up to 170 nm. This construction permits the medium to be written and read in a conventional wavelength range of about 780 nm and a shorter wavelength range of about 630-680 nm.
摘要翻译: 本发明提供一种包含至少两个包含染料的记录层的光学记录介质。 至少两层记录层具有不同的光学常数,并且具有不同光学常数的这些记录层中的至少一个包含形成具有半值宽度高达170nm的吸收光谱的薄膜的染料。 这种结构允许介质以约780nm的常规波长范围和约630-680nm的较短波长范围进行写入和读取。
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公开(公告)号:US6017604A
公开(公告)日:2000-01-25
申请号:US696570
申请日:1996-08-16
申请人: Sumiko Kitagawa , Masahiro Shinkai , Kenryo Namba
发明人: Sumiko Kitagawa , Masahiro Shinkai , Kenryo Namba
IPC分类号: C09B47/067 , G11B7/248 , B32B3/00
CPC分类号: G11B7/248 , C09B47/0675 , Y10S428/913 , Y10S430/146 , Y10T428/21
摘要: A phthalocyanine dye of specific structure represented by the following general formula (1) or (2): ##STR1## where Y is O or S attached to the phthalocyanine ring, Z is the group of atoms required to complete a carbon or heterocyclic ring together with C, A.sub.1 is a monovalent substituent bulkier than a hydrogen atom, and each of X.sub.1 and X.sub.2 is H or a monovalent substituent or, in the alternative, X.sub.1 and X.sub.2, taken together, form a single bond, ##STR2## where Y and Z.sub.1 have the same meanings as defined for Y and Z in formula (1). A.sub.11 is a monovalent substituent having a branched alkyl group, which is attached to the ring completed by Z.sub.1, and s1 is the number of A.sub.11, is used for the recording layer of an optical recording layer. This phthalocyanine dye is unlikely to attack a substrate material such as PC, can be handled with ease, and has a high solubility in a coating solvent advantageous for film formation, for instance, an alcoholic solvent, e.g., ethyl cellosolve or an aliphatic hydrocarbon solvent.
摘要翻译: 由以下通式(1)或(2)表示的具有特定结构的酞菁染料:其中Y是连接到酞菁环上的O或S,Z是与C一起形成碳或杂环所需的原子团, A1是比氢原子更大的一价取代基,X 1和X 2各自为H或一价取代基,或者作为选择,X 1和X 2一起形成单键,其中Y和Z 1具有与 对于式(1)中的Y和Z定义。 A11是具有支链烷基的一价取代基,其连接到由Z1完成的环上,s1是A11的数,用于光学记录层的记录层。 这种酞菁染料不太可能侵蚀诸如PC的基材,可以容易地处理,并且在有利于成膜的涂布溶剂中具有高溶解度,例如醇溶剂,例如乙基溶纤剂或脂族烃溶剂 。
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公开(公告)号:US5679430A
公开(公告)日:1997-10-21
申请号:US665283
申请日:1996-06-17
CPC分类号: G11B7/249 , G11B7/241 , G11B7/246 , G11B2007/24612 , G11B7/2467 , G11B7/2472 , G11B7/248 , G11B7/2492 , G11B7/2495 , G11B7/2534 , G11B7/2542 , G11B7/2595 , Y10S428/913 , Y10S430/146 , Y10T428/21
摘要: A recording layer contains a dye A having a complex index of refraction at 780 nm whose real part n is 1.8-2.8 and imaginary part k is up to 0.15 and forming a thin film exhibiting an absorption spectrum whose half-value width is up to 170 nm and a dye B having a complex index of refraction at 630 nm or 650 nm whose real part n is 1.8-2.8 and imaginary part k is up to 0.2. An optical recording medium capable of writing and reading in a conventional wavelength region of about 780 nm and a shorter wavelength region of about 630 to 680 nm is obtained.
