摘要:
Methods comprising: providing a test substance, providing two solvents that are substantially immiscible, introducing a known amount of the test substance and known amounts of the two solvents into a single vessel to create a pre-equilibrium sample, adjusting the concentration of the test substance in the pre-equilibrium sample so that the concentration of the test substance is below the critical micelle concentration of both solvents if the concentration of the test substance is not already below the critical micelle concentration, allowing the test substance to equilibrate between the two solvents over time at a substantially constant temperature, determining the equilibrium concentration of the test substance in each of the solvents, and calculating the partition coefficient.
摘要:
Of the many methods and compositions provided herein, one method includes a method comprising contacting a metal surface with an acidic fluid comprising an aqueous base-fluid, an acid, a corrosion inhibitor, and a corrosion inhibitor intensifier composition comprising a compound that corresponds to a formula R1R2XCCOOH, wherein X is a halogen, R1 comprises at least one group selected from the group consisting of a C1-C20 alkyl group, a C3-C20 cycloalkyl group, a C1-C20 oxyalkyl, and a C6-C20 aryl group, and R2 comprises at least one group selected from the group consisting of a C1-C20 alkyl group, a C3-C20 cycloalkyl group, a C1-C20 oxyalkyl, and a C6-C20 aryl group.
摘要:
Methods and compositions that include a method comprising providing a treatment fluid that comprises an aqueous base fluid, a biocide, a biocide enhancer, a friction reducer, and a compatibility aid, and introducing the treatment fluid into a subterranean formation. A composition provided includes a treatment fluid comprising an aqueous base fluid, a biocide, a biocide enhancer, a friction reducer, and a compatibility aid.
摘要:
Of the many methods and compositions provided herein, one method includes a method comprising contacting a metal surface with an acidic fluid comprising an aqueous base-fluid, an acid, a corrosion inhibitor, and a corrosion inhibitor intensifier composition comprising a compound that corresponds to a formula R1R2XCCOOH, wherein X is a halogen, R1 comprises at least one group selected from the group consisting of a C1-C20 alkyl group, a C3-C20 cycloalkyl group, a C1-C20 oxyalkyl, and a C6-C20 aryl group, and R2 comprises at least one group selected from the group consisting of a C1-C20 alkyl group, a C3-C20 cycloalkyl group, a C1-C20 oxyalkyl, and a C6-C20 aryl group.
摘要:
The present invention relates to well bore stabilization and, more particularly, to treatment fluids that may reduce the tendency of shales to swell and associated methods. In some embodiments, the present invention provides a method of stabilizing a subterranean formation that comprises a shale, the method comprising contacting the subterranean formation that comprises the shale with a treatment fluid, the treatment fluid comprising a base fluid, and a hydrophobically modified polymer. In other embodiments, the treatment fluids comprise a base fluid and a hydrophilically modified polymer. In yet other embodiments, the present invention provides shale-inhibiting components, treatment fluids, and methods of reducing the tendency of shale to swell when exposed to a treatment fluid.
摘要:
Provided herein are defoaming agents that comprise lecithin and a solvent. Optionally, they may comprise hydrophobic particles. One embodiment provides a defoaming agent that comprises lecithin and a solvent.
摘要:
A method of treating a subterranean formation including with a bactericidal fluid is provided. The method comprises the steps of: (a) continuously mixing to obtain a stream of a treatment fluid: (i) a base fluid comprising water; (ii) an aqueous solution comprising a hypochlorite having a pH equal to or greater than 7; and (iii) a pH-adjusting agent selected to be capable of lowering the pH of water to less than 7; and (b) injecting the treatment fluid into a wellbore. The step of continuously mixing the base fluid, the aqueous solution of hypochlorite, and the pH-adjusting agent is preferably under conditions and in proportions sufficient to obtain a stream of a treatment fluid having a free chlorine concentration of at least 1 ppm by weight of the water in the treatment fluid and having a pH in the range of 4-7.
摘要:
For use in estimating or predicting bioaccumulation of a chemical analyte, even a surfactant, log Pow values for the analyte may be determined by calculating the log of the ratio of the concentrations of the analyte in n-octanol and in water, equilibrated using a slow-stir method. In this method, samples of the analyte are prepared and stirred in n-octanol and water (or other largely immiscible solvents) at a rate sufficiently low to avoid emulsions over time at a constant temperature. After stirring, the n-octanol layer and the water layer are sampled and the quantity of analyte in each measured.
摘要:
An inverter fluid that intermixes with a non-aqueous (e.g., oil) external/aqueous internal fluid to cause external/internal inversion is designed. This includes testing a selected inverter fluid with a test fluid having a composition nominally equivalent to the composition of the non-aqueous external/aqueous internal fluid. A quantity of the designed inverter fluid is made and placed in the annulus of a well, such as an oil or gas well, to remove the non-aqueous external/aqueous internal fluid on at least a portion of one or more surfaces of the annulus. This can include pumping the inverter fluid along with a stream of cement. The inverter fluid displaces at least part of the non-aqueous external/aqueous internal fluid in the annular region and inverts the coating of non-aqueous external/aqueous internal fluid sufficient to remove the coating ahead of the cement. Determining a suitable inverter fluid comprises: measuring a parameter related to electrical conductivity of an initial mixture including (1) a test fluid having a composition nominally equivalent to the non-aqueous external/aqueous internal fluid and (2) part of a selected inverter fluid; and adding a further part of the selected inverter fluid to the initial mixture until the measured parameter indicates the external/internal phases of the test fluid have inverted.
摘要:
Disclosed herein are defoamers comprising ethylene glycol, a defoaming hydrocarbon base fluid, and a non-ionic surfactant wherein the hydrocarbon base fluid comprises an internal olefin or a straight-chain n-alcohol, and wherein the non-ionic surfactant is present in the defoamer in an amount in the range of from about 1% to about 10% by weight of the defoamer. Also disclosed herein are cement compositions comprising water, hydraulic cement, and a defoamer, wherein the defoamer comprises ethylene glycol, a non-ionic surfactant, and a defoaming hydrocarbon base fluid wherein the hydrocarbon base fluid comprises an internal olefin or a straight-chain n-alcohol, and wherein the non-ionic surfactant is present in the defoamer in an amount in the range of from about 1% to about 10% by weight of the defoamer.