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1.发明授权
公开(公告)号：US4568769A
公开(公告)日：1986-02-04
申请号：US622865
申请日：1984-06-20
申请人： Akira Yashima , Teruo Matsuda , Tadao Sato , Mitsuaki Takahashi , Kiyomi Sakai
发明人： Akira Yashima , Teruo Matsuda , Tadao Sato , Mitsuaki Takahashi , Kiyomi Sakai
IPC分类号： C07C29/48 , C07C45/33 , C07C45/53 , C07C409/14
CPC分类号： C07C409/14 , C07C29/48 , C07C407/00 , C07C45/33 , C07C45/53 , C07C2101/14
摘要： Disclosed in a method for producing a mixture containing cycloalkanone and/or cycloalkanol which comprises oxidizing a cycloalkane with molecular oxygen to a cycloalkyl hydroperoxide represented by the formula (1): ##STR1## (wherein m represents an integer of 4.ltoreq.m.ltoreq.11) and decomposing the cycloalkyl hydroperoxide to obtain a mixture containing cycloalkanone and/or cycloalkanol, wherein the oxidation of the cycloalkane with molecular oxygen and/or the decomposition of the cycloalkyl hydroperoxide are carried out in the presence of a catalyst composition comprising at least one metallic salt represented by the formula (2):MX.sub.n (2)(wherein M represent Co, Mn, Cr or Fe, X represents an anionic ligand and n represents 2 or 3) and at least one compound represented by the formula (3): ##STR2## (wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represent hydrogen or a lower alkyl group) and/or a catalyst composition comprising at least one metal complex represented by the formula (4): ##STR3## (wherein M represents Co, Mn, Cr or Fe, X represents an anionic ligand, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represent hydrogen or a lower alkyl group, p is 1 or 2 and q is 0, 1 or 2).Advantages of the method are higher conversion of cycloalkyl hydroperoxide, higher yields of cycloalkanone and cycloalkanol and higher production ratio of cycloalkanone.
摘要翻译： 本发明涉及制备含有环烷酮和/或环烷醇的混合物的方法，该方法包括用分子氧将环烷烃氧化为由式（1）表示的环烷基氢过氧化物：其中m表示4的整数， = m 11）并分解环烷基氢过氧化物以获得含有环烷酮和/或环烷醇的混合物，其中环烷烃与分子氧的氧化和/或环烷基氢过氧化物的分解在催化剂存在下进行 包含至少一种由式（2）表示的金属盐的组合物：MXn（2）（其中M表示Co，Mn，Cr或Fe，X表示阴离子配体，n表示2或3）和至少一种由 式（3）：其中R1，R2，R3和R4独立地表示氢或低级烷基）和/或包含至少一种由式（4）表示的金属络合物的催化剂组合物： （图） 4）（其中M表示Co，Mn，Cr或Fe，X表示阴离子配体，R1，R2，R3和R4独立地表示氢或低级烷基，p为1或2，q为0,1或2） 。 该方法的优点是环烷基氢过氧化物的转化率较高，环烷酮和环烷醇的产率较高，环烷酮的生产率较高。
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公开(公告)号：US5291692A
公开(公告)日：1994-03-08
申请号：US583173
申请日：1990-09-10
IPC分类号： B24B13/005 , B24B47/00
CPC分类号： B24B13/005
摘要： A polishing work holder for supporting a lens to be polished for use in a lens polishing machine is disclosed. The work holder comprises a holder body rotatably supported by a housing and having a recess portion formed on a rotating shaft of one end face thereof and a suction hole opened at the end face, a lens receptacle having a hole communicated with the suction hole to suck and hold a lens at one end surface, a spherical body intervened between the recess portion of the holder body and the lens holder so as to contact the another end face and for carrying the lens receptacle tiltably and movably in the crossing direction to the axis of the holder body, a fitting ring secured to the holder body concentrically and loosely fitted onto an outer periphery face of the lens or an outer periphery face of the lens receptacle so as to limit the tilting of the lens and the moving in the diametrical direction, and a sealing member provided between the holder body and the receptacle at outside of the suction hole.
摘要翻译： 公开了一种用于支撑用于透镜抛光机的待抛光透镜的研磨工作保持器。 工件保持器包括：保持器主体，其被壳体可旋转地支撑并且具有形成在其一个端面的旋转轴上的凹部和在端面处开口的吸入孔;透镜接收器，其具有与吸入孔连通以吸取 并且在一个端面保持透镜，插入在保持器主体的凹部与透镜保持件之间的球体，以便接触另一个端面，并且用于将透镜容纳件可沿着与 保持器主体，固定到保持器本体同心且松散地配合到透镜的外周面或透镜容座的外周面上的配合环，以限制透镜的倾斜和沿直径方向的移动， 以及密封构件，其设置在所述吸入孔的外部的所述保持器主体和所述容器之间。
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公开(公告)号：US5140777A
公开(公告)日：1992-08-25
申请号：US591132
申请日：1990-10-01
摘要： An apparatus for controlling the machining of optical elements is disclosed. The apparatus comprises the thus measured value of radius curvature with the measured value of radius curvature of previously polished lens, means for determining curvature correcting value by comparing the thus obtained curvature variation value with a previously set allowed value of radius curvature, means for determining correcting value of machining conditions during the swinging motion based on the thus determined curvature correcting value, and means for adjusting the machining conditions in accordance with the correcting value of machining conditions.
摘要翻译： 公开了一种用于控制光学元件加工的装置。 该装置包括如此测量的半径曲率值与先前抛光透镜的半径曲率的测量值，通过将由此获得的曲率变化值与预先设定的半径曲率的允许值进行比较来确定曲率校正值的装置的装置，用于确定校正 基于由此确定的曲率校正值在摆动期间的加工条件的值，以及根据加工条件的校正值来调整加工条件的装置。
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公开(公告)号：US5357716A
公开(公告)日：1994-10-25
申请号：US32443
申请日：1993-03-15
IPC分类号： B24B13/005 , B24B41/06
CPC分类号： B24B13/005
摘要： A holding device for holding an optical element to be ground is arranged such that pressure applied to a receiving face of the optical element on the holder base is made different in the radial direction in order to eliminate deformation, positional deviation or inclination of the optical element due to grinding resistances during grinding or due to high-pressure grinding. An elastic member is employed as an elastic member, or a receiving member capable of absorbing the positional deviation, the inclination, or the like of the optical element during grinding thereof is used.
摘要翻译： 用于保持待研磨的光学元件的保持装置被布置成使得施加到保持器基座上的光学元件的接收面的压力在径向方向上不同，以消除光学元件的变形，位置偏离或倾斜 由于研磨期间的磨削阻力或由于高压研磨。 使用弹性构件作为弹性构件，或者使用能够吸收光学元件在其研磨期间的位置偏离，倾斜度等的接收构件。
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公开(公告)号：US5131159A
公开(公告)日：1992-07-21
申请号：US559840
申请日：1990-07-30
摘要： A spherometer for measuring the radius of curvature of 1 lens is disclosed. The spherometer comprises a spherometer ring having an annular portion or a part of an annular portion, a measuring member coaxially secured to the spherometer ring, a supporting member for supporting the spherometer ring, and a tilt facilitating member interposed between the spherometer ring and the ring supporting member.
摘要翻译： 公开了一种用于测量1个透镜的曲率半径的球形计。 所述球形计包括具有环形部分或环形部分的一部分的测厚仪环，同轴地固定到所述测厚仪环的测量构件，用于支撑所述测微计环的支撑构件以及插入所述球形测量环和所述环之间的倾斜促进构件 支持会员
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