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    Method For Hair Treatment With Shape Memory Polymers
    3.
    发明申请
    Method For Hair Treatment With Shape Memory Polymers 审中-公开
    用形状记忆聚合物治疗头发的方法

    公开(公告)号：US20070275020A1

    公开(公告)日：2007-11-29

    申请号：US10566232

    申请日：2004-07-14

    申请人： Andreas Lendlein ,  Axel Kalbfleisch ,  Anja Duchscherer ,  Angelika Beyer ,  Susanne Graner ,  Tareq Ali Abdulla Hasson ,  Thomas Krause ,  Karl Kratz ,  Hong-Yan Jiang ,  Simone Moersheim ,  Yasmin Ghazlan

    发明人： Andreas Lendlein ,  Axel Kalbfleisch ,  Anja Duchscherer ,  Angelika Beyer ,  Susanne Graner ,  Tareq Ali Abdulla Hasson ,  Thomas Krause ,  Karl Kratz ,  Hong-Yan Jiang ,  Simone Moersheim ,  Yasmin Ghazlan

    IPC分类号： A61K8/85

    CPC分类号： A61Q5/06 ,  A61K8/90 ,  A61K2800/54 ,  C08G63/06 ,  C08G63/664 ,  C08G2261/126

    摘要： A method for producing a retrievable hairstyling using shape memory polymers is described. Here a composition is applied to the hair, said composition containing a shape memory polymer P or a macromer M that can be cross-linked to a shape memory polymer, the hair is arranged into a given (permanent) shape and said permanent shape is then fixed by means of chemical cross-linking of the macromer M under the formation of a shape memory polymer and/or under physical cross-linking of the polymer P. The polymer P and the macromer M are formed from block copolymers, each of which comprises at least a first block and at least two additional blocks. The first block is a polyol and is selected from polyethers, dimerdiol and derivatives derived therefrom, as well as from polyesters of dicarboxylic acids with diols. The additional blocks are polyesters of hydroxycarboxylic acids or their lactones. The macromer M possesses cross-linkable regions, as well as thermoplastic regions that are not cross-linkable and, after cross-linking, has a transition temperature of Ttrans. The polymer P has a hard segment with a first transition temperature T′trans, which is above room temperature, and a soft segment with a second transition temperature Ttrans which is lower than T′trans.

    摘要翻译： 描述了使用形状记忆聚合物生产可回收发型的方法。 这里将组合物施加到头发上，所述组合物含有可以与形状记忆聚合物交联的形状记忆聚合物P或大分子单体M，将毛发排列成给定（永久）形状，然后所述永久形状 在形成记忆聚合物的形成和/或在物理交联聚合物P的情况下通过大分子单体M的化学交联固定。聚合物P和大分子单体M由嵌段共聚物形成，每个嵌段共聚物包含 至少第一块和至少两个附加块。 第一个嵌段是多元醇，选自聚醚，二聚二醇及其衍生物，以及二羧酸与二醇的聚酯。 附加的嵌段是羟基羧酸或其内酯的聚酯。 大分子单体M具有可交联的区域以及不可交联的热塑性区域，并且在交联之后具有T T的转变温度。 聚合物P具有高于室温的第一转变温度T'>反式的硬链​​段和低于第二转变温度T lt反式的软链段 比T'。

    Method for Producing Shape Memory Effects in Hair in Connection with Hydrophobic Active Ingredients
    4.
    发明申请
    Method for Producing Shape Memory Effects in Hair in Connection with Hydrophobic Active Ingredients 审中-公开
    在与疏水性活性成分相关的头发中产生形状记忆效应的方法

    公开(公告)号：US20080311050A1

    公开(公告)日：2008-12-18

    申请号：US10566230

    申请日：2004-07-14

    申请人： Andreas Lendlein ,  Tareq Ali Abdulla Hasson ,  Karl Kratz ,  Leonid Kuper ,  Thomas Krause ,  Axel Kalbfleisch ,  Anja Duchscherer ,  Angelika Beyer

    发明人： Andreas Lendlein ,  Tareq Ali Abdulla Hasson ,  Karl Kratz ,  Leonid Kuper ,  Thomas Krause ,  Axel Kalbfleisch ,  Anja Duchscherer ,  Angelika Beyer

