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公开(公告)号：US5847060A
公开(公告)日：1998-12-08
申请号：US912593
申请日：1997-08-18
Applicant: Alexei Alexeyevich Gridnev , Steven Dale Ittel
Inventor： Alexei Alexeyevich Gridnev , Steven Dale Ittel
IPC: C08F2/38 , C08F4/26 , C08F36/04 , C08F36/08 , C08F36/14 , C08F36/18 , C08F4/06 , C08F14/14 , C08F36/06
Abstract: This invention relates to the controlled molecular weight production of macromonomers and polymers with terminal conjugated double bonds from starting monomers including, but not limited to substituted butadienes. The terminal diene end thus produced is also a potential reaction site for further polymerization or functionalization. The molecular weight is controlled by use of Co chain transfer catalysts and appropriate process conditions.
Abstract translation: 本发明涉及从起始单体包括但不限于取代的丁二烯的具有末端共轭双键的大分子单体和聚合物的受控分子量产生。 由此产生的末端二烯端也是进一步聚合或官能化的潜在反应位点。 通过使用Co链转移催化剂和适当的工艺条件来控制分子量。
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2.发明授权公开(公告)号：US06388036B1
公开(公告)日：2002-05-14
申请号：US09857135
申请日：2001-05-31
Applicant: Alexei Alexeyevich Gridnev , Steven Dale Ittei
Inventor： Alexei Alexeyevich Gridnev , Steven Dale Ittei
IPC: C08F2400
CPC classification number: C08F24/00
Abstract: This invention relates to the oligomerization, polymerization and copolymerization of substituted and unsubstituted &agr;-methylene-&ggr;-butyrolactones and the products thereof, Cobalt (II) and cobalt (III) chain transfer catalysts are used to control the molecular weight and impart an aromatic functionality to the products formed.
Abstract translation: 本发明涉及取代和未取代的α-亚甲基-γ-丁内酯及其产物的低聚，聚合和共聚，钴（II）和钴（III）链转移催化剂用于控制分子量并赋予芳族官能度 到产品形成。
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公开(公告)号：US06388153B2
公开(公告)日：2002-05-14
申请号：US09851549
申请日：2001-05-09
Applicant: Alexei Alexeyevich Gridnev
Inventor： Alexei Alexeyevich Gridnev
IPC: C07C1552
CPC classification number: C09D125/02 , C07C2/04 , C07C15/50 , C07C209/68 , C07C263/16 , C07C275/24 , C07C2531/22 , C08F12/12 , C07C211/50 , C07C265/14
Abstract: The present invention relates to a method of making alpha-methylstyrene dimers by combining a cobalt catalyst, a free-radical initiator and an alpha-methylstyrene monomer, in an inert atmosphere, to form a mixture. The mixture is heated to a temperature in the range of 65° C. to 140° C. to form alpha methyl styrene dimers. The present invention also relates to the products produced by this inventive method.
Abstract translation: 本发明涉及通过在惰性气氛中组合钴催化剂，自由基引发剂和α-甲基苯乙烯单体来制备α-甲基苯乙烯二聚体以形成混合物的方法。 将混合物加热至65℃至140℃的温度，以形成α-甲基苯乙烯二聚体。 本发明还涉及通过本发明方法生产的产品。
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Patent Agency Ranking
公开(公告)号：US6117958A
公开(公告)日：2000-09-12
申请号：US193701
申请日：1998-11-17
Applicant: Steven Dale Ittel , Alexei Alexeyevich Gridnev
Inventor： Steven Dale Ittel , Alexei Alexeyevich Gridnev
IPC: C08F2/38 , C08F4/00 , C08F4/80 , C08F290/04
CPC classification number: C08F2/38 , C08F290/04 , C08F4/80
Abstract: This invention relates to a method by which olefinically-unsaturated organic molecules, which are otherwise nonpolymerizable, may be homopolymerized or copolymerized with conventional monomers through the use of cobalt chain transfer catalysts. The resulting macromonomers contain one terminal functional group and a terminal double bond on the other end of the chain.
