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    Method for making aqueous solutions of (meth)acryloyloxyethylbenzyldimethylammonium chlorides
    2.
    发明授权
    Method for making aqueous solutions of (meth)acryloyloxyethylbenzyldimethylammonium chlorides 失效
    制备（甲基）丙烯酰氧基乙基苄基二甲基氯化铵水溶液的方法

    公开(公告)号：US07084296B2

    公开(公告)日：2006-08-01

    申请号：US10344322

    申请日：2001-08-07

    申请人： Alain Riondel ,  Gilles Herbst ,  Serge Tretjak

    发明人： Alain Riondel ,  Gilles Herbst ,  Serge Tretjak

    IPC分类号： C07C69/52

    CPC分类号： C07C213/08 ,  C07C219/08

    摘要： This process for the manufacture of an aqueous solution of (meth)acryloyloxyethylbenzyl-dimethylammonium chloride ((M)ADAMQUAT BZ) by reaction, in the presence of water, of N,N-dimethylaminoethyl (meth)acrylate ((M)ADAME) with benzyl chloride is characterized in that the reaction is carried out continuously in a reactor operating according to the perfectly stirred reactor technology.

    摘要翻译： 通过在水存在下，将N，N-二甲基氨基乙基（甲基）丙烯酸酯（（M）ADAME）与（甲基）丙烯酰氧基乙基苄基 - 二甲基氯化铵（（M）ADAMQUAT BZ）的水溶液 苄基氯的特征在于反应在根据完全搅拌的反应器技术操作的反应器中连续进行。

    Method for Preparing (Meth) Acrylic Esters or Anhydrides
    4.
    发明申请
    Method for Preparing (Meth) Acrylic Esters or Anhydrides 审中-公开
    制备（甲基）丙烯酸酯或酸酐的方法

    公开(公告)号：US20080161596A1

    公开(公告)日：2008-07-03

    申请号：US11664938

    申请日：2005-10-11

    申请人： Alain Riondel ,  Jean-Philippe Gendarme ,  Gilles Herbst

    发明人： Alain Riondel ,  Jean-Philippe Gendarme ,  Gilles Herbst

    IPC分类号： C07C69/66 ,  B01J8/06

    CPC分类号： C07C213/06 ,  C07C213/10 ,  C07C219/08

    摘要： The invention concerns a method for preparing (meth)acrylic esters or anhydrides from acrylic acid of formulae (I), where R is H or Me, and R′ is alkyl and R″ is alkyl or ethyl substituted by dialkylamino whereof the alkyls can form with the nitrogen atom, a 5- or 6-membered heterocycle, capable of bearing one or several alkyl substituents. OII or ═O, or R′ is H and R″ is alkyl, the alcohol R″—OH being primary or secondary; or (II) wherein R′ is H or Me, functioning preferably in the presence of at least one catalyst, wherein is performed a reaction in a reaction R2 with constant equilibrium displacement provided with a first reactor R1 designed for prior dehydration of the reagents to be involved in the reaction.

    摘要翻译： 本发明涉及一种由式（I）的丙烯酸制备（甲基）丙烯酸酯或酸酐的方法，其中R是H或Me，R'是烷基，R“是被二烷基氨基取代的烷基或乙基，其中烷基可以 与氮原子一起形成能够带有一个或多个烷基取代基的5-或6-元杂环。 OII或-O，或R'是H，R“是烷基，醇R”-OH是伯或仲的; 或（II）其中R'是H或Me，优选在至少一种催化剂的存在下起作用，其中在具有恒定平衡位移的反应R 2中进行反应，其中提供了第一反应器R 1，其设计用于先前脱水的 试剂参与反应。

    Method for making aqueous solutions of unsaturated quaternary ammonium salts
    5.
    发明授权
    Method for making aqueous solutions of unsaturated quaternary ammonium salts 失效
    制备不饱和季铵盐水溶液的方法

    公开(公告)号：US07151190B1

    公开(公告)日：2006-12-19

    申请号：US09889699

    申请日：2000-01-20

    申请人： Alain Riondel ,  Gilles Herbst ,  Marc Esch

    发明人： Alain Riondel ,  Gilles Herbst ,  Marc Esch

    IPC分类号： C07C69/533

    CPC分类号： C07C213/08 ,  C07C219/08

    摘要： The invention concerns a method for making aqueous solutions of unsaturated quaternary ammonium salts of formula (I) by reacting, in the presence of water, N,N-dimethylaminoethyl acrylate with a quaternizing agent of formula (II): R—Cl, said method is characterized in that it consists in: (a) in a closed reactor containing 5 60 wt. % of N,N-dimethylaminoethyl acrylate required for the reaction and which has been pressurized with air or depleted air at 0.5 to 3 bars, carrying out the reaction by continuously introducing, at a temperature ranging between 35 to 65° C., the quaternizing agent (II), and water, and finally the remaining N,N-dimethylaminoethyl acrylate, until the desired concentration of salt (I) in the water is reached, the water being introduced only when 0–20 wt. % of the amount required for the quaternizing agent (II) reaction has been added; the introduction of the remaining N,N-dimethylaminoethyl acrylate starting only when 20–80 wt. % required for the quaternizing agent (II) reaction has been added; and the pressure at the end of the reaction capable of reaching 9 bars; then (b) in depressurizing while maintaining the oxygen content constant by simultaneous introduction of air and, after returning to atmospheric pressure, eliminating the residual quaternizing agent. In formule (I) and (II). R=methyl or benzyl.

