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公开(公告)号：US4090932A
公开(公告)日：1978-05-23
申请号：US733714
申请日：1976-10-18
申请人： Akira Kazihara , Shinsaku Ogawa , Takekuni Kobayashi , Maomi Seko
发明人： Akira Kazihara , Shinsaku Ogawa , Takekuni Kobayashi , Maomi Seko
摘要： Heated substances, e.g. electrolytes or gases from electrodes, formed during electrolysis of an alkali halide in an electrolytic cell using a cation exchange membrane to separate anode and cathode chambers are used effectively as heat source for heating an aqueous caustic alkali solution to be concentrated in an evaporator.
摘要翻译： 加热物质，例如 作为用于加热浓缩在蒸发器中的苛性碱水溶液的热源，可以有效地利用在使用阳离子交换膜分离阳极室和阴极室的电解槽中碱性卤化物电解期间形成的来自电极的电解质或气体。
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2.发明授权Electrode coating consisting of a solid solution of a noble metal oxide, titanium oxide, and zirconium oxide 失效由贵金属氧化物，氧化钛和氧化锆的固溶体组成的电极涂层
公开(公告)号：US4005004A
公开(公告)日：1977-01-25
申请号：US611889
申请日：1975-09-10
申请人： Maomi Seko , Shinsaku Ogawa , Mitsuo Yoshida , Akira Nakamura
发明人： Maomi Seko , Shinsaku Ogawa , Mitsuo Yoshida , Akira Nakamura
CPC分类号： C25B11/0484
摘要： A solid solution of a noble metal oxide, titanium oxide and zirconium oxide, containing 1 to 50 mol % of titanium oxide and zirconium oxide as the total content, is coated on an anti-corrosive substrate, e.g. titanium metal to give an electrode which is excellent in low oxygen content in chlorine gas, low electrode consumption and low chlorine overvoltage when it is used as anode for electrolysis of an aqueous sodium chloride solution.
摘要翻译： 将含有1〜50摩尔％的氧化钛和氧化锆作为总含量的贵金属氧化物，氧化钛和氧化锆的固溶体涂布在防腐蚀基板上，例如， 钛金属，当用作电解氯化钠水溶液的阳极时，得到氯气中低氧含量优异，电极消耗低，氯过电压低的电极。
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3.发明授权
公开(公告)号：US4209369A
公开(公告)日：1980-06-24
申请号：US969272
申请日：1978-12-14
申请人： Maomi Seko , Shinsaku Ogawa , Reiji Takemura
发明人： Maomi Seko , Shinsaku Ogawa , Reiji Takemura
CPC分类号： C25B1/46 , B01D1/26 , C25B15/08 , Y02P20/129
摘要： In a process for electrolysis of sodium chloride in an electrolytic cell divided into the anode chamber and the cathode chamber by a cation exchange membrane, well brine is used as the starting material for the electrolysis and the dilute aqueous sodium chloride solution formed as the result of the electrolysis is subjected to concentration for re-use as the starting material.
摘要翻译： 在通过阳离子交换膜分解成阳极室和阴极室的电解池中电解氯化钠的方法中，使用盐水作为电解的起始原料，并且作为结果形成的稀氯酸钠水溶液 将电解作为起始原料进行浓缩再利用。
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公开(公告)号：US4111779A
公开(公告)日：1978-09-05
申请号：US790924
申请日：1977-04-26
申请人： Maomi Seko , Shinsaku Ogawa , Nobuo Ajiki , Muneo Yoshida
发明人： Maomi Seko , Shinsaku Ogawa , Nobuo Ajiki , Muneo Yoshida
CPC分类号： C25B9/206
摘要： A bipolar system electrolytic cell having a partition wall made of explosion-bonded titanium plate and iron plate which is electrically connected to anode of titanium substrate at its titanium side and to cathode of iron at its iron side, space is preferably given between anode and the partition wall and also between cathode and the partition wall. An assembly having a number of such unit cells arranged in series is useful for electrolysis of sodium chloride which can be performed under a low voltage per unit cell.
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公开(公告)号：US4108742A
公开(公告)日：1978-08-22
申请号：US771978
申请日：1977-02-25
申请人： Maomi Seko , Shinsaku Ogawa , Muneo Yoshida
发明人： Maomi Seko , Shinsaku Ogawa , Muneo Yoshida
CPC分类号： C25B1/46
摘要： In an electrolytic cell having cation exchange membrane as diaphragm to partition said cell into cathode and anode chambers, electrolysis of an electrolyte aqueous solution is conducted while generating gas from anode by keeping the inner pressure in cathode chamber higher than that in anode chamber. Some disadvantages caused in the case of electrolyzing an aqueous alkali metal halide solution to form alkali metal hydroxide in cathode chamber are overcome by adjusting the anolyte at pH
摘要翻译： 在具有阳离子交换膜作为隔膜的电解池中，将电池分隔成阴极室和阳极室，通过将阴极室内的内压保持在比阳极室高的方式从阳极产生气体的同时进行电解。 在阴极室中电解碱金属卤化物水溶液以形成碱金属氢氧化物的情况下的一些缺点是通过调节pH <3.5的阳极电解液来克服。 还公开了可用于本方法的电解池。
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6.发明授权
公开(公告)号：US4276130A
公开(公告)日：1981-06-30
申请号：US42304
申请日：1979-05-25
申请人： Maomi Seko , Shinsaku Ogawa , Reiji Takemura
发明人： Maomi Seko , Shinsaku Ogawa , Reiji Takemura
CPC分类号： C25B1/46
摘要： High purity aqueous alkali hydroxide solutions containing predetermined, low concentrations of alkali metal halide are obtained in the anode compartment of an electrolytic cell using a cationic ion exchange membrane by conducting the electrolysis under controlled conditions such that the difference between the concentration of alkali metal halide in the anode compartment and the limiting concentration of alkali metal halide in the anode compartment is within a defined range.
