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公开(公告)号:US06168843A
公开(公告)日:2001-01-02
申请号:US09117621
申请日:1999-02-16
申请人: Emiko Kambe , Masahiro Shinkai , Sumiko Kitagawa , Atsushi Monden
发明人: Emiko Kambe , Masahiro Shinkai , Sumiko Kitagawa , Atsushi Monden
IPC分类号: B32B300
CPC分类号: G11B7/246 , G11B7/2467 , G11B7/2472 , G11B7/248 , G11B7/249 , G11B7/2492 , G11B7/2495 , G11B7/2534 , G11B7/256 , G11B7/2575 , G11B7/2595 , G11B2007/24612 , G11B2007/24618 , Y10S428/913 , Y10S430/146 , Y10T428/21
摘要: An optical recording medium is provided in which a recording layer contains a salt-forming dye between an ion of an azo metal complex of the following formula (I) and an ion of a cyanine dye of the following formula (II), having a complex index of refraction in the wavelength region of recording light and/or reading light whose imaginary part k is up to 0.20, or at least one of azo oxovanadium metal complexes having an azo compound of the following formula (III) as a ligand and metal complexes having azo compounds of the following formulae (IV) and (V) as a ligand. Recording and reading can be carried out at a conventional wavelength or a short wavelength of about 630-690 nm or both. In formulae (I) and (III), A is an aromatic ring group having an active hydrogen-bearing group at a position adjacent to the diazo group or a nitrogenous heteroaromatic ring group having an oxovanadium-coordinatable nitrogen atom at a position adjacent to the carbon atom in the ring attached to the diazo group, and B is an aromatic ring group having an active hydrogen-bearing group at a position adjacent to the diazo group. In formula (I), m is equal to 1 or 2, and M1 is a center metal. In formula (II), Q1 and Q2 each are a group of atoms forming a 5-membered nitrogenous heterocyclic ring which may have a fused ring, L is a methine chain, R1 and R2 each are an alkyl group. In formulae (IV) and (V), X is an active hydrogen-bearing group, R1 and R2 each are an alkyl group, the total number of carbon atoms in R1 and R2 is from 2 to 8, R is a nitro group, and n is equal to 0 or 1.
摘要翻译: 提供一种光记录介质,其中记录层在下式(I)的偶氮金属络合物的离子与下式(II)的花青染料的离子之间含有形成盐的染料,其具有复合物 记录光的波长区域的折射率和/或虚部k高达0.20的读取光,或具有下式(III)的偶氮化合物的偶氮氧化钒金属络合物作为配体和金属配合物中的至少一种 具有下式(IV)和(V)的偶氮化合物作为配体。 记录和读取可以在常规波长或约630-690nm的短波长或两者下进行。在式(I)和(III)中,A是在位置上具有活性含氢基团的芳环基团 邻近重氮基团或在与重氮基团连接的环中与碳原子相邻的位置具有氧化钒可配位氮原子的含氮杂芳族基团,B是具有活性含氢基团的芳环基团 与重氮组相邻的位置。 在式(I)中,m等于1或2,M1是中心金属。在式(II)中,Q1和Q2各自是形成可以具有稠环的5元含氮杂环的原子 ,L是次甲基链,R1和R2各自是烷基。在式(IV)和(V)中,X是含活性氢基团,R1和R2各自是烷基,碳原子数 在R1和R2中为2-8,R为硝基,n等于0或1。
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公开(公告)号:US5858613A
公开(公告)日:1999-01-12
申请号:US786458
申请日:1997-01-21
CPC分类号: G11B7/249 , C09B45/00 , G11B7/2467 , G11B7/248 , G11B2007/24612 , G11B7/2492 , G11B7/2498 , G11B7/2534 , G11B7/2542 , G11B7/256 , G11B7/2595 , Y10S430/146
摘要: An optical recording medium which can be recorded and read at a short wavelength (about 635-680 nm) or which can be recorded and read at two wavelengths, the short wavelength and a conventional wavelength (about 780 nm) has a recording layer containing an azo metal complex dye obtained by reacting a metal compound with an azo compound of formula (I) or an azo compound of formula (II). ##STR1## In formula (I), Q.sub.1 is a group of atoms necessary to form an aromatic ring with two C, A is C or a hetero-atom, Q.sub.2 is a group of atoms necessary to form an aromatic ring with two C and A, and Q.sub.3 is a group of atoms necessary to form an aromatic ring with C, N and A, fused to the aromatic ring completed by Q.sub.2. In formula (II), Q.sup.1 is a 8-quinolyl radical and Q.sup.2 is a 2-imidazolyl radical whose nitrogen at the 1-position has active hydrogen.