    摘要翻译： 本发明涉及一种制备式（I）的不饱和季铵盐的水溶液的方法，该方法是在水，N，N-二甲基氨基乙基丙烯酸酯与式（II）的季铵化剂：R-Cl的存在下反应，所述方法 其特征在于它包括：（a）在含有60重量％ 反应中所需的N，N-二甲基氨基乙基丙烯酸酯的百分比，并且已经用空气或贫的空气在0.5至3巴加压，通过在35至65℃的温度范围内连续引入季铵化 （II）和水，最后是剩余的N，N-二甲基氨基乙基丙烯酸酯，直到达到所需浓度的盐（I），仅在0-20wt。 添加季铵化剂（II）反应所需量的％; 引入剩余的N，N-二甲基氨基乙基丙烯酸酯仅在20-80wt。 加入季铵化剂（II）反应所需的％; 反应结束时的压力可以达到9巴; 然后（b）在同时引入空气的同时保持氧含量恒定的同时减压，并且在返回到大气压力之后，消除残留的季铵化剂。 在式（I）和（II）中。 R =甲基或苄基。

    Process for the manufacture of aqueous solutions of unsaturated quaternary ammonium salts
    6.
    发明授权
    Process for the manufacture of aqueous solutions of unsaturated quaternary ammonium salts 失效
    制备不饱和季铵盐水溶液的方法

    公开(公告)号：US06683203B2

    公开(公告)日：2004-01-27

    申请号：US10132690

    申请日：2002-04-26

    申请人： Thierry Druzkowski ,  Gilles Herbst ,  Serge Tretjak ,  Alain Riondel

    发明人： Thierry Druzkowski ,  Gilles Herbst ,  Serge Tretjak ,  Alain Riondel

    IPC分类号： C07C6952

    CPC分类号： C07C213/08 ,  C07C219/08

    摘要： This process for the manufacture of an aqueous solution of the unsaturated quaternary ammonium salt corresponding to the formula (I), by reaction, in the presence of water, of N,N-dimethylaminoethyl acrylate (DAMEA) with a quaternizing agent of formula (II), is characterized in that the said reaction is carried out continuously in a rotating disc agitated column, with introduction of the quaternizing agent in the column bottom and introduction of the DAMEA and the water in the column top, the said reaction being carried out at a temperature of 35 to 60° C. and under a pressure of 10 to 20 bar.  R—Cl  (II) R=methyl or benzyl radical.

    摘要翻译： 通过在水存在下，将N，N-二甲基氨基乙基丙烯酸酯（DAMEA）与式（II）的季铵化剂反应制备对应于式（I）的不饱和季铵盐的水溶液的该方法 ），其特征在于所述反应在旋转圆盘搅拌柱中连续进行，并将季铵化合物引入塔底并将DAMEA和水引入塔顶，所述反应在 温度为35至60℃，压力为10至20巴.R =甲基或苄基。

    Method for making aqueous solutions of unsaturated quaternary ammonium salts
    7.
    发明授权
    Method for making aqueous solutions of unsaturated quaternary ammonium salts 有权
    制备不饱和季铵盐水溶液的方法

    公开(公告)号：US06521782B1

    公开(公告)日：2003-02-18

    申请号：US09889727

    申请日：2001-09-27

    申请人： Alain Riondel ,  Gilles Herbst ,  Marc Esch ,  Eric Delaunay ,  Peter Meyer

    发明人： Alain Riondel ,  Gilles Herbst ,  Marc Esch ,  Eric Delaunay ,  Peter Meyer

    IPC分类号： C07C6952

    CPC分类号： C07C213/08 ,  C07C219/08

    摘要： The present invention relates to a process for the manufacture of aqueous solutions of unsaturated quaternary ammonium salts. The salts can correspond to the following formula (I): in which R represents a methyl or benzyl radical, by reaction, in the presence of water, of N,N-dimethyl-amninoethyl acrylate (DAMEA) with a quaternizing agent of formula (II): R—Cl  (II) in which R is as defined above. Generally, the reaction is carried out in a closed reactor, which includes all the DAMEA and has been pressurized by air or depleted air to 0.5 to 3 bar, by continuously introducing, at a temperature of 35 to 65° C., the quatenlizing agent (II) and the water, until a concentration of salt (I) in the water is obtained. The water starts to be introduced beginning when 0-20% of the amount by weight of the quaternizing agent (II) necessary for the reaction has been added and it being possible for the pressure at the end of the reaction to reach 9 bar. Next, the reactor can be depressurized while keeping the oxygen content constant by simultaneous introduction of air and, after returning to atmospheric pressure, the residual quaternizing agent may be removed.

    摘要翻译： 本发明涉及一种制备不饱和季铵盐水溶液的方法。 盐可以对应于下式（I）：其中R表示甲基或苄基，通过在水存在下，将N，N-二甲基 - 氨基甲基乙基丙烯酸酯（DAMEA）与式（I）的季铵化剂反应 II）：其中R如上所定义。 通常，反应在封闭的反应器中进行，该反应器包括所有的DAMEA，并通过空气或贫化空气将其加压至0.5-3巴，通过在35至65℃的温度下连续引入季戊酸化剂 （II）和水，直到获得水中的盐（I）浓度。 当加入反应所需的季铵化剂（II）的重量的0-20％时，开始引入水，反应结束时的压力可能达到9巴。 接下来，可以通过同时引入空气同时保持氧含量恒定来减压反应器，并且在返回到大气压之后，可以除去残留的季铵化剂。