摘要翻译： 在电解槽的阳极室中，使用阳离子交换膜，在受控条件下进行电解，得到含有预先确定的低浓度碱金属卤化物的高纯度碱金属氢氧化物溶液，使碱金属卤化物浓度之间的差异 阳极室和阳极室中碱金属卤化物的极限浓度在规定的范围内。
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公开(公告)号：US4132588A
公开(公告)日：1979-01-02
申请号：US764471
申请日：1977-01-31
申请人： Shinsaku Ogawa
发明人： Shinsaku Ogawa
摘要： A method and apparatus in which the effects in multiple effect evaporation systems are separated into successive stages and the vapors in the stages of one effect are utilized as a heat source for the liquid in stages of a subsequent effect.
摘要翻译： 一种方法和装置，其中多效蒸发系统的效果被分成连续的阶段，并且在一个效应的阶段中的蒸气被用作液体的热源，在后续的效果阶段。
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公开(公告)号：US4007151A
公开(公告)日：1977-02-08
申请号：US583221
申请日：1975-06-02
申请人： Shinsaku Ogawa , Matsuei Yamanoue , Norio Oyabu
发明人： Shinsaku Ogawa , Matsuei Yamanoue , Norio Oyabu
CPC分类号： C08G18/2835 , C08G18/282 , C08G18/3206 , C08G18/672 , C08G18/674 , C08G18/8025 , C08G18/8045
摘要： A solventless polyurethane coating composition having a low viscosity suitable for coating, which comprises (a) an aliphatic or alicyclic polyisocyanate containing at least 3 isocyanate groups, (b) at least 1/3 equivalent, based on the isocyanate groups, of a monohydric alcohol, and (c) a low-molecular-weight polyhydric alcohol having at least 3 active hydrogen atoms. The composition provides coatings having superior properties such as good hardness, weatherability and intimate adhesion to a substrate.
摘要翻译： 一种具有适于涂布的低粘度的无溶剂聚氨酯涂料组合物，其包含（a）含有至少3个异氰酸酯基团的脂族或脂环族多异氰酸酯，（b）至少1/3当量的异氰酸酯基团的一元醇 ，和（c）具有至少3个活性氢原子的低分子量多元醇。 该组合物提供具有优异性能的涂层，例如良好的硬度，耐候性和与基材的密合性。
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公开(公告)号：US4190505A
公开(公告)日：1980-02-26
申请号：US948659
申请日：1978-10-03
申请人： Shinsaku Ogawa , Mitsuo Yoshida , Hiroyuki Shiroki
发明人： Shinsaku Ogawa , Mitsuo Yoshida , Hiroyuki Shiroki
CPC分类号： C25B1/46
摘要： A sodium chloride feed solution containing an iron cyanide complex is subjected to purification to reduce the content of iron cyanide complex to not more than 0.5 ppm before it is fed as anolyte into an ion-exchange membrane electrolytic cell. The iron cyanide complex is preferably converted by oxidative decomposition to iron ions for removal. By use of such a purified sodium chloride as starting material, electrolysis of sodium chloride using an ion-exchange membrane can be performed for a long term at a constant electrolysis voltage.
摘要翻译： 将含有氰化铁络合物的氯化钠进料溶液进行纯化，将其作为阳极电解液进料到离子交换膜电解池中之前将氰化铁络合物的含量降低至不大于0.5ppm。 氰化铁络合物优选通过氧化分解转化成铁离子以除去。 通过使用这种纯化的氯化钠作为原料，可以在恒定的电解电压下长时间地使用离子交换膜电解氯化钠。
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公开(公告)号：US4105515A
公开(公告)日：1978-08-08
申请号：US811277
申请日：1977-06-29
申请人： Shinsaku Ogawa , Muneo Yoshida
发明人： Shinsaku Ogawa , Muneo Yoshida
CPC分类号： C25B1/46 , Y02P20/129
摘要： In carrying out electrolysis of alkali halide in an electrolytic cell having anode and cathode chambers separated by a cation exchange membrane by feeding an aqueous alkali halide solution into the anode chamber to produce halogen gas in the anode chamber and caustic alkali and hydrogen gas in the cathode chamber, the electrolytic cell is pressurized at higher than atmospheric pressure to obtain various improved results.
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