摘要翻译: 可以在短波长(约635-680nm)下记录和读取的光记录介质,其可以在短波长和常规波长(约780nm)的两个波长下进行记录和读取,具有包含 通过使金属化合物与式(I)的偶氮化合物或式(II)的偶氮化合物反应而获得的偶氮金属络合染料。 (I)Q1NNQ2(II)在式(I)中,Q1是形成具有两个C,A是C或杂原子的芳环所必需的一组原子,Q2是形成所需的原子团 具有两个C和A的芳香环,Q3是与C,N和A形成芳香环所必需的一组原子,与Q2完成的芳香环融合。 在式(II)中,Q1是8-喹啉基,Q2是2-位咪唑基,其1位的氮具有活性氢。
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公开(公告)号:US07897269B2
公开(公告)日:2011-03-01
申请号:US10922218
申请日:2004-08-20
申请人: Emiko Kambe , Akira Ebisawa , Satoshi Shirai , Masahiro Shinkai , Tetsushi Inoue
发明人: Emiko Kambe , Akira Ebisawa , Satoshi Shirai , Masahiro Shinkai , Tetsushi Inoue
CPC分类号: H01L51/004 , H01L51/0035 , H01L51/0037 , H01L51/0039 , H01L51/0052 , H01L51/0058 , H01L51/007 , H01L51/0077 , H01L51/0081 , H01L51/0089 , H01L51/5012 , H01L51/5096 , H01L2251/5346 , H01L2251/558 , Y10S428/917 , Y10T428/24942 , Y10T428/26
摘要: Organic EL elements provided with a substrate 10, a first electrode layer 12 and a second electrode layer 18 situated in a mutually opposing manner on one side of the substrate 10, and a luminescent layer 20 situated between the electrode layers, wherein one of the first electrode layer 12 and the second electrode layer 18 is a hole injection electrode layer and the other is an electron injection electrode layer, and there is formed in the luminescent layer 20 a modified section 16 which contains an organic polymer compound different from the organic compound composing the luminescent layer 14, in bias toward the electron injection electrode layer.
摘要翻译: 设置有基板10,第一电极层12和第二电极层18的有机EL元件,位于基板10一侧的相互相对的方式,位于电极层之间的发光层20,其中第一 电极层12和第二电极层18是空穴注入电极层,另一方面是电子注入电极层,在发光层20中形成改性部16,该改性部16含有与构成的有机化合物不同的有机高分子化合物 发光层14偏向电子注入电极层。
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公开(公告)号:US06242067B1
公开(公告)日:2001-06-05
申请号:US09420941
申请日:1999-10-19
申请人: Emiko Kambe , Atsushi Monden
发明人: Emiko Kambe , Atsushi Monden
IPC分类号: B32B302
CPC分类号: G11B7/2495 , C09B45/14 , C09B69/045 , G11B7/246 , G11B7/2467 , G11B7/247 , G11B7/2472 , G11B7/2534 , G11B7/256 , G11B7/2575 , G11B7/2595 , Y10S428/913 , Y10S430/146 , Y10T428/21
摘要: In an optical recording medium using writing and reading light having a wavelength of up to 690 nm and having a recording layer and preferably a reflective layer, the recording layer contains a chelate compound having an azo compound of specific structure as a ligand (i.e., azo metal complex dye). This results in an optical recording medium of the heat mode having advantages including the dye's sufficient solubility in a coating solvent which does not attack polycarbonate substrates and improved write/read characteristics with light having a wavelength of up to 690 nm.
