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公开(公告)号：US09358531B2
公开(公告)日：2016-06-07
申请号：US12808080
申请日：2008-12-03
申请人： Angela Carati , Donatella Berti , Roberto Millini , Franco Rivetti , Maria Angela Mantegazza , Gianni Girotti
发明人： Angela Carati , Donatella Berti , Roberto Millini , Franco Rivetti , Maria Angela Mantegazza , Gianni Girotti
IPC分类号： C01B39/08 , C01B37/00 , B01J29/89 , B01J35/02 , C07C249/04
CPC分类号： B01J29/89 , B01J35/023 , C01B37/005 , C01B39/085 , C07C249/04 , C07C251/44
摘要： The invention relates to a new process which allows the preparation of TS-1 zeolites in a pure phase and with a crystallinity higher than 95%, operating at reduced reaction volumes, and obtaining high productivities and extremely high crystallization yields. The particular crystalline form of the TS-1 zeolite thus prepared, is also described.
摘要翻译： 本发明涉及一种新方法，其允许在纯相中制备TS-1沸石并且结晶度高于95％，在降低的反应体积下操作，并且获得高生产率和极高的结晶产率。 还描述了如此制备的TS-1沸石的特定结晶形式。
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公开(公告)号：US06524984B2
公开(公告)日：2003-02-25
申请号：US09159751
申请日：1998-09-24
IPC分类号： B01J2906
CPC分类号： C01B37/005 , B01J29/06 , B01J29/40 , B01J2229/32 , C01B37/02 , C01B39/40 , Y10S423/22 , Y10S423/29
摘要： A process is described for the preparation of zeolitic catalysts in the form of microspheres, comprising zeolite and oligomeric silica, characterized by a high mechanical resistance. The process consists in subjecting to rapid drying the suspension, to which tetra-alkylorthosilicate is optionally added, resulting from the synthesis of zeolite by hydrothermal treatment at autogenous pressure of the reagent mixture containing tetra-alkylammoniumhydroxide as templating agent, and subjecting the product resulting from the drying to calcination.
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公开(公告)号：US07018595B2
公开(公告)日：2006-03-28
申请号：US10315022
申请日：2002-12-10
CPC分类号： C01B37/005 , B01J29/06 , B01J29/40 , B01J2229/32 , C01B37/02 , C01B39/40 , Y10S423/22 , Y10S423/29
摘要： A process is described for the preparation of zeolitic catalysts in the form of microspheres, comprising zeolite and oligomeric silica, characterized by a high mechanical resistance. The process consists in subjecting to rapid drying the suspension, to which tetra-alkylorthosilicate is optionally added, resulting from the synthesis of zeolite by hydrothermal treatment at autogenous pressure of the reagent mixture containing tetra-alkylammoniumhydroxide as templating agent, and subjecting the product resulting from the drying to calcination.
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公开(公告)号：US07074383B2
公开(公告)日：2006-07-11
申请号：US11107903
申请日：2005-04-18
IPC分类号： C01B39/36
CPC分类号： C01B37/005 , B01J29/06 , B01J29/40 , B01J2229/32 , C01B37/02 , C01B39/40 , Y10S423/22 , Y10S423/29
摘要： A process is described for the preparation of zeolitic catalysts in the form of microspheres, comprising zeolite and oligomeric silica, characterized by a high mechanical resistance. The process consists in subjecting to rapid drying the suspension, to which tetra-alkylorthosilicate is optionally added, resulting from the synthesis of zeolite by hydrothermal treatment at autogenous pressure of the reagent mixture containing tetra-alkylammoniumhydroxide as templating agent, and subjecting the product resulting from the drying to calcination.
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公开(公告)号：US06403514B1
公开(公告)日：2002-06-11
申请号：US09690732
申请日：2000-10-18
IPC分类号： B01J2034
摘要： A process is described for regenerating exhausted zeolitic catalysts containing titanium and deriving from oxidation processes of organic substrates with hydrogen peroxide. Said process consists in carrying out a treatment in an aqueous medium with hydrogen peroxide in the presence of inorganic fluorinated compounds, subsequent to thermal treatment of the exhausted catalyst.
摘要翻译： 描述了一种用于再生含有钛的耗尽的沸石催化剂并由有机底物氧化过程产生的过氧化氢的方法。 所述方法在于在无机氟化物的存在下，在热处理耗尽的催化剂之后，在含水介质中用过氧化氢进行处理。
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公开(公告)号：US20130011893A1
公开(公告)日：2013-01-10
申请号：US13518550
申请日：2010-12-23
CPC分类号： C07C2/864 , Y02E50/17 , Y02P20/52 , C07C15/073
摘要： The invention relates to a process for the production of ethylbenzene which comprises: a reaction step in which benzene is reacted with ethanol, or a mixture of ethanol and ethylene, at a pressure higher than atmospheric pressure, preferably in gaseous phase or in mixed gas-liquid phase, in the presence of a catalytic system containing a zeolite belonging to the BEA family, and a separation step of the product obtained. According to a preferred aspect, ethanol deriving from biomasses is used, in particular ethanol obtained from the fermentation of sugars deriving from biomasses.
