摘要:
A composite material which has excellent ballistic performance and has improved flexibility. Surprisingly, it has been found that a combination of poly(alpha-olefin) fiber and matrix resin provides these desirable product features. The resin matrix is a block copolymer of a conjugated diene and a vinyl aromatic monomer, preferably a styrene-isoprene-styrene block copolymer, that is applied as an aqueous composition. The fiber has a tenacity of at least about 35 g/d and a tensile modulus of at least about 1200 g/d. The composite has a total density equal to or less than about 100 g/m2 and a stiffness of less than about 2.5 pounds (1.14 kg) for a two layer structure of the composite, and a total areal density equal to or less than about 190 g/m2 and a stiffness of less than about 3.0 pounds (1.36 kg) for a four layer structure of the composite. The Peel Strength for a two layer structure of less than about 1.0 pounds (0.45 kg) for a two layer structure of the composite, and less than about 0.7 pounds (0.32 kg) for a four layer structure of the composite. The process of this invention permits fabrication of these desirable products in a cost-effective manner. Body armor made from the composite has improved flexibility and excellent ballistic characteristics.
摘要翻译:具有优良弹道性能,弹性好的复合材料。 令人惊奇的是,已经发现聚(α-烯烃)纤维和基质树脂的组合提供了这些所需的产品特征。 树脂基质是作为水性组合物施用的共轭二烯和乙烯基芳族单体,优选苯乙烯 - 异戊二烯 - 苯乙烯嵌段共聚物的嵌段共聚物。 纤维的强度为至少约35g / d,拉伸模量为至少约1200g / d。 复合材料的总密度等于或小于约100g / m 2,对于复合材料的两层结构,刚度小于约2.5磅(1.14kg),并且总面密度等于或小于约190 g / m 2,对于复合材料的四层结构,刚度小于约3.0磅(1.36kg)。 对于复合材料的两层结构,小于约1.0磅(0.45kg)的双层结构的剥离强度,并且对于复合材料的四层结构小于约0.7磅(0.32kg)。 本发明的方法允许以成本有效的方式制造这些所需产品。 由复合材料制成的护甲具有改善的弹性和优异的弹道特性。
摘要:
A ballistic resistant composite material useful in rigid armor applications. The composite material includes at least one consolidated network of high tenacity fibers in a thermoplastic matrix material. The resin is a thermoplastic polyurethane resin that is semi-crystalline at room temperature. The high tenacity fibers have a tenacity of at least about 7 g/d. Prior to consolidation the polyurethane resin matrix material is in an aqueous medium. When dry, the polyurethane matrix material has a tensile modulus (at 100% elongation) of at least about 500 psi (3.45 MPa), a tensile modulus (at 300% elongation) of at least about 500 psi (3.45 MPa), and an ultimate tensile strength of at least about 2000 psi (13.78 MPa). The ballistic resistant composite material has improved ballistic properties.
摘要:
A ballistic resistant composite material useful in rigid armor applications. The composite material includes at least one consolidated network of high tenacity fibers in a thermoplastic matrix material. The resin is a thermoplastic polyurethane resin that is semi-crystalline at room temperature. The high tenacity fibers have a tenacity of at least about 7 g/d. Prior to consolidation the polyurethane resin matrix material is in an aqueous medium. When dry, the polyurethane matrix material has a tensile modulus (at 100% elongation) of at least about 500 psi (3.45 MPa), a tensile modulus (at 300% elongation) of at least about 500 psi (3.45 MPa), and an ultimate tensile strength of at least about 2000 psi (13.78 MPa). The ballistic resistant composite material has improved ballistic properties.
摘要:
Flexible ballistic resistant composite material that has improved resistance to pick-up of water and other liquids, the composite material comprising a plurality of non-woven fibrous layers. The fibrous layers are formed from a network of high tenacity fibers (aramid fibers, extended chain polyethylene fibers and/or rigid rod fibers). The fibers are embedded in a matrix of a thermoplastic polyurethane resin. Preferably, at least two adjacent fiber layers are oriented in a cross-ply arrangement with respect to each other. Flexible armor, such as body vests, are provided which are formed at least in part from the flexible composite material.
摘要:
Flexible ballistic resistant composite material that has improved resistance to pick-up of water and other liquids, the composite material comprising a plurality of non-woven fibrous layers. The fibrous layers are formed from a network of high tenacity fibers (aramid fibers, extended chain polyethylene fibers and/or rigid rod fibers). The fibers are embedded in a matrix of a thermoplastic polyurethane resin. Preferably, at least two adjacent fiber layers are oriented in a cross-ply arrangement with respect to each other. Flexible armor, such as body vests, are provided which are formed at least in part from the flexible composite material.
摘要:
A multilayered composite fabric which comprises (a) a first fabric comprising non-woven unidirectionally oriented fibers in a first resin matrix, the fibers comprising high tenacity fibers, the first fabric comprising first and second surfaces; and (b) a second fabric comprising multi-directionally oriented fibers optionally in a second resin matrix, the second fabric also comprising high tenacity fibers, the second fabric having first and second surfaces, the first surface of the second fabric being bonded to the second surface of the first fabric thereby forming the composite fabric. Also described is a method of making such fabric wherein the second fabric layer is used as a support during the manufacturing process and is thereafter consolidated into a single structure with the first fabric layer.
摘要:
Ballistic resistant articles having excellent resistance to deterioration due to liquid exposure. More particularly, a ballistic resistant structures and articles formed from a hybrid of woven and non-woven fibrous components that retain their superior ballistic resistance performance after exposure to liquids such as sea water and organic solvents, such as gasoline and other petroleum-based products. The hybrid structures are particularly useful for the formation of or for use in conjunction with soft, flexible body armor.
摘要:
Multilayer ballistic resistant articles formed from a combination of flexible and semi-rigid panel components. The flexible and semi-rigid panels may include woven fibrous layers, non-woven fibrous layers or both. The articles provide suitable protection against high energy ballistic threats, while remaining suitable for flexible vest applications.
摘要:
A method of making a ballistic resistant composite material having improved resistance to high energy rifle bullets and the like. The method comprises providing at least one fibrous layer comprising a network of high tenacity aramid fibers. The fibrous layer is coated with a thermoplastic polyurethane resin. The coated fibrous layer is molded at a pressure of at least about 1,500 psi (10.3 MPa).Preferably, a plurality of fibrous layers are employed, each of which is formed from unidirectionally oriented aramid fibers in a thermoplastic polyurethane resin matrix. Adjacent fibrous layers are preferably oriented at 90° with respect to each other.
摘要:
Ballistic resistant fabrics and articles that retain superior ballistic resistance performance after exposure to liquids such as sea water and organic solvents, such as gasoline and other petroleum-based products. The fabrics are formed from high performance fibers coated with a nitrile rubber binder polymer having an acrylonitrile content of from about 15 wt. % to about 50 wt. %, and are optionally coated with a binder that is a blend of a nitrile rubber and a fluorine-containing material.