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1.发明授权Polymers containing repeating cycloketonic units, and method for obtaining them 失效含有重复环丙基单元的聚合物及其获得方法
公开(公告)号：US5369187A
公开(公告)日：1994-11-29
申请号：US71517
申请日：1993-06-03
摘要： Polymers having a very good combination of chemical, mechanical and process properties, and particularly useable either alone or as mixtures, as high-tenacity thermoplastic polymer and as elastomers or elastomeric modifiers, contain, randomly distributed along their chain, repeating cycloketonic structural units having the following general formula (I): ##STR1## wherein: A represents a tetravalent aliphatic or cycloaliphatic, substituted or non-substituted moiety containing a total number of from 4 to 50, preferably from 4 to 20, carbon atoms.Such polymers can be prepared by means of a process which comprises reacting, in a liquid media, a polydiene containing adjacent structural units derived from the 1,4-cis polymerization of conjugated dienes, with carbon monoxide, in the presence of free radical generating compounds and, optionally, a compound capable of acting as a hydrogen donor.
摘要翻译： 作为高韧性热塑性聚合物和弹性体或弹性体改性剂，具有非常好的化学，机械和加工性能的组合，特别是可单独使用或作为混合物使用的聚合物包含沿着它们的链无规分布的重复的环酮结构单元， 通式（I）：其中：A表示含有总数为4至50，优选4至20个碳原子的四价脂族或脂环族，取代或未取代的部分。 这样的聚合物可以通过一种方法制备，该方法包括使液体介质中含有衍生自共轭二烯的1,4-顺式聚合的相邻结构单元的聚二烯与一氧化碳在存在自由基产生化合物 和任选的能够充当氢供体的化合物。
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2.发明授权Catalytic system and system for copolymerizing carbon monoxide with one or more olefins 失效用于将一氧化碳与一种或多种烯烃共聚的催化体系和系统
公开(公告)号：US5346873A
公开(公告)日：1994-09-13
申请号：US29476
申请日：1993-03-11
CPC分类号： C08G67/02
摘要： A catalyst active in the preparation of alternating olefin/carbon monoxide (CO) copolymers is constituted by:(a) at least one salt of a metal of Group IB of the Periodic System,(b) a mono or bidentate ligand base containing one or two nitrogen or phosphorus atoms capable of linking to the metal atom by means of dative bonds,(c) a mineral or organic oxidizer agent.Also disclosed are the preparation of the catalyst and the use of said catalyst in alternated copolymerization of ethylene (C2) and/or other olefins with carbon monoxide (CO).
摘要翻译： 在制备交替烯烃/一氧化碳（CO）共聚物中有活性的催化剂由以下组成：（a）至少一种周期系统IB族金属的盐，（b）含有一个或多个 能够通过二价键与金属原子连接的两个氮或磷原子，（c）矿物或有机氧化剂。 还公开了催化剂的制备和所述催化剂在乙烯（C2）和/或其它烯烃与一氧化碳（CO）的交替共聚中的用途。
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3.发明授权Preparation of alternating olefin/carbon monoxide copolymers by means of a heterogeneous supported catalyst 失效通过非均相负载催化剂制备交替的烯烃/一氧化碳共聚物
公开(公告)号：US5314856A
公开(公告)日：1994-05-24
申请号：US26022
申请日：1993-03-04
CPC分类号： C08G67/02 , B01J31/1625 , B01J31/1805 , B01J31/181 , B01J31/183 , B01J31/2243 , B01J31/2409 , B01J2531/824 , B01J31/223
摘要： A catalyst active in the preparation of alternating olefin/carbon monoxide (CO) copolymers is constituted by:(a) Pd(O.sub.2 CNEt.sub.2).sub.2 (NHET.sub.2).sub.2 supported on a solid carrier preferably constituted by hydroxylated silica,(b) an either mono- or bidentate ligand containing one or two nitrogen or phosphorous atoms capable of linking to Pd atom by dative bonds,(c) a mineral or organic acid.Disclosed are the preparation of the catalyst and the use of said catalyst in alternated copolymerization of ethylene (C2) and/or other olefins with carbon monoxide (CO).
