Bipolar system electrolytic cell
    1.
    发明授权
    Bipolar system electrolytic cell 失效
    双极体系电解槽

    公开(公告)号:US4111779A

    公开(公告)日:1978-09-05

    申请号:US790924

    申请日:1977-04-26

    IPC分类号: C25B9/20 C25B9/00

    CPC分类号: C25B9/206

    摘要: A bipolar system electrolytic cell having a partition wall made of explosion-bonded titanium plate and iron plate which is electrically connected to anode of titanium substrate at its titanium side and to cathode of iron at its iron side, space is preferably given between anode and the partition wall and also between cathode and the partition wall. An assembly having a number of such unit cells arranged in series is useful for electrolysis of sodium chloride which can be performed under a low voltage per unit cell.

    Electrolysis
    2.
    发明授权
    Electrolysis 失效
    电解

    公开(公告)号:US4108742A

    公开(公告)日:1978-08-22

    申请号:US771978

    申请日:1977-02-25

    IPC分类号: C25B1/46 C25B1/16 C25B1/26

    CPC分类号: C25B1/46

    摘要: In an electrolytic cell having cation exchange membrane as diaphragm to partition said cell into cathode and anode chambers, electrolysis of an electrolyte aqueous solution is conducted while generating gas from anode by keeping the inner pressure in cathode chamber higher than that in anode chamber. Some disadvantages caused in the case of electrolyzing an aqueous alkali metal halide solution to form alkali metal hydroxide in cathode chamber are overcome by adjusting the anolyte at pH

    摘要翻译: 在具有阳离子交换膜作为隔膜的电解池中,将电池分隔成阴极室和阳极室,通过将阴极室内的内压保持在比阳极室高的方式从阳极产生气体的同时进行电解。 在阴极室中电解碱金属卤化物水溶液以形成碱金属氢氧化物的情况下的一些缺点是通过调节pH <3.5的阳极电解液来克服。 还公开了可用于本方法的电解池。

    Process for the production of high purity aqueous alkali hydroxide
solution
    5.
    发明授权
    Process for the production of high purity aqueous alkali hydroxide solution 失效
    生产高纯度碱性氢氧化碱水溶液的方法

    公开(公告)号:US4276130A

    公开(公告)日:1981-06-30

    申请号:US42304

    申请日:1979-05-25

    IPC分类号: C25B1/46 C25B1/16 C25B1/26

    CPC分类号: C25B1/46

    摘要: High purity aqueous alkali hydroxide solutions containing predetermined, low concentrations of alkali metal halide are obtained in the anode compartment of an electrolytic cell using a cationic ion exchange membrane by conducting the electrolysis under controlled conditions such that the difference between the concentration of alkali metal halide in the anode compartment and the limiting concentration of alkali metal halide in the anode compartment is within a defined range.

    摘要翻译: 在电解槽的阳极室中,使用阳离子交换膜,在受控条件下进行电解,得到含有预先确定的低浓度碱金属卤化物的高纯度碱金属氢氧化物溶液,使碱金属卤化物浓度之间的差异 阳极室和阳极室中碱金属卤化物的极限浓度在规定的范围内。

    Multi-cell electrolyzer
    7.
    发明授权
    Multi-cell electrolyzer 失效
    多池电解槽

    公开(公告)号:US4643818A

    公开(公告)日:1987-02-17

    申请号:US760897

    申请日:1985-07-31

    CPC分类号: C25B9/206 C25B9/04 C25B9/045

    摘要: A multi-cell electrolyzer comprising a plurality of unit cells, each of which is composed of an anode chamber containing an anode and a cathode chamber containing a cathode and a cation exchange membrane for partitioning said unit cell into said anode chamber and said cathode chamber, and each of which is adapted to have an internal pressure maintained at a level higher than the atmospheric pressure in operation of the electrolyzer, said plurality of unit cells being arranged in series and adapted to be energized through a plurality of current lead plates, and rigid multi-contact electrically conductive means provided between the adjacent unit cells and/or between each current lead plate and the unit cell adjacent thereto, thereby establishing electrical connection between the adjacent unit cells and/or between each current lead plate and the unit cell adjacent thereto. With such a structure, not only is the electrical contact resistance between the adjacent unit cells and between each current lead plate and the unit cell adjacent thereto extremely reduced but also the current density in the unit cells is rendered uniform. Further, the present multi-cell electrolyzer can be easily constructed either in a bipolar form or in a monopolar form using unit cells common to both of the bipolar and monopolar forms.

    摘要翻译: 一种多单元电解槽,包括多个单元电池,每个单元电池由包含阳极的阳极室和含有阴极的阳极室和用于将所述单电池分隔成所述阳极室和所述阴极室的阳离子交换膜组成, 并且其中的每一个适于在电解槽的操作中将内部压力维持在高于大气压力的水平面上,所述多个单元电池串联布置并适于通过多个电流引线板通电,并且刚性 设置在相邻单元电池之间和/或每个电流引线板和与其相邻的单元电池之间的多触点导电装置,从而在相邻单元电池之间和/或每个电流引线板与与其相邻的单元电池之间建立电连接 。 通过这样的结构,不仅相邻单位电池之间和每个电流引线板与与其相邻的单位电池之间的电接触电阻极大地降低,而且单元电池中的电流密度也是均匀的。 此外,本发明的多单元电解器可以容易地以双极形式或单极形式使用双极和单极形式共同的单元电池。

    Method of simultaneous concentration and dilution of isotopes
    10.
    发明授权
    Method of simultaneous concentration and dilution of isotopes 失效
    同时浓缩和稀释同位素的方法

    公开(公告)号:US3953568A

    公开(公告)日:1976-04-27

    申请号:US272250

    申请日:1972-07-17

    摘要: A method of simultaneously obtaining separate enriched fractions of heavier and lighter isotopes from mixtures thereof with the use of an ion exchange resin column by passing a ligand body containing this isotope mixture through the column. The isotopes, as they are passed through the column, are present in the forms of ligand-containing coordination compounds having different valence states and are followed by an eluant and form a band which travels through the column, the front and rear portions of which are respectively enriched in one of the isotopes and depleted in the other.

    摘要翻译: 一种通过使含有该同位素混合物的配体通过该柱而使用离子交换树脂柱同时从混合物中获得较重和较轻同位素的分离的富集部分的方法。 当它们通过色谱柱时,同位素以具有不同价态的配体配位化合物的形式存在,并且随后是洗脱剂并形成行进通过柱的带,其前部和后部是 分别富集了一种同位素,另一种是耗尽的。