    IPC分类号： A61K8/06 ,  A61K9/107 ,  A61Q5/04

    CPC分类号： A61K8/891 ,  A61K8/8152 ,  A61K8/86 ,  A61K8/87 ,  A61K8/892 ,  A61K2800/54 ,  A61Q5/06

    摘要： A method for achieving a retrievable hair restyling is described. Here a composition is applied to the hair, said composition containing at least one first active ingredient or active ingredient complex which can provide a shape memory effect by itself or in combination with other substances after being applied to the hair and after the performance of the treatment of the hair according to the invention. The composition additionally contains at least one second active ingredient, namely a hydrophobic substance with a water solubility of ≦5 percent by weight at 20° C. The hair is arranged into a given (permanent) shape and said permanent shape is then fixed by inducing a chemical or physical modification of the applied active ingredients, wherein after a wanted or unwanted deformation of the shape memory, the original shape memory can be restored by means of a physical stimulation. In addition to the permanent hairstyle, a second (temporary) shape can be impressed. A method is also described for restoring a previously programmed permanent hairstyle that was temporarily transformed into a temporary shape or that was otherwise deformed.

    摘要翻译： 描述了一种用于实现可回收毛发修复的方法。 这里将组合物施用于毛发，所述组合物含有至少一种第一活性成分或活性成分复合物，其可以在施用于毛发后自身或与其它物质组合提供形状记忆效应，并且在进行处理之后 的根据本发明的头发。 该组合物另外含有至少一种第二活性成分，即在20℃下水溶性为<= 5重量％的疏水性物质。毛发排列成给定（永久）形状，然后将所述永久形状固定在 诱导所施加的活性成分的化学或物理改性，其中在形状记忆体的想要或不期望的变形之后，可以通过物理刺激来恢复原始形状记忆。 除了永久发型之外，还可以留下第二（暂时）形状。 还描述了一种用于恢复临时转变成临时形状或以其他方式变形的先前编程的永久性发型的方法。

    Method of treating hair with form memory polymers
    5.
    发明申请
    Method of treating hair with form memory polymers 审中-公开
    用形态记忆聚合物处理毛发的方法

    公开(公告)号：US20060088494A1

    公开(公告)日：2006-04-27

    申请号：US10510873

    申请日：2003-04-10

    申请人： Andreas Lendlein ,  Werner Grasser ,  Karl Kratz ,  Thomas Krause ,  Axel Kalbfleisch ,  Gunther Lang ,  Jurgen Allwohn ,  Johannes Burghaus ,  Gerhard Sendelbach ,  Detlef Mattinger ,  Stefan Uhl

    发明人： Andreas Lendlein ,  Werner Grasser ,  Karl Kratz ,  Thomas Krause ,  Axel Kalbfleisch ,  Gunther Lang ,  Jurgen Allwohn ,  Johannes Burghaus ,  Gerhard Sendelbach ,  Detlef Mattinger ,  Stefan Uhl

    IPC分类号： A61K8/81

    CPC分类号： A61K8/86 ,  A61K8/046 ,  A61K8/416 ,  A61K8/8152 ,  A61K8/8182 ,  A61K8/88 ,  A61K2800/594 ,  A61Q5/06

    摘要： A method for the provision of a recallable hair transformation using shape-memory polymers is disclosed. In this respect a composition which comprises a macromer or prepolymer which is cross-linkable to a shape-memory polymer is applied onto the hair and the hair is brought into a defined (permanent) shape and subsequently the permanent shape is fixed by means of the chemical cross-linking of the macromer or prepolymer under formation of the shape-memory polymer. The macromer or prepolymer contains segments which are cross-linkable by means of chemical bonds as well as thermoplastic segments which are not chemically cross-linkable. The shape-memory polymers do possess at least one transition temperature TTrans. In addition to the permanent shape of a hairdo a second (temporary) shape can be impressed. Furthermore, disclosed is a method for the recovery of a previously programmed, permanent shape of a hairdo, which has been temporarily brought into a temporary form or which has been deformed in a different manner.