摘要翻译： 本发明涉及一种生产乙苯的方法，该方法包括：在高于大气压，优选气相或混合气体反应器中，苯与乙醇或乙醇和乙烯的混合物反应的反应步骤， 在含有属于BEA族的沸石的催化体系的存在下，所得的产物的分离步骤。 根据优选的方面，使用衍生自生物质的乙醇，特别是从衍生自生物质的糖的发酵得到的乙醇。
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公开(公告)号：US09193643B2
公开(公告)日：2015-11-24
申请号：US13518550
申请日：2010-12-23
CPC分类号： C07C2/864 , Y02E50/17 , Y02P20/52 , C07C15/073
摘要： The invention relates to a process for the production of ethylbenzene which comprises: a reaction step in which benzene is reacted with ethanol, or a mixture of ethanol and ethylene, at a pressure higher than atmospheric pressure, preferably in gaseous phase or in mixed gas-liquid phase, in the presence of a catalytic system containing a zeolite belonging to the BEA family, and a separation step of the product obtained. According to a preferred aspect, ethanol deriving from biomasses is used, in particular ethanol obtained from the fermentation of sugars deriving from biomasses.
摘要翻译： 本发明涉及一种生产乙苯的方法，该方法包括：在高于大气压，优选气相或混合气体反应器中，苯与乙醇或乙醇和乙烯的混合物反应的反应步骤， 在含有属于BEA族的沸石的催化体系的存在下，所得的产物的分离步骤。 根据优选的方面，使用衍生自生物质的乙醇，特别是从衍生自生物质的糖的发酵得到的乙醇。
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公开(公告)号：US07154015B2
公开(公告)日：2006-12-26
申请号：US10019273
申请日：2001-05-15
申请人： Carlo Perego , Stefano Peratello , Paolo Pollesel , Sergio Sgorlon , Maria Angela Mantegazza , Massimo Romagnoli
发明人： Carlo Perego , Stefano Peratello , Paolo Pollesel , Sergio Sgorlon , Maria Angela Mantegazza , Massimo Romagnoli
IPC分类号： C07C4/06
CPC分类号： C07C4/06 , C07C2529/70 , C10G2400/20 , C07C11/06
摘要： Process for the production of propylene starting from mixtures of hydrocarbons, prevalently olefins, the above hydrocarbons having a boiling point ranging from −15° C. to +80° C., preferably from −12° C. to +60° C., which comprises putting the above mixture of hydrocarbons in contact, under cracking conditions, with a large-pore zeolite having a molar ratio Silica/Alumina lower than 200, preferably ranging from 50 to 150.
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公开(公告)号：US4918194A
公开(公告)日：1990-04-17
申请号：US262354
申请日：1988-10-25
IPC分类号： C07D295/22 , B01J29/035 , B01J29/04 , C07B43/00 , C07B61/00 , C07C239/08 , C07D295/24
CPC分类号： C07D295/24 , Y02P20/582
摘要： The invention relates to a process for the synthesis of an N,N-dialkyl-hydroxylamine by reaction of the corresponding dialkylamine with H.sub.2 O.sub.2, said reaction being carried out in the presence of a catalyst based on titanium-silicalite.
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公开(公告)号：US06288004B1
公开(公告)日：2001-09-11
申请号：US09305281
申请日：1999-05-05
申请人： Luigi Balducci , Raffaele Ungarelli , Daniele Bianchi , Maria Angela Mantegazza , Roberto Bagatin
发明人： Luigi Balducci , Raffaele Ungarelli , Daniele Bianchi , Maria Angela Mantegazza , Roberto Bagatin
IPC分类号： B01J2989
CPC分类号： C07C249/04 , B01J29/89 , C07C37/60 , C07D301/12 , Y02P20/52 , Y02P20/582 , C07C39/04 , C07C39/08
摘要： A method is described for improving the catalytic performances of titanium silicalite having formula (I) by the activation of the catalyst (I) in an aqueous medium with hydrogen peroxide, in the presence of precursors of fluoride ions or anionic species containing fluorine. The activated catalyst (I) is particularly useful in oxidation processes with hydrogen peroxide of organic substrates and, in particular, in hydroxylation reactions of aromatic compounds, amoximation reactions of carbonyl compounds, epoxidation reactions of olefinic compounds and oxidation reactions of nitrogenated compounds.
摘要翻译： 描述了一种通过在具有氟离子或含氟阴离子物质的前体的存在下，通过在具有过氧化氢的水性介质中活化催化剂（I）来改善式（I）的钛硅沸石的催化性能的方法。 活化的催化剂（I）特别适用于有机底物的过氧化氢的氧化过程，特别是芳族化合物的羟基化反应，羰基化合物的肟化反应，烯烃化合物的环氧化反应和含氮化合物的氧化反应。
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