摘要翻译: 在使用具有高达690nm的波长的写入和读取光并且具有记录层并且优选地具有反射层的光学记录介质中,记录层含有具有特定结构的偶氮化合物作为配体的螯合化合物(即偶氮 金属络合染料)。 这导致热模式的光学记录介质具有包括染料在不侵蚀聚碳酸酯基底的涂层溶剂中的足够溶解性和具有高达690nm波长的光的改进的读/写特性的优点。
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公开(公告)号:US20060238110A1
公开(公告)日:2006-10-26
申请号:US10550873
申请日:2004-03-29
申请人: Satoshi Shirai , Akira Ebisawa , Masahiro Shinkai , Emiko Kambe
发明人: Satoshi Shirai , Akira Ebisawa , Masahiro Shinkai , Emiko Kambe
IPC分类号: H01J1/62
CPC分类号: C09K11/06 , C09B23/14 , C09B57/00 , C09B69/109 , C09K2211/1416 , H05B33/14 , Y10S428/917
摘要: An organic EL element of the present invention comprises a substrate, an electrode layer, an organic layer, and an electrode layer, whereas the organic layer 3 contains a vinyl polymer obtained by polymerizing a polymerizable monomer containing a compound represented by formula (1) or (2): wherein each of L1 and L2 is a bivalent group; each of X1, X2, X3, X4, X5, and X6 is alkyl group or the like; each of a and e is 0 or 1; each of b, f, g, and h is an integer of 0 to 3; c is an integer of 0 to 2; and d is an integer of 0 to 4.
摘要翻译: 本发明的有机EL元件包括基板,电极层,有机层和电极层,有机层3含有通过聚合含有式(1)表示的化合物或 (2):其中L 1和L 2各自为二价基团; X 1,X 2,X 3,X 4,X 5,...中的每一个, >,X 6是烷基等; a和e各自为0或1; b,f,g和h各自为0〜3的整数; c为0〜2的整数, d为0〜4的整数。
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公开(公告)号:US20050129979A1
公开(公告)日:2005-06-16
申请号:US10922218
申请日:2004-08-20
申请人: Emiko Kambe , Akira Ebisawa , Satoshi Shirai , Masahiro Shinkai , Tetsushi Inoue
发明人: Emiko Kambe , Akira Ebisawa , Satoshi Shirai , Masahiro Shinkai , Tetsushi Inoue
CPC分类号: H01L51/004 , H01L51/0035 , H01L51/0037 , H01L51/0039 , H01L51/0052 , H01L51/0058 , H01L51/007 , H01L51/0077 , H01L51/0081 , H01L51/0089 , H01L51/5012 , H01L51/5096 , H01L2251/5346 , H01L2251/558 , Y10S428/917 , Y10T428/24942 , Y10T428/26
摘要: Organic EL elements provided with a substrate 10, a first electrode layer 12 and a second electrode layer 18 situated in a mutually opposing manner on one side of the substrate 10, and a luminescent layer 20 situated between the electrode layers, wherein one of the first electrode layer 12 and the second electrode layer 18 is a hole injection electrode layer and the other is an electron injection electrode layer, and there is formed in the luminescent layer 20 a modified section 16 which contains an organic polymer compound different from the organic compound composing the luminescent layer 14, in bias toward the electron injection electrode layer.
摘要翻译: 设置有基板10,第一电极层12和第二电极层18的有机EL元件,位于基板10一侧的相互相对的方式,位于电极层之间的发光层20,其中第一 电极层12和第二电极层18是空穴注入电极层,另一方面是电子注入电极层,在发光层20中形成改性部16,该改性部16含有与构成的有机化合物不同的有机高分子化合物 发光层14偏向电子注入电极层。
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公开(公告)号:US20050064241A1
公开(公告)日:2005-03-24
申请号:US10950519
申请日:2004-09-28
申请人: Emiko Kambe , Masahiro Shinkai
发明人: Emiko Kambe , Masahiro Shinkai
CPC分类号: H01L51/5092 , C09K11/06 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , C09K2211/1044 , C09K2211/181 , C09K2211/182 , H01L51/0039 , H01L51/005 , H01L51/0079 , H01L51/5012 , Y10S428/917 , Y10T428/24917 , Y10T428/31692 , Y10T428/31855
摘要: In an organic EL device comprising a cathode, an anode, and two or more stacked organic layers therebetween including a light emitting layer, an electron injecting organic layer containing an organic salt or complex of a metal having a standard electrode potential of more negative than −1.8 V at 25° C. is formed close to the cathode by coating, and an organic layer containing a high molecular weight EL material is disposed close to the electron injecting organic layer. A multilayer structure of organic layers can be formed by coating, and the organic EL device has a high luminance, high efficiency, high reliability, long life and ease of handling.