Abstract translation: 本发明涉及一种通过使用钴链转移催化剂使烯属不饱和有机分子（其它不可聚合）与常规单体均聚或共聚的方法。 所得大分子单体在链的另一端含有一个末端官能团和末端双键。
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公开(公告)号：US06294708B1
公开(公告)日：2001-09-25
申请号：US09245521
申请日：1999-02-05
Applicant: Alexei Alexeyevich Gridnev
Inventor： Alexei Alexeyevich Gridnev
IPC: C07C274
CPC classification number: C09D125/02 , C07C2/04 , C07C15/50 , C07C209/68 , C07C263/16 , C07C275/24 , C07C2531/22 , C08F12/12 , C07C211/50 , C07C265/14
Abstract: The present invention relates to a method of making alpha-methylstyrene dimers by combining a cobalt catalyst, a free-radical initiator and an alpha-methylstyrene monomer, in an inert atmosphere, to form a mixture. The mixture is heated to a temperature in the range of 5° C. to 140° C. to form alpha methyl styrene dimers. The present invention also relates to the products produced by this inventive method.
Abstract translation: 本发明涉及通过在惰性气氛中组合钴催化剂，自由基引发剂和α-甲基苯乙烯单体来制备α-甲基苯乙烯二聚体以形成混合物的方法。 将混合物加热至5℃至140℃的温度，以形成α-甲基苯乙烯二聚体。 本发明还涉及通过本发明方法生产的产品。
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公开(公告)号：US5883206A
公开(公告)日：1999-03-16
申请号：US818860
申请日：1997-03-17
Applicant: Steven Dale Ittel , Alexei Alexeyevich Gridnev
Inventor： Steven Dale Ittel , Alexei Alexeyevich Gridnev
IPC: C08F2/38 , C08F4/00 , C08F4/80 , C08F290/04
CPC classification number: C08F2/38 , C08F290/04 , C08F4/80
Abstract: This invention relates to a method by which olefinically-unsaturated organic molecules, which are otherwise nonpolymerizable, may be homopolymerized or copolymerized with conventional monomers through the use of cobalt chain transfer catalysts. The resulting macromonomers contain one terminal functional group and a terminal double bond on the other end of the chain.
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7.发明授权Decolorization of hydroxy-containing methacrylate homopolymers and copolymers 失效含羟基甲基丙烯酸酯均聚物和共聚物的脱色
公开(公告)号：US5750772A
公开(公告)日：1998-05-12
申请号：US791373
申请日：1997-01-30
Applicant: Alexei Alexeyevich Gridnev
Inventor： Alexei Alexeyevich Gridnev
Abstract: This invention relates to a process whereby hydroxy-containing methacrylate homo- and copolymers are decolorized by the addition of a strong acid and a chelating bidentate nitrogen ligand, with subsequent filtering through a polar adsorption medium.
Abstract translation: 本发明涉及通过加入强酸和螯合二齿氮配体将含羟基的甲基丙烯酸酯均聚物和共聚物脱色，随后通过极性吸附介质过滤的方法。
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公开(公告)号：US5726263A
公开(公告)日：1998-03-10
申请号：US791372
申请日：1997-01-30
Applicant: Alexei Alexeyevich Gridnev
Inventor： Alexei Alexeyevich Gridnev
Abstract: Macromonomers formed by chain transfer catalysis polymerization methods may be decolorized by selective extraction and/or adsorption. The dimers and trimers formed during the polymerization reaction are also removed from the macromonomer mixture so that the remaining mixture has a very low optical density and a desirable degree of polymerization.
Abstract translation: 通过链转移催化聚合方法形成的大分子单体可以通过选择性萃取和/或吸附脱色。 在聚合反应期间形成的二聚体和三聚体也从大分子单体混合物中除去，使得剩余的混合物具有非常低的光密度和所需的聚合度。
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