    摘要翻译： 公开了使用形状记忆聚合物提供可召回的毛发转化的方法。 在这方面，将包含可与形状记忆聚合物交联的大分子单体或预聚物的组合物施加到头发上，并将头发置于限定（永久）形状中，随后将永久形状通过 形成记忆聚合物形成的大分子单体或预聚物的化学交联。 大分子单体或预聚物含有通过化学键可交联的区段以及不可化学交联的热塑性区段。 形状记忆聚合物确实具有至少一个转变温度T Trans。 除了发型的永久形状之外，可以印象第二（暂时）形状。 此外，公开了一种用于回收已经暂时形成或以不同方式变形的发型的先前编程的永久形状的方法。

    Hair wax product with reduced density
    7.
    发明授权
    Hair wax product with reduced density 失效
    发蜡产品密度降低

    公开(公告)号：US07037488B2

    公开(公告)日：2006-05-02

    申请号：US10170091

    申请日：2002-06-12

    申请人： Thomas Krause ,  Bernd Stein ,  Axel Kalbfleisch ,  Werner Brocks ,  Michael Franzke ,  Thomas Schulz

    发明人： Thomas Krause ,  Bernd Stein ,  Axel Kalbfleisch ,  Werner Brocks ,  Michael Franzke ,  Thomas Schulz

    IPC分类号： A61K7/11 ,  A61K7/09

    CPC分类号： A61K8/046 ,  A61K8/31 ,  A61K8/86 ,  A61K8/92 ,  A61K8/922 ,  A61Q5/06

    摘要： A hair wax product is made by a process, in which a solid wax composition is heated to melt or soften it and then foamed with a gas in a mixer that applies shear energy to it. The gas is preferably air or a non-reactive gas, such as nitrogen. The gas is introduced to the liquified or softened solid wax composition in a sufficient amount so that the density of the resulting hair wax product is less than or equal to 0.9 g/ml, preferably 0.6 to 0.8 g/ml. The hair wax product contains bubbles and/or pores having a size of from 0.0001 to 5 mm and has melting and softening properties such that rubbing it by hand is sufficient to remove a waxy portion from it and work the waxy portion into hair.

    摘要翻译： 通过一种方法制造发蜡产品，其中将固体蜡组合物加热熔化或软化，然后在混合器中用气体发泡，该混合器对其施加剪切能。 气体优选为空气或非反应性气体，例如氮气。 将气体以足够的量引入到液化或软化的固体蜡组合物中，使得所得发蜡产品的密度小于或等于0.9g / ml，优选为0.6至0.8g / ml。 毛发产品含有尺寸为0.0001至5mm的气泡和/或孔，具有熔融和软化性能，使得用手摩擦足以从其中除去蜡状部分并将蜡状部分加工成头发。

    Hair wax product with reduced density
    8.
    发明授权
    Hair wax product with reduced density 失效
    发蜡产品密度降低

    公开(公告)号：US07108849B2

    公开(公告)日：2006-09-19

    申请号：US11028365

    申请日：2005-01-03

    申请人： Thomas Krause ,  Bernd Stein ,  Axel Kalbfleisch ,  Werner Brocks ,  Michael Franzke ,  Thomas Schulz

    发明人： Thomas Krause ,  Bernd Stein ,  Axel Kalbfleisch ,  Werner Brocks ,  Michael Franzke ,  Thomas Schulz

    IPC分类号： A61Q5/06

    CPC分类号： A61K8/046 ,  A61K8/31 ,  A61K8/86 ,  A61K8/92 ,  A61K8/922 ,  A61Q5/06

    摘要： The wax composition for styling human hair provides hold, strength and rigidity, includes at least one wax and/or waxy material, and has a density of less than or equal to 0.9 g/ml, after being foamed in a fluid or softened state with a gas, preferably air or a non-reactive gas, such as nitrogen, so that it includes a bubble and/or pore structure. In the method for styling human hair this wax composition is applied to the hair and the hair is shaped with the wax composition applied to it.