摘要翻译: 在包括阴极,阳极及其间的两层或多层堆叠的有机层的有机EL器件中,包括发光层,含有有机盐的有机盐或配合物的电子注入有机层, 通过涂布在阴极附近形成25℃的1.8V,并且将含有高分子量EL材料的有机层设置在电子注入有机层附近。 可以通过涂布形成有机层的多层结构,并且有机EL器件具有高亮度,高效率,高可靠性,长寿命和易于处理。
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公开(公告)号:US06821649B2
公开(公告)日:2004-11-23
申请号:US10222778
申请日:2002-08-19
申请人: Emiko Kambe , Masahiro Shinkai
发明人: Emiko Kambe , Masahiro Shinkai
IPC分类号: H05B3314
CPC分类号: H01L51/5092 , C09K11/06 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , C09K2211/1044 , C09K2211/181 , C09K2211/182 , H01L51/0039 , H01L51/005 , H01L51/0079 , H01L51/5012 , Y10S428/917 , Y10T428/24917 , Y10T428/31692 , Y10T428/31855
摘要: In an organic EL device comprising a cathode, an anode, and two or more stacked organic layers therebetween including a light emitting layer, an electron injecting organic layer containing an organic salt or complex of a metal having a standard electrode potential of more negative than −1.8 V at 25° C. is formed close to the cathode by coating, and an organic layer containing a high molecular weight EL material is disposed close to the electron injecting organic layer. A multilayer structure of organic layers can be formed by coating, and the organic EL device has a high luminance, high efficiency, high reliability, long life and ease of handling.
摘要翻译: 在包括阴极,阳极及其间的两层或多层堆叠的有机层的有机EL器件中,包括发光层,含有有机盐的有机盐或配合物的电子注入有机层, 通过涂布在阴极附近形成25℃的1.8V,并且将含有高分子量EL材料的有机层设置在电子注入有机层附近。 可以通过涂布形成有机层的多层结构,并且有机EL器件具有高亮度,高效率,高可靠性,长寿命和易于处理。
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公开(公告)号:US07425375B2
公开(公告)日:2008-09-16
申请号:US10550873
申请日:2004-03-29
申请人: Satoshi Shirai , Akira Ebisawa , Masahiro Shinkai , Emiko Kambe
发明人: Satoshi Shirai , Akira Ebisawa , Masahiro Shinkai , Emiko Kambe
CPC分类号: C09K11/06 , C09B23/14 , C09B57/00 , C09B69/109 , C09K2211/1416 , H05B33/14 , Y10S428/917
摘要: An organic EL element of the present invention comprises a substrate, an electrode layer, an organic layer, and an electrode layer, whereas the organic layer 3 contains a vinyl polymer obtained by polymerizing a polymerizable monomer containing a compound represented by formula (1) or (2): wherein each of L1 and L2 is a bivalent group; each of X1, X2, X3, X4, X5, and X6 is alkyl group or the like; each of a and e is 0 or 1; each of b, f, g, and h is an integer of 0 to 3; c is an integer of 0 to 2; and d is an integer of 0 to 4.
摘要翻译: 本发明的有机EL元件包括基板,电极层,有机层和电极层,有机层3含有通过聚合含有式(1)表示的化合物或 (2):其中L 1和L 2各自为二价基团; X 1,X 2,X 3,X 4,X 5,...中的每一个 >,X 6是烷基等; a和e各自为0或1; b,f,g和h各自为0〜3的整数; c为0〜2的整数, d为0〜4的整数。
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公开(公告)号:US07018724B2
公开(公告)日:2006-03-28
申请号:US10950519
申请日:2004-09-28
申请人: Emiko Kambe , Masahiro Shinkai
发明人: Emiko Kambe , Masahiro Shinkai
IPC分类号: H05B33/14
CPC分类号: H01L51/5092 , C09K11/06 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , C09K2211/1044 , C09K2211/181 , C09K2211/182 , H01L51/0039 , H01L51/005 , H01L51/0079 , H01L51/5012 , Y10S428/917 , Y10T428/24917 , Y10T428/31692 , Y10T428/31855
摘要: In an organic EL device comprising a cathode, an anode, and two or more stacked organic layers therebetween including a light emitting layer, an electron injecting organic layer containing an organic salt or complex of a metal having a standard electrode potential of more negative than −1.8 V at 25° C. is formed close to the cathode by coating, and an organic layer containing a high molecular weight EL material is disposed close to the electron injecting organic layer. A multilayer structure of organic layers can be formed by coating, and the organic EL device has a high luminance, high efficiency, high reliability, long life and ease of handling.
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