摘要翻译： 用于制备交替烯烃/一氧化碳（CO）共聚物的催化剂由以下组成：（a）负载在优选由羟基化二氧化硅构成的固体载体上的Pd（O 2 CNEt 2）2（NHET 2）2，（b） 或含有一个或两个能通过二价键与Pd原子连接的氮或磷原子的二齿配体，（c）矿物或有机酸。 公开了催化剂的制备和所述催化剂在乙烯（C2）和/或其它烯烃与一氧化碳（CO）的交替共聚中的用途。
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4.发明授权Process for the preparation of copolymers of carbon monoxide and at least one compound containing an alkenyl unsaturation 失效制备一氧化碳和至少一种含有烯基不饱和化合物的共聚物的方法
公开(公告)号：US5734010A
公开(公告)日：1998-03-31
申请号：US825159
申请日：1997-03-26
IPC分类号： C08G67/02
CPC分类号： C08G67/02
摘要： Linear alternating copolymers of carbon monoxide and at least one compound containing an alkenyl unsaturation are obtained by reaction between carbon monoxide and at least one compound containing an alkenyl unsaturation, in a solvent which is liquid under the operating conditions, in the presence of a preformed bischelated catalyst having general formula (I) active without cocatalysts: �Pd(chel)(chel')!.sup.++ �A.sup.- !.sub.2 (I) wherein: chel and chel', the same or different, represent a nitrogenated or phosphorated bidentate chelating agent, and A.sup.- represents an essentially non-co-ordinating, non-esterifiable and non-labile anion selected from (3,5-(CF.sub.3).sub.2 -C.sub.6 H.sub.3).sub.4 B.sup.-, tetra(perfluorophenyl)borate B(C.sub.6 F.sub.5).sub.4.sup.- and Al(C.sub.6 F.sub.5).sub.4.sup.-.
摘要翻译： 一氧化碳和至少一种含烯基不饱和化合物的线性交替共聚物是通过一氧化碳与至少一种含有烯基不饱和键的化合物在操作条件下为液态的溶剂中，在预先形成的切割的 具有通式（I）的催化剂没有助催化剂：[Pd（螯合物）（螯合物）] ++ [A-] 2（I）其中：相同或不同的螯合物和螯合物代表氮化或磷酸化二齿螯合 并且A-表示选自（3,5-（CF 3）2 -C 6 H 3）4B-，四（全氟苯基）硼酸盐B（C 6 F 5）4 - 的基本上非配位，不可酯化和非不稳定的阴离子 和Al（C 6 F 5）4。
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5.发明授权Homogeneous catalytic system and process for copolymerizing olefins with carbon monoxide 失效均相催化体系和烯烃与一氧化碳的共聚方法
公开(公告)号：US5369073A
公开(公告)日：1994-11-29
申请号：US29875
申请日：1993-03-11
CPC分类号： C08G67/02
摘要： A catalyst active in the preparation of alternating olefin/carbon monoxide (CO) copolymers is constituted by:(a) at least one salt of a metal of Group IB of the Periodic System,(b) an either mono- or bidentate ligand containing one or two nitrogen or phosphorus atoms capable of linking to the copper, silver or gold atom by means of dative bonds,(c) a mineral or organic acid.Disclosed are the preparation of the catalyst and the use of said catalyst in alternated copolymerization of ethylene (C2) and/or other olefins with carbon monoxide.
