公开(公告)号：US07081437B2

公开(公告)日：2006-07-25

申请号：US10647829

申请日：2003-08-25

申请人： Arvind D. Patel ,  Jim Friedheim ,  John Candler ,  Stephen Rabke

发明人： Arvind D. Patel ,  Jim Friedheim ,  John Candler ,  Stephen Rabke

IPC分类号： C09K8/34

CPC分类号： C09K8/34

摘要： A method of formulating and the resulting biodegradable wellbore fluid includes a first synthetic internal olefin fraction having from 16 to 18 carbon atoms (C16-18 IO), a second synthetic internal olefin fraction having between 15 to 18 carbon atoms (C15-18 IO), and a third synthetic internal olefin fraction having 15 to 16 carbon atoms (C15-16 IO). The components of the wellbore fluid are blended such that the desired characteristics of polycyclic aromatic hydrocarbon content, toxicity and biodegrability are balance to achieve compliance with environmental requirements for hydrocarbon based drilling fluids. One such illustrative embodiment achieves this result by utilizing a formulation in which the first internal olefin fraction is present in a range of about 45 to about 55 percent by weight of the wellbore fluid and wherein the second internal olefin fraction is present in range of about 20 to about 30 percent by weight of the wellbore fluid and wherein the third olefin fraction is present in range of about 20 to about 30 percent by weight of the wellbore fluid. Optionally, the illustrative fluid can include a C16 alpha olefin (C16 AO). In such instances, the C16 alpha olefin (C16 AO) is present in the range of about 10 to about 20 percent by weight of the wellbore fluid.

摘要翻译： 配制方法和所得到的可生物降解的井筒流体包括具有16至18个碳原子（C 16-18 O 10）的第一合成内烯烃部分，具有15至18个碳原子的第二合成内烯烃部分 碳原子（C 15-18 O）和具有15至16个碳原子的第三合成内烯烃部分（C 15-16 I）。 将井眼流体的组分混合，使得多环芳烃含量，毒性和生物降解性的期望特征是平衡的，以达到符合烃基钻井液的环境要求。 一个这样的说明性实施例通过使用其中第一内部烯烃部分以约45至约55重量％的井眼流体​​的范围存在的配方实现该结果，并且其中第二内部烯烃部分以约20的范围存在 至约30重量％的井筒流体，并且其中第三烯烃馏分以井眼流体的约20重量％至约30重量％的范围存在。 任选地，说明性的流体可以包括C 16 C 17α-烯烃（C 16 C 40）。 在这种情况下，C 16 C 17α-烯烃（C 16 O 40）以井眼流体的约10至约20重量％的范围存在。

公开(公告)号：US20050054539A1

公开(公告)日：2005-03-10

申请号：US10647829

申请日：2003-08-25

申请人： Arvind Patel ,  Jim Friedheim ,  John Candler ,  Stephen Rabke

发明人： Arvind Patel ,  Jim Friedheim ,  John Candler ,  Stephen Rabke

IPC分类号： C09K7/00

CPC分类号： C09K8/34

摘要： A method of formulating and the resulting biodegradable wellbore fluid includes a first synthetic internal olefin having from 16 to 18 carbon atoms (C16-18 IO), a second synthetic internal olefin having between 15 to 18 carbon atoms (C15-18 IO), and a third synthetic internal olefin having 15 to 16 carbon atoms (C15-16 IO). The components of the wellbore fluid are blended such that the desired characteristics of polycyclic aromatic hydrocarbon content, toxicity and biodegrability are balance to achieve compliance with environmental requirements for hydrocarbon based drilling fluids. One such illustrative embodiment achieves this result by utilizing a formulation in which the first internal olefin is present in a range of about 45 to about 55 percent by weight of the wellbore fluid and wherein the second internal olefin is present in range of about 20 to about 30 percent by weight of the wellbore fluid and wherein the third olefin is present in range of about 20 to about 30 percent by weight of the wellbore fluid. Optionally, the illustrative fluid can include a C16 alpha olefin (C16 AO). In such instances, the C16 alpha olefin (C16 AO) is present in the range of about 10 to about 20 percent by weight of the wellbore fluid.