摘要翻译: 记录层包含在780nm处具有复数折射率的染料A,其实部n为1.8-2.8,虚部k高达0.15,并形成表现出半值宽度达到170的吸收光谱的薄膜 nm,染料B在630nm或650nm具有复数折射率,其实部n为1.8-2.8,虚部k高达0.2。 获得能够在约780nm的常规波长区域和约630至680nm的较短波长区域中进行写入和读取的光学记录介质。
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公开(公告)号:US06168843A
公开(公告)日:2001-01-02
申请号:US09117621
申请日:1999-02-16
申请人: Emiko Kambe , Masahiro Shinkai , Sumiko Kitagawa , Atsushi Monden
发明人: Emiko Kambe , Masahiro Shinkai , Sumiko Kitagawa , Atsushi Monden
IPC分类号: B32B300
CPC分类号: G11B7/246 , G11B7/2467 , G11B7/2472 , G11B7/248 , G11B7/249 , G11B7/2492 , G11B7/2495 , G11B7/2534 , G11B7/256 , G11B7/2575 , G11B7/2595 , G11B2007/24612 , G11B2007/24618 , Y10S428/913 , Y10S430/146 , Y10T428/21
摘要: An optical recording medium is provided in which a recording layer contains a salt-forming dye between an ion of an azo metal complex of the following formula (I) and an ion of a cyanine dye of the following formula (II), having a complex index of refraction in the wavelength region of recording light and/or reading light whose imaginary part k is up to 0.20, or at least one of azo oxovanadium metal complexes having an azo compound of the following formula (III) as a ligand and metal complexes having azo compounds of the following formulae (IV) and (V) as a ligand. Recording and reading can be carried out at a conventional wavelength or a short wavelength of about 630-690 nm or both. In formulae (I) and (III), A is an aromatic ring group having an active hydrogen-bearing group at a position adjacent to the diazo group or a nitrogenous heteroaromatic ring group having an oxovanadium-coordinatable nitrogen atom at a position adjacent to the carbon atom in the ring attached to the diazo group, and B is an aromatic ring group having an active hydrogen-bearing group at a position adjacent to the diazo group. In formula (I), m is equal to 1 or 2, and M1 is a center metal. In formula (II), Q1 and Q2 each are a group of atoms forming a 5-membered nitrogenous heterocyclic ring which may have a fused ring, L is a methine chain, R1 and R2 each are an alkyl group. In formulae (IV) and (V), X is an active hydrogen-bearing group, R1 and R2 each are an alkyl group, the total number of carbon atoms in R1 and R2 is from 2 to 8, R is a nitro group, and n is equal to 0 or 1.
摘要翻译: 提供一种光记录介质,其中记录层在下式(I)的偶氮金属络合物的离子与下式(II)的花青染料的离子之间含有形成盐的染料,其具有复合物 记录光的波长区域的折射率和/或虚部k高达0.20的读取光,或具有下式(III)的偶氮化合物的偶氮氧化钒金属络合物作为配体和金属配合物中的至少一种 具有下式(IV)和(V)的偶氮化合物作为配体。 记录和读取可以在常规波长或约630-690nm的短波长或两者下进行。在式(I)和(III)中,A是在位置上具有活性含氢基团的芳环基团 邻近重氮基团或在与重氮基团连接的环中与碳原子相邻的位置具有氧化钒可配位氮原子的含氮杂芳族基团,B是具有活性含氢基团的芳环基团 与重氮组相邻的位置。 在式(I)中,m等于1或2,M1是中心金属。在式(II)中,Q1和Q2各自是形成可以具有稠环的5元含氮杂环的原子 ,L是次甲基链,R1和R2各自是烷基。在式(IV)和(V)中,X是含活性氢基团,R1和R2各自是烷基,碳原子数 在R1和R2中为2-8,R为硝基,n等于0或1。
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公开(公告)号:US5858613A
公开(公告)日:1999-01-12
申请号:US786458
申请日:1997-01-21
CPC分类号: G11B7/249 , C09B45/00 , G11B7/2467 , G11B7/248 , G11B2007/24612 , G11B7/2492 , G11B7/2498 , G11B7/2534 , G11B7/2542 , G11B7/256 , G11B7/2595 , Y10S430/146
摘要: An optical recording medium which can be recorded and read at a short wavelength (about 635-680 nm) or which can be recorded and read at two wavelengths, the short wavelength and a conventional wavelength (about 780 nm) has a recording layer containing an azo metal complex dye obtained by reacting a metal compound with an azo compound of formula (I) or an azo compound of formula (II). ##STR1## In formula (I), Q.sub.1 is a group of atoms necessary to form an aromatic ring with two C, A is C or a hetero-atom, Q.sub.2 is a group of atoms necessary to form an aromatic ring with two C and A, and Q.sub.3 is a group of atoms necessary to form an aromatic ring with C, N and A, fused to the aromatic ring completed by Q.sub.2. In formula (II), Q.sup.1 is a 8-quinolyl radical and Q.sup.2 is a 2-imidazolyl radical whose nitrogen at the 1-position has active hydrogen.
摘要翻译: 可以在短波长(约635-680nm)下记录和读取的光记录介质,其可以在短波长和常规波长(约780nm)的两个波长下进行记录和读取,具有包含 通过使金属化合物与式(I)的偶氮化合物或式(II)的偶氮化合物反应而获得的偶氮金属络合染料。 (I)Q1NNQ2(II)在式(I)中,Q1是形成具有两个C,A是C或杂原子的芳环所必需的一组原子,Q2是形成所需的原子团 具有两个C和A的芳香环,Q3是与C,N和A形成芳香环所必需的一组原子,与Q2完成的芳香环融合。 在式(II)中,Q1是8-喹啉基,Q2是2-位咪唑基,其1位的氮具有活性氢。
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