    摘要翻译： 用于造型人类头发的蜡组合物在流体或软化状态下发泡之后提供保持，强度和刚度，包括至少一种蜡和/或蜡质材料，并且具有小于或等于0.9g / ml的密度， 气体，优选空气或非反应性气体，例如氮气，使得其包括气泡和/或孔结构。 在用于造型人发的方法中，将该蜡组合物施用于头发，并且用施用于其上的蜡组合物将头发成型。

    Hair wax product with reduced density
    9.
    发明申请
    Hair wax product with reduced density 失效
    发蜡产品密度降低

    公开(公告)号：US20050118127A1

    公开(公告)日：2005-06-02

    申请号：US11028365

    申请日：2005-01-03

    申请人： Thomas Krause ,  Bernd Stein ,  Axel Kalbfleisch ,  Werner Brocks ,  Michael Franzke ,  Thomas Schulz

    发明人： Thomas Krause ,  Bernd Stein ,  Axel Kalbfleisch ,  Werner Brocks ,  Michael Franzke ,  Thomas Schulz

    IPC分类号： C08L91/06 ,  A61K7/06

    CPC分类号： A61K8/046 ,  A61K8/31 ,  A61K8/86 ,  A61K8/92 ,  A61K8/922 ,  A61Q5/06

    摘要： The wax composition for styling human hair provides hold, strength and rigidity, includes at least one wax and/or waxy material, and has a density of less than or equal to 0.9 g/ml, after being foamed in a fluid or softened state with a gas, preferably air or a non-reactive gas, such as nitrogen, so that it includes a bubble and/or pore structure. In the method for styling human hair this wax composition is applied to the hair and the hair is shaped with the wax composition applied to it.

    摘要翻译： 用于造型人类头发的蜡组合物在流体或软化状态下发泡之后提供保持，强度和刚度，包括至少一种蜡和/或蜡质材料，并且具有小于或等于0.9g / ml的密度， 气体，优选空气或非反应性气体，例如氮气，使得其包括气泡和/或孔结构。 在用于造型人发的方法中，将该蜡组合物施用于头发，并且用施用于其上的蜡组合物将头发成型。

    Hair treatment compositions containing itaconic acid mono-ester/acrylate copolymer and polystyrene sulfonate
    10.
    发明申请
    Hair treatment compositions containing itaconic acid mono-ester/acrylate copolymer and polystyrene sulfonate 审中-公开
    包含衣康酸单酯/丙烯酸酯共聚物和聚苯乙烯磺酸盐的头发处理组合物

    公开(公告)号：US20050232886A1

    公开(公告)日：2005-10-20

    申请号：US11103252

    申请日：2005-04-11

    申请人： Andrea Walter ,  Susanne Birkel ,  Manuela Hannich ,  Axel Kalbfleisch

    发明人： Andrea Walter ,  Susanne Birkel ,  Manuela Hannich ,  Axel Kalbfleisch

    IPC分类号： A61K8/00 ,  A61K8/25 ,  A61K8/37 ,  A61K8/81 ,  A61K8/899 ,  A61Q5/06 ,  A61Q5/10 ,  A61K7/06 ,  A61K7/11

    CPC分类号： A61K8/8164 ,  A61K8/8117 ,  A61Q5/06 ,  A61Q5/065

    摘要： The hair treatment composition contains a combination of at least one itaconic acid monoester/acrylate copolymer and at least one polystyrene sulfonate with a molecular weight in a range from 50,000 to 200,000. The itaconic acid monoester monomer or monomers are of formula CH2═C(COOR1)CH2COOR2, wherein one of R1 and R2 represents hydrogen and another of R1 and R2 represents —(CH2CH2O)x—R3, x is a number between 1 and 100 and R3 is an alkyl group with 8 to 30 carbon atoms. In an especially preferred embodiment the hair treatment composition contains an itaconic acid monocetyl ester/acrylate copolymer and an itaconic acid monostearyl ester/acrylate copolymer.

    摘要翻译： 毛发处理组合物含有至少一种衣康酸单酯/丙烯酸酯共聚物和至少一种分子量为50,000至200,000的聚苯乙烯磺酸酯的组合。 衣康酸单酯单体或单体具有式CH 2 - （C 1 -C 12）CH 2 CO 2， 其中R 1和R 2之一表示氢，R 1和R 2中的另一个表示 - （ CH 2，CH 2，O 2，X 3 -R 3，x是1至100之间的数，R 1， SUP> 3是具有8至30个碳原子的烷基。 在特别优选的实施方案中，毛发处理组合物含有衣康酸单酯酯/丙烯酸酯共聚物和衣康酸单硬脂酯/丙烯酸酯共聚物。