摘要翻译： 配制和生成的可生物降解的井筒流体的方法包括具有16-18个碳原子的第一合成内烯烃（C16-18O10），具有15-18个碳原子的第二合成内烯烃（C15-18O）和 具有15至16个碳原子的第三合成内烯烃（C 15-16 IO）。 将井眼流体的组分混合，使得多环芳烃含量，毒性和生物降解性的期望特征是平衡的，以达到符合烃基钻井液的环境要求。 一个这样的说明性实施方案通过使用其中第一内烯存在于井眼流体的约45至约55重量％的范围内的制剂来实现该结果，并且其中第二内烯存在的范围为约20至约 30重量％的井眼流体​​，其中第三烯烃以井眼流体的约20重量％至约30重量％的范围存在。 任选地，说明性流体可以包括C16α烯烃（C16AO）。 在这种情况下，C16α烯烃（C16 AO）的存在量是井眼流体重量的约10％至约20％。

公开(公告)号：US20080009422A1

公开(公告)日：2008-01-10

申请号：US11772618

申请日：2007-07-02

申请人： Arvind D. Patel ,  Emanuel Stamatakis ,  Steve Young ,  Jim Friedheim

发明人： Arvind D. Patel ,  Emanuel Stamatakis ,  Steve Young ,  Jim Friedheim

IPC分类号： C09K8/18

CPC分类号： C09K8/18 ,  C09K8/035 ,  C09K2208/12 ,  C09K2208/34

摘要： A water based drilling fluid which includes an aqueous fluid, at least one of a weighting agent and a gelling agent, and a lubricant, which includes at least one ester derivative of at least one fatty acid derived from castor oil is disclosed.

摘要翻译： 公开了一种水基钻井液，其包括水性流体，至少一种加重剂和胶凝剂，以及润滑剂，其包含至少一种衍生自蓖麻油的脂肪酸的酯衍生物。

公开(公告)号：US07250390B2

公开(公告)日：2007-07-31

申请号：US11008008

申请日：2004-12-09

申请人： Arvind D. Patel ,  Emanuel Stamatakis ,  Eric Davis ,  Jim Friedheim

发明人： Arvind D. Patel ,  Emanuel Stamatakis ,  Eric Davis ,  Jim Friedheim

IPC分类号： C09K8/04

CPC分类号： C09K8/22 ,  C09K8/24 ,  C09K2208/12

摘要： A water-base fluid for use in drilling wells and other drilling operation includes a shale clay which swells in the presence of water. The fluid preferably includes: an aqueous based continuous phase, and a shale hydration inhibition agent having the formula: H—(OR)x—[—NH—CH2—CH2—CH2—O—CH2—CH2—NH—]—(R′O)y—H wherein R and R′ are independently selectable alkylene groups having 2 to 4 carbon atoms, and wherein x and y have independently selected values such that the sum of x and y is at least 1. The shale hydration inhibition agent should be present in sufficient concentration to reduce the swelling of the shale clay. The fluid may be used for formulating drilling fluids such as water-base drilling muds or clear brine drilling fluids. The fluid may also be used in the slurrification and disposal of drill cuttings that contain water swellable clays or shale clays.

摘要翻译： 用于钻井和其他钻井操作的水基流体包括在水存在下膨胀的页岩粘土。 流体优选包括：基于水的连续相和具有下式的页岩水合抑制剂：<？in-line-formula description =“In-line Formulas”end =“lead”？> H（OR） _{- - - - - - - - - - - CH 2 -CH 2 CH 2 -CH 2 CH 2 - -N 2 - （R'O） - - - - （R'O）y -H-α-in-line-formula description =“In-line Formulas”end =“ 尾“→其中R和R'独立地是可选择的具有2至4个碳原子的亚烷基，并且其中x和y具有独立选择的值，使得x和y之和至少为1.页岩水化抑制剂应为 以足够的浓度存在，以减少页岩粘土的膨胀。 流体可以用于配制钻井液，例如水基钻井泥浆或透明盐水钻井液。 该流体也可用于含有可溶胀的粘土或页岩粘土的钻屑的脱气和处理。}

