Catalyst for living radical polymerization and polymerization method
    2.
    发明授权
    Catalyst for living radical polymerization and polymerization method 有权
    催化剂用于活性自由基聚合和聚合方法

    公开(公告)号:US09018325B2

    公开(公告)日:2015-04-28

    申请号:US14240607

    申请日:2012-08-24

    摘要: A nonmetallic compound having an ionic bond with a halide ion is used as a catalyst for living radical polymerization. Even if a radical initiator is not used, a monomer can be subjected to a radical polymerization to obtain a polymer having narrow molecular weight distribution. The cost of the living radical polymerization can be remarkably reduced, and it is made possible to prevent adverse effects of using a radical initiator (such as side reactions). The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages such as low toxicity of the catalyst, low amount of the catalyst necessary, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor, etc. The catalyst can be applied to various monomers and enables synthesis of high molecular weight polymers.

    摘要翻译: 使用与卤离子具有离子键的非金属化合物作为活性自由基聚合的催化剂。 即使不使用自由基引发剂,也可以对单体进行自由基聚合,得到分子量分布窄的聚合物。 活性自由基聚合的成本可以显着降低,并且可以防止使用自由基引发剂(例如副反应)的不利影响。 本发明由于催化剂毒性低,催化剂用量少,催化剂溶解性高,反应条件温和,无着色/无色性等优点,比现有的活性自由基聚合方法显着更环保,经济, 没有气味等。催化剂可以应用于各种单体,并能够合成高分子量聚合物。

    CATALYST FOR LIVING RADICAL POLYMERIZATION AND POLYMERIZATION METHOD
    4.
    发明申请
    CATALYST FOR LIVING RADICAL POLYMERIZATION AND POLYMERIZATION METHOD 有权
    用于生物聚合和聚合方法的催化剂

    公开(公告)号:US20140303334A1

    公开(公告)日:2014-10-09

    申请号:US14240607

    申请日:2012-08-24

    IPC分类号: C08F4/00

    摘要: A nonmetallic compound having an ionic bond with a halide ion is used as a catalyst for living radical polymerization. Even if a radical initiator is not used, a monomer can be subjected to a radical polymerization to obtain a polymer having narrow molecular weight distribution. The cost of the living radical polymerization can be remarkably reduced, and it is made possible to prevent adverse effects of using a radical initiator (such as side reactions). The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages such as low toxicity of the catalyst, low amount of the catalyst necessary, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor, etc. The catalyst can be applied to various monomers and enables synthesis of high molecular weight polymers.

    摘要翻译: 使用与卤离子具有离子键的非金属化合物作为活性自由基聚合的催化剂。 即使不使用自由基引发剂,也可以对单体进行自由基聚合,得到分子量分布窄的聚合物。 活性自由基聚合的成本可以显着降低,并且可以防止使用自由基引发剂(例如副反应)的不利影响。 本发明由于催化剂毒性低,催化剂用量低,催化剂溶解性高,反应条件温和,无着色/无色性等优点,比现有的活性自由基聚合方法显着提高环保性和经济性, 没有气味等。催化剂可以应用于各种单体,并能够合成高分子量聚合物。

    CATALYST FOR LIVING RADICAL POLYMERIZATION
    5.
    发明申请
    CATALYST FOR LIVING RADICAL POLYMERIZATION 有权
    催化剂用于生物辐射聚合

    公开(公告)号:US20110275775A1

    公开(公告)日:2011-11-10

    申请号:US13062688

    申请日:2009-09-08

    摘要: Provided is a catalyst used for a living radical polymerization method, which contains a central element consisting of carbon and at least one halogen atom binding to the central element. Further, a hydrocarbon compound can be used as a catalyst precursor. A monomer having a radical-reactive unsaturated bond is subjected to a radical polymerization reaction in the presence of the catalyst, consequently a polymer having narrow molecular weight distribution can be obtained, and thus the cost of the living radical polymerization can be remarkably reduced. The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages such as low toxicity of the catalyst, low amount of the catalyst used, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor (no need of any post-treatments for a molded article), and the like.

    摘要翻译: 提供了用于活性自由基聚合法的催化剂,其包含由碳和与中心元素结合的至少一个卤素原子组成的中心元素。 此外,可以使用烃化合物作为催化剂前体。 具有自由基反应性不饱和键的单体在催化剂的存在下进行自由基聚合反应,因此可以获得具有窄分子量分布的聚合物,从而可显着降低活性自由基聚合的成本。 本发明由于催化剂的毒性低,催化剂用量少,催化剂溶解性高,反应条件温和,无着色/无色性等优点,比现有的活性自由基聚合法更具环保性和经济性, 无异味(不需要对成形品进行后处理)等。

    AQUEOUS PIGMENT DISPERSION AND APPLICATIONS THEREOF
    6.
    发明申请
    AQUEOUS PIGMENT DISPERSION AND APPLICATIONS THEREOF 审中-公开
    水性颜料分散体及其应用

    公开(公告)号:US20110223529A1

    公开(公告)日:2011-09-15

    申请号:US12737568

    申请日:2009-07-24

    摘要: Disclosed are an aqueous pigment dispersion containing at least a pigment, water, a high-molecular dispersant, and an alkali. The high-molecular dispersant is a diblock polymer having a formula (1) of A-B or a triblock polymer having a formula (2) of A-B-C. The diblock or triblock polymer is a diblock or triblock polymer obtained by polymerizing addition-polymerizable monomers with a radical generator while using an organic iodide as a polymerization initiating compound and an organic phosphorus compound, organic nitrogen compound or organic oxygen compound as a catalyst. Also disclosed are a production method and use of the aqueous pigment dispersion. With the high-molecular dispersant obtained by a simple living radical polymerization process free of the problems of conventional living radical polymerization and having a precisely-controlled molecular structure, the aqueous pigment dispersion can be obtained with the pigment dispersed in it.