摘要翻译： 在制备交替烯烃/一氧化碳（CO）共聚物中有活性的催化剂由以下组成：（a）至少一种周期系IB族金属的盐，（b）含有一个或多个 或能够通过二价键连接到铜，银或金原子的两个氮或磷原子，（c）矿物或有机酸。 公开了催化剂的制备和所述催化剂在乙烯（C2）和/或其它烯烃与一氧化碳的交替共聚中的用途。
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6.发明授权Process for the preparation of copolymers based on carbon monoxide and at least one compound having an alkenylic unsaturation 失效用于制备基于一氧化碳和至少一种具有烯基不饱和键的化合物的共聚物的方法
公开(公告)号：US5739264A
公开(公告)日：1998-04-14
申请号：US604651
申请日：1996-02-21
CPC分类号： C08G67/02
摘要： A process for the preparation of alternated linear copolymers based on carbon monoxide and one or more compounds having an unsaturation of the alkenylic type comprises, reacting in a halogenated aromatic or aliphatic solvent the carbon monoxide and one or more compounds having an alkenylic unsaturation in the presence of a catalyst having general formula (I) �Pd(chel)(chel')!.sup.+ �A.sup.- ! wherein: chel represents a non-charged bidentate chelating agent, chel' represents the anion of an organic compound containing a double carbon--carbon bond co-ordinated via .pi. bond to palladium (Pd) and a carbanion bound via .sigma. bond to palladium which is co-ordinated to the metal as a bidentate chelating agent and A.sup.- is an anion of a non-esterifiable or almost non-esterifiable and non-coordinating acid.
摘要翻译： 用于制备基于一氧化碳和一种或多种具有烯基型不饱和键的化合物的交替线性共聚物的方法包括：在卤代芳族或脂族溶剂中使一氧化碳和一种或多种在存在下具有烯基不饱和键的化合物 具有通式（I）[Pd（螯合物）（螯合物）] + [A-]的催化剂，其中：螯合物表示不带电的二齿螯合剂，“螯合物”表示含有双重碳原子的有机化合物的阴离子， 碳键通过π键与钯（Pd）和通过σ键键合的碳阴离子与钯结合，其与作为二齿螯合剂的金属配位，并且A-是不可酯化或几乎不相关的阴离子， 可酯化和非配位酸。
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公开(公告)号：US5310871A
公开(公告)日：1994-05-10
申请号：US14527
申请日：1993-02-08
CPC分类号： C08G67/02
摘要： Process for preparing straight, alternate polymers based on carbon monoxide and at least one olefin, which comprises causing carbon monoxide and the olefin to react in the presence of:(a) a catalyst of general formula (I):[Pd(chel)(chel')]++[A-].sub.2 (I) wherein chel and chel', which may be the same, or different from each other, represent a bidentate chelating agent and A- stands for an anion of an acid having a pKa smaller than 6; and(b) optionally, an organic oxidizer agent.
摘要翻译： 用于制备基于一氧化碳和至少一种烯烃的直链交替聚合物的方法，其包括使一氧化碳和烯烃在以下存在下反应：（a）通式（I）的催化剂：[Pd（螯合物）（ 螯合物）] ++ [A-] 2（I）其中可以相同或彼此不同的螯合物和螯合物代表二齿螯合剂，A-代表具有pKa的酸的阴离子 小于6; 和（b）任选的有机氧化剂。
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8.发明授权Process for the preparation of copolymers based on carbon monoxide and at least one compound containing an alkenyl unsaturation 失效用于制备基于一氧化碳和至少一种含有烯基不饱和化合物的共聚物的方法
公开(公告)号：US5717060A
公开(公告)日：1998-02-10
申请号：US741901
申请日：1996-10-31
CPC分类号： C08G67/02
摘要： An improved process is described for the preparation of alternating linear copolymers based on carbon monoxide and at least one compound containing an alkenyl unsaturation which comprises reacting in a liquid solvent under the operating conditions, a mixture of carbon monoxide and one or more compounds containing an alkenyl unsaturation in the presence of: (i) a catalyst having general formula (I) �Pd(chel) (chel') !.sup.++ �A.sup.- !.sub.2 (I) wherein chel and chel' the same or different, represent a nitrogenated or phosphorated bidentate chelating agent, and A.sup.- represents an essentially non-coordinating, non esterifiable and non labile anion of an acid with pKa less than 2; and (ii) a cocatalyst having general formula (II) �chel"H.sup.+ !�A'.sup.- ! (II) wherein A'.sup.-, the same as or different from A.sup.-, has the same meaning defined above and chel" represents a nitrogenated bidentate chelating agent the same as or different from chel and chel'.