公开(公告)号：US07084092B2

公开(公告)日：2006-08-01

申请号：US10647830

申请日：2003-08-25

申请人： Arvind D. Patel ,  Emanuel Stamatakis ,  Eric Davis ,  Jim Friedheim

发明人： Arvind D. Patel ,  Emanuel Stamatakis ,  Eric Davis ,  Jim Friedheim

IPC分类号： C09K8/12

CPC分类号： C09K8/06 ,  C09K8/22 ,  C09K2208/12 ,  Y10S507/922

摘要： A water-base fluid for use in drilling, cementing, workover, fracturing and abandonment of subterranean wells through a formation containing a shale which swells in the presence of water. In one illustrative embodiment, the drilling fluid includes, an aqueous based continuous phase, a weighting agent, and a shale hydration inhibition agent. The shale hydration inhibition agent should have the general formula: in which A is independently selected from H and CH2CH2CH2NH2; and in which B is independently selected from H, CH2CH2OH, CH2CH2OCH2CH2CH2NH2 and CH2CH2CH2NH2. The shale hydration inhibition agent is present in sufficient concentration to substantially reduce the swelling of shale drilling cuttings upon contact with the drilling fluid. The drilling fluid may be formulated to include a wide variety of components of aqueous based drilling fluids, such as weighting agents, fluid loss control agents, suspending agents, viscosifying agents, rheology control agents, as well as other compounds and materials known to one of skill in the art. The fluids may also be used in the disposal by reinjection of drilling cutting into a selected subterranean disposal formation.

摘要翻译： 一种用于通过含有在水存在下膨胀的页岩的地层的钻井，固井，修井，压裂和放弃地下井的水基流体。 在一个说明性实施例中，钻井流体包括水基连续相，加重剂和页岩水合抑制剂。 页岩水化抑制剂应具有以下通式：其中A独立地选自H和CH 2 CH 2 CH 2 H 2 N _{2 并且其中B独立地选自H，CH 2 CH 2 OH，CH 2 CH 2 OCH 2， 2> 2 CH 2 2 CH 2 NH 2和CH 2 CH 2 2 < / 2 NH 2。 页岩水化抑制剂以足够的浓度存在，以在与钻井液接触时基本上减少页岩钻屑的膨胀。 钻井液可以被配制成包括水基钻井液的各种各样的组分，例如加重剂，流体损失控制剂，悬浮剂，增粘剂，流变控制剂，以及其它化合物和材料 艺术技能 流体还可以通过将钻削切割注入到选定的地下处理层中而用于处理。}

公开(公告)号：US06831043B2

公开(公告)日：2004-12-14

申请号：US10062071

申请日：2002-01-31

申请人： Arvind D. Patel ,  Emanuel Stamatakis ,  Eric Davis ,  Jim Friedheim

发明人： Arvind D. Patel ,  Emanuel Stamatakis ,  Eric Davis ,  Jim Friedheim

IPC分类号： C09K702

CPC分类号： C09K8/22 ,  C09K8/24 ,  C09K2208/12

摘要： A water-base fluid for use in drilling wells and other drilling operation includes a shale clay which swells in the presence of water. The fluid preferably includes: an aqueous based continuous phase, and a shale hydration inhibition agent having the formula: wherein R and R′ are independently selectable alkylene groups having 2 to 4 carbon atoms, and wherein x and y have independently selected values such that the sum of x and y is at least 1. The shale hydration inhibition agent should be present in sufficient concentration to reduce the swelling of the shale clay. The fluid may be used for formulating drilling fluids such as water-base drilling muds or clear brine drilling fluids. The fluid may also be used in the slurrification and disposal of drill cuttings that contain water swellable clays or shale clays.