    摘要翻译: 公开了至少含有颜料,水,高分子分散剂和碱的水性颜料分散体。 高分子分散剂是具有式(1)的A-B的二嵌段聚合物或具有式(2)的A-B-C的三嵌段聚合物。 二嵌段或三嵌段聚合物是通过使用有机碘化物作为聚合引发化合物和有机磷化合物,有机氮化合物或有机氧化合物作为催化剂,通过使自由基发生剂聚合加成聚合的单体获得的二嵌段或三嵌段聚合物。 还公开了水性颜料分散体的制造方法和用途。 利用通过简单的活性自由基聚合方法获得的高分子分散体,其不存在常规活性自由基聚合和精确控制分子结构的问题,可以通过分散在其中的颜料来获得水性颜料分散体。

    FLOW RATE CONTROL VALVE AND SPOOL POSITION DETECTION DEVICE FOR THE FLOW RATE CONTROL VALVE
    7.
    发明申请
    FLOW RATE CONTROL VALVE AND SPOOL POSITION DETECTION DEVICE FOR THE FLOW RATE CONTROL VALVE 有权
    流速控制阀和流量控制阀的阀位置检测装置

    公开(公告)号:US20100200785A1

    公开(公告)日:2010-08-12

    申请号:US12671396

    申请日:2008-07-31

    申请人: Atsushi Goto

    发明人: Atsushi Goto

    IPC分类号: F16K31/08 G01B7/14

    摘要: Flow rate control valve includes: a target probe formed of a magnetically-responsive substance and mounted to one end of a spool; a sensor housing mounted to the one end of the sleeve and having a cylinder section defining an inner space to permit entry therein of the target probe; and first and second coils provided around the cylinder section and axially spaced from each other by a predetermined distance. The probe is constructed so that magnetic response of the coils gradually varies in one direction in response to a linear position of the target probe. The first coil responds to the target probe, while the second coil dose not respond to the target probe. Impedance of the first coil varies with a linear position of the probe (31), and the linear position of the probe is detected through differential synthesis performed between outputs of the first and second coils.

    摘要翻译: 流量控制阀包括:由磁响应物质形成并安装在阀芯一端的目标探头; 传感器壳体,其安装到所述套筒的一端并且具有限定内部空间以允许所述目标探针进入的气缸部分; 以及围绕所述气缸部分设置并且彼此轴向间隔预定距离的第一和第二线圈。 探针被构造成使得线圈的磁响应响应于目标探针的线性位置在一个方向上逐渐变化。 第一个线圈响应目标探针,而第二个线圈不响应目标探针。 第一线圈的阻抗随着探针(31)的线性位置而变化,并且通过在第一和第二线圈的输出之间执行的差分合成来检测探针的线性位置。

    Packing method, packing member and manufacturing method therefor
    8.
    发明授权
    Packing method, packing member and manufacturing method therefor 失效
    包装方法,包装件及其制造方法

    公开(公告)号:US07681379B2

    公开(公告)日:2010-03-23

    申请号:US11411068

    申请日:2006-04-26

    IPC分类号: B65B3/04

    摘要: A packing member for packing an article, includes a medium accommodating portion for accommodating medium; a non-return valve for passing the medium to the medium accommodating portion and stopping the medium away from the medium accommodating portion; an introducing portion for introducing the medium into the medium accommodating portion with the non-return valve from an outside of the packing member to balloon the medium accommodating portion; and a sealing region, disposed upstream of the non-return valve with respect to a direction of the introduction of the medium from the introducing portion toward the non-return valve, for sealing against the introduction of the medium to prevent leakage from the introducing portion to an outside of the packing member, the sealing region being sealed to keep the medium in the medium accommodating portion.

    摘要翻译: 一种用于包装物品的包装件,包括用于容纳介质的介质容纳部分; 用于将介质传送到介质容纳部分并使介质停止于介质容纳部分的止回阀; 引导部分,用于将介质从打包构件的外部引导到具有止回阀的介质容纳部分中以使介质容纳部分气球; 以及密封区域,其设置在所述止回阀的上游侧,所述密封区域相对于介质从所述引入部朝向所述止回阀的方向引入,用于密封所述介质的引入,以防止从所述引入部分泄漏 到密封部件的外部,密封区域被密封以将介质保持在介质容纳部分中。

    Packing method, packing member and manufacturing method therefor

    公开(公告)号:US20060191817A1

    公开(公告)日:2006-08-31

    申请号:US11411069

    申请日:2006-04-26

    IPC分类号: B65D81/02

    摘要: A packing member for packing an article, includes a medium accommodating portion for accommodating medium; a non-return valve for passing the medium to the medium accommodating portion and stopping the medium away from the medium accommodating portion; an introducing portion for introducing the medium into the medium accommodating portion with the non-return valve from an outside of the packing member to balloon the medium accommodating portion; and a sealing region, disposed upstream of the non-return valve with respect to a direction of the introduction of the medium from the introducing portion toward the non-return valve, for sealing against the introduction of the medium to prevent leakage from the introducing portion to an outside of the packing member, the sealing region being sealed to keep the medium in the medium accommodating portion.