摘要:
A process for making branched, substantially unsaturated fatty alcohols involving: (a) providing a C16-22 fatty acid; (b) dimerizing the C16-22 fatty acid to form a monomer fraction containing branched, substantially unsaturated fatty acids; (c) removing the monomer fraction; (d) esterifying the branched, substantially unsaturated fatty acids contained in the monomer fraction into branched, substantially unsaturated fatty acid methyl esters; and (e) hydrogenating the branched, substantially unsaturated fatty acid methyl esters with their double bonds intact, to form the branched, substantially unsaturated fatty alcohols.
摘要:
Alkyl-substituted butenols having the formula (I): R1—CH2—CH═CR2—CH2OH (I) wherein R1 is a saturated or olefinically unsaturated alkyl or cycloalkyl group having from 4 to 16 carbon atoms and wherein R1 is optionally substituted by an alkyl, cycloalkyl, aryl or alkaryl having up to 12 carbon atoms; R2 is hydrogen or an alkyl group having from 1 to about 6 carbon atoms are produced by a process which comprises: (1) reacting an aldehyde of the formula (II): R1—CH2—CHO (II) wherein R1 has the same meaning as in formula (I), with the corresponding lower aldehyde to form an unsaturated aldehyde in an inert organic solvent; (2) continuously contacting an optionally calcined copper/zinc catalyst with the unsaturated aldehyde under isothermal conditions at temperatures of from about 45 to about 60° C. and under a hydrogen pressure of from 1 to about 300 bar.
摘要:
Unsaturated palm oil fatty alcohols with an iodine number in the range from 65 to 85, which contain substantially unsaturated fatty alcohols and mixtures of saturated fatty alcohols of the formula (I): R1OH (I) in which R1 is a saturated or unsaturated, linear or branched alkyl radical having 14 to 20 carbon atoms, are obtained by (a) fractionating palm oil fatty acid methyl esters into a mainly saturated C16-distillate and a mainly unsaturated C16/18-bottom product; and (b) hydrogenating the bottom product with retention of the double bonds to give the corresponding alcohols.
摘要:
Unsaturated coconut and/or palm nut fatty alcohols having an iodine number in the range from 65 to 85, which essentially comprise unsaturated fatty alcohols and mixtures of saturated fatty alcohols of the formula (I): R1OH (I) in which R1 is a saturated or unsaturated, linear or branched alkyl radical having 12 to 20 carbon atoms, obtainable by fractionating coconut and/or palm nut fatty acid methyl esters to obtain a fraction containing predominantly C16-C18 portions, fractionating the C16-C18 fatty acid methyl ester fraction into a predominantly saturated distillate and a predominantly unsaturated bottom product, and hydrogenating the bottom product with retention of the double bonds to give the corresponding alcohols; are disclosed.
摘要:
The present invention relates to a process for preparing a compound having at least one ether group, at least one ester group, at least one amino group or at least one urethane group by a1) preparing 1,2-propanediol by means of a process wherein glycerol is hydrogenated in the presence of a catalyst, glycerol being reacted to at most 95% and a 1,2-propanediol phase obtained and a2) reacting the 1,2-propanediol phase with a compound having at least one active hydrogen atom, at least one epoxide group, at least one ester group or at least one isocyanate group. The present invention relates to the compounds which can be obtained using this process and the chemical products, emulsions, cosmetic formulations, plastics material compositions and drilling compositions prepared using the compound and the use and preparations thereof.
摘要:
The present invention relates to a process for preparing 1,2-propanediol by hydrogenation of glycerol by means of hydrogen gas, wherein glycerol is reacted with hydrogen in at least “i” fluidically interconnected reactors R1 to Ri each having a hydrogenation catalyst to form 1,2-propanediol, wherein the process comprises sequential steps from reactors R1 through Rn, wherein n as used hereinafter is an integer in the range from 2 to i. The process includes introducing hydrogen gas and a glycerol phase into the first reactor R1 and a first 1,2-propanediol containing phase and a first hydrogen phase are formed in the reactor, and introducing sequentially the 1,2-propanediol containing phase formed in the preceding reactor and hydrogen into each of the subsequent reactors wherein the glycerol phase containing at least 60% by weight, based on the total weight of the glycerol phase of glycerol.
摘要:
A resonator arrangement has a conductive, semi-open outer housing, at an interior of which a conductive bar is provided disposed coaxially to the housing. At one end of the bar in a direction of a housing bottom, the bar has a die and, together with a dielectric and the housing bottom, forms a capacitor. The bar is short-circuited to the housing at another end, so that the bar and housing together form an LC oscillator circuit. Also disclosed is a method for analyzing a sample using a resonator arrangement.
摘要:
The object of the invention is a dual-mode band pass filter consisting of resonators each having a spherically shaped dielectric arranged on at least one high-temperature superconductive film, with a shielding housing, which is arranged over the high-temperature superconductive film and which encloses the dielectric, and with a coupling device for coupling the dipole modes, as well as other coupling and tuning elements.
摘要:
A resonator arrangement has a conductive, semi-open outer housing, at an interior of which a conductive bar is provided disposed coaxially to the housing. At one end of the bar in a direction of a housing bottom, the bar has a die and, together with a dielectric and the housing bottom, forms a capacitor. The bar is short-circuited to the housing at another end, so that the bar and housing together form an LC oscillator circuit. Also disclosed is a method for analyzing a sample using a resonator arrangement.
摘要:
The invention relates to a near-field antenna comprising a dielectric shaped body having a tip. The shaped body is characterized in that at least the surface of the tip is metallized, thereby enhancing the sensitivity of devices comprising the near-field antenna, for example, spectroscopes, microscopes or read-write heads.