摘要翻译： 用于钻井和其他钻井操作的水基流体包括在水存在下膨胀的页岩粘土。 流体优选包括：基于水性的连续相和具有下式的页岩水化抑制剂：其中R和R'独立地是可选择的具有2至4个碳原子的亚烷基，并且其中x和y具有独立选择的值，使得 x和y之和至少为1.页岩水化抑制剂应以足够的浓度存在，以减少页岩粘土的溶胀。 流体可以用于配制钻井液，例如水基钻井泥浆或透明盐水钻井液。 该流体也可用于含有可溶胀的粘土或页岩粘土的钻屑的脱气和处理。

公开(公告)号：US06770602B2

公开(公告)日：2004-08-03

申请号：US10062854

申请日：2002-01-31

申请人： Arvind D. Patel ,  Reginald Bell ,  Burhan Hoxha ,  Jim Friedheim

发明人： Arvind D. Patel ,  Reginald Bell ,  Burhan Hoxha ,  Jim Friedheim

IPC分类号： C09K706

CPC分类号： C09K8/36 ,  C09K2208/18

摘要： A fluid having utility in subterranean wells is formulated to include: an oleaginous fluid; and a solids tolerance agent having the formula: in which R is a C6 to C20 aliphatic group and R′ is a C2 to C6 aliphatic group and x has a value from about 1 to about 10. Preferably R′ is selected from ethyl and isopropyl and R is an unsaturated aliphatic group. The fluid is formulated such that the oleaginous fluid is from about 30% to about 99% by volume of said fluid. In one illustrative embodiment, the oleaginous fluid is composed from about 5% to about 100% by volume of the oleaginous fluid of a material selected from a group consisting of diesel oil, mineral oil, synthetic oil, esters, ethers, acetals, di-alkylcarbonates, olefins, and combinations of these and similar fluids. A non-oleaginous fluid may also be included in the formulation that is from about 1% to about 70% by volume of said fluid. The non-oleaginous fluid is preferably selected from sea water, a brine containing organic or inorganic dissolved salts, a liquid containing water-miscible organic compounds, and combinations thereof. Also included in the fluid formulation may be weighting agents, fluids loss agents, viscosity agents and other similar agents utilized in the formulation of oil-based and invert emulsion drilling fluids.

摘要翻译： 在地下井中具有效用的流体被配制成包括：含油流体; 和具有下式的固体耐受剂：其中R是C6至C20脂族基团，R'是C2至C6脂族基团，x具有约1至约10的值。优选地，R'选自乙基和异丙基 并且R是不饱和脂族基团。 流体被配制成使得含油流体占所述流体的约30体积％至约99体积％。 在一个说明性实施方案中，含油流体由选自柴油，矿物油，合成油，酯，醚，缩醛，二缩水甘油醚的材料的约5体积％至约100体积％的油质流体组成， 烷基碳酸酯，烯烃，以及这些和类似流体的组合。 制剂中也可以包含约1％至约70％体积的所述流体的非含油液体。 非油质流体优选选自海水，含有机或无机溶解盐的盐水，含有水混溶性有机化合物的液体及其组合。 还包括在流体配方中可以是增稠剂，流体损失剂，粘度剂和用于油基和反相乳液钻井液配方中的其它类似物质。

公开(公告)号：US06589917B2

公开(公告)日：2003-07-08

申请号：US09745147

申请日：2000-12-20

申请人： Arvind D. Patel ,  Jim Friedheim

发明人： Arvind D. Patel ,  Jim Friedheim

IPC分类号： C09K706

CPC分类号： C09K8/32 ,  C09K8/36 ,  C09K8/52 ,  E21B21/068

摘要： An invert emulsion suitable for drilling subterranean wells, in particular oil and gas wells is disclosed which has negative alkalinity and includes an oleaginous phase, and a non-oleaginous phase and an emulsifying agent which stabilizes the invert emulsion under conditions of negative alkalinity. The practice of the present invention permits the formulation of drilling fluids which are absent an alkaline reserve and are compatible with elastomers utilized in drilling equipment. Thus the invert emulsion fluids of the present invention are highly suitable for drilling oil and gas wells.