摘要翻译： 描述了一种用于制备基于一氧化碳和至少一种含有烯基不饱和键的化合物的交替线性共聚物的改进方法，该化合物包括在操作条件下在液体溶剂中反应，一氧化碳和一种或多种含有烯基的化合物的混合物 存在下的不饱和度：（i）具有通式（I）[Pd（螯合物）（螯合物）] ++ [A-] 2（I）的催化剂，其中螯合物和螯合物相同或不同，代表氮化 或磷酸二异构螯合剂，A-代表pKa小于2的酸的基本上非配位的，非酯化的和非不稳定的阴离子; 和（ii）具有通式（II）[chel'H +] [A' - ]（II）的助催化剂，其中与A相同或不同的A'具有与上述相同的含义，并且“ 表示与螯合物相同或不同的氮化二齿螯合剂。
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9.发明授权Preparation of alternating olefin/carbon monoxide copolymers by means of a heterogeneous supported catalyst 失效通过非均相负载催化剂制备交替的烯烃/一氧化碳共聚物
公开(公告)号：US5408030A
公开(公告)日：1995-04-18
申请号：US198274
申请日：1994-02-18
CPC分类号： C08G67/02 , B01J31/1625 , B01J31/1805 , B01J31/181 , B01J31/183 , B01J31/2243 , B01J31/2409 , B01J2531/824 , B01J31/223
摘要： A catalyst active in the preparation of alternating olefin/carbon monoxide (CO) copolymers is constituted by:(a) Pd(O.sub.2 CNEt.sub.2).sub.2 (NHET.sub.2).sub.2 supported on a solid carrier preferably constituted by hydroxylated silica,(b) an either mono- or bidentate ligand containing one or two nitrogen or phosphorous atoms capable of linking to Pd atom by dative bonds,(c) a mineral or organic acid.Disclosed are the preparation of the catalyst and the use of said catalyst in alternated copolymerization of ethylene (C2) and/or other olefins with carbon monoxide (CO).
摘要翻译： 用于制备交替烯烃/一氧化碳（CO）共聚物的催化剂由以下组成：（a）负载在优选由羟基化二氧化硅构成的固体载体上的Pd（O 2 CNEt 2）2（NHET 2）2，（b） 或含有一个或两个能通过二价键与Pd原子连接的氮或磷原子的二齿配体，（c）矿物或有机酸。 公开了催化剂的制备和所述催化剂在乙烯（C2）和/或其它烯烃与一氧化碳（CO）的交替共聚中的用途。
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公开(公告)号：US5370918A
公开(公告)日：1994-12-06
申请号：US100577
申请日：1993-07-30
CPC分类号： D06M23/08 , C08J5/06 , D01F11/14 , Y10S428/902 , Y10T428/237 , Y10T428/249948 , Y10T428/2929 , Y10T428/2964 , Y10T428/2982
摘要： A mixed-matrix composite material reinforced with continuous fibre comprising a flexible sheath of thermoplastic polymer covering a multifibre filament impregnated with a powder consisting of:50-99% by weight, and preferably 70-95%, of a thermoplastic polymer;50-1% by weight, and preferably 30-5%, of a C.sub.2 -C.sub.4 olefin/carbon monoxide alternating polymer having an intrinsic viscosity exceeding 0.1 dl/g when measured in m-cresol at 100.degree. C.
摘要翻译： 用连续纤维增强的混合基质复合材料，其包括热塑性聚合物的柔性护套，其覆盖多层纤维，所述多纤维被浸渍有由以下组成的粉末：50-99重量％，优选70-95重量％的热塑性聚合物; 当在间甲酚中在100℃下测定时，特性粘度超过0.1dl / g的C 2 -C 4烯烃/一氧化碳交替聚合物为50-1重量％，优选30-5重量％
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