摘要翻译： 公开了一种适用于钻井地下井，特别是油气井的反相乳液，其具有负碱性并且包括油相，以及在负极性条件下稳定反相乳液的非油质相和乳化剂。 本发明的实践允许制备不存在碱性储备并与钻井设备中使用的弹性体相容的钻井液。 因此，本发明的倒液乳液非常适用于钻油气井。

公开(公告)号：US08524640B2

公开(公告)日：2013-09-03

申请号：US11772588

申请日：2007-07-02

申请人： Arvind D. Patel ,  Sashikumar Mettath ,  Emanuel Stamatakis ,  Steve Young ,  Jim Friedheim

发明人： Arvind D. Patel ,  Sashikumar Mettath ,  Emanuel Stamatakis ,  Steve Young ,  Jim Friedheim

IPC分类号： C09K8/035

CPC分类号： C09K8/36 ,  C09K8/502

摘要： A composition that includes a product resulting from a condensation reaction of quebracho with at least one organophilic species that includes a reactive amine is disclosed.

摘要翻译： 公开了一种组合物，其包含由quebracho与至少一种包含反应性胺的亲有机体的缩合反应产生的产物。

公开(公告)号：US07871962B2

公开(公告)日：2011-01-18

申请号：US10647737

申请日：2003-08-25

申请人： Arvind D. Patel ,  Jim Friedheim ,  John Lee ,  Burnham Hoxha

发明人： Arvind D. Patel ,  Jim Friedheim ,  John Lee ,  Burnham Hoxha

IPC分类号： C09K8/36 ,  C09K8/34

CPC分类号： C09K8/36 ,  C09K2208/18

摘要： A drilling fluid having an oleaginous fluid that forms the continuous phase; a non-oleaginous fluid, which is the discontinuous phase; a primary emulsifier in sufficient concentration to stabilize the invert emulsion; and a rheology modifier, which serves to moderate the rheology change across a temperature range of 40 to 150° C. The rheology modifier may be a dimer poly-carboxylic C12 to C22 fatty acid, trimer poly-carboxylic C12 to C22 fatty acid, tetramer poly-carboxylic C12 to C22 fatty acid, mixtures of these acids, or a polyamide wherein the polyamide is the condensation reaction product of a C12-C22 fatty acid and a polyamine selected from the group consisting of diethylenetriamine, triethylenetetramine; and pentaethylenetetramine. The drilling fluid preferably includes a weighting agent or bridging agent which may be selected from galena, hematite, magnetite, iron oxides, illmenite, barite, siderite, celestite, dolomite, calcite as well as combinations and mixtures of these and similar compounds. Optionally organophillic clay, fluid loss agents, alkali reserve materials, and other conventional invert emulsion drilling fluid components may be added to the drilling fluid.

摘要翻译： 具有形成连续相的含油流体的钻井液; 非油质流体，其是不连续相; 足够浓度的初级乳化剂以稳定反相乳液; 和流变改性剂，其用于在40至150℃的温度范围内调节流变学变化。流变改性剂可以是二聚体多羧酸C12至C22脂肪酸，三聚体多羧酸C12至C22脂肪酸，四聚体 聚羧酸C12至C22脂肪酸，这些酸的混合物或聚酰胺，其中聚酰胺是C12-C22脂肪酸和选自二亚乙基三胺，三亚乙基四胺的多胺的缩合反应产物; 和五亚乙基四胺。 钻井液优选包括可以选自方铅矿，赤铁矿，磁铁矿，氧化铁，镍铁矿，重晶石，菱铁矿，天青石，白云石，方解石以及这些和类似化合物的组合和混合物的加重剂或桥接剂。 任选地，有机物粘土，流体损失剂，碱储备材料和其它常规的反相乳液钻井液组分可以添加到钻井液中。