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公开(公告)号:US10279516B2
公开(公告)日:2019-05-07
申请号:US14897746
申请日:2014-06-11
申请人: BASF SE
IPC分类号: B29C44/34 , B29B9/06 , C08J9/16 , B29B9/12 , B29C44/04 , C08J9/00 , C08J9/12 , C08J9/34 , B29B7/88 , B29B7/90 , B29B9/14 , B29C47/00 , B29C47/86 , B29K21/00 , B29K77/00 , B29K105/00 , B29K105/16
摘要: A process for producing expanded pellets from a thermoplastic elastomer having an elongation at break of more than 100% measured to DIN EN ISO 527-2, comprising: (a) pressing a polymer melt comprising a blowing agent through a perforated disk (18) controlled to a temperature between 150° C. and 280° C. and into a pelletizing chamber (26), (b) using a cutting device (20) to comminute the polymer melt pressed through the perforated disk (18) into individual expanding pellets, (c) discharging the pellets from the pelletizing chamber (26) using a liquid stream (36), wherein the blowing agent comprises CO2 and/or N2 and the amount of blowing agent in the polymer melt is from 0.5 to 2.5 wt %, the pelletizing chamber (26) is traversed by a stream of liquid at a temperature between 5° C. and 90° C. and the pressure of 0.1 bar to 20 bar above ambient pressure such that the pellets are expanded in the pressurized liquid by the blowing agent, producing expanded pellets having an uninterrupted skin.
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公开(公告)号:US20150174808A1
公开(公告)日:2015-06-25
申请号:US14391870
申请日:2013-04-12
申请人: BASF SE
发明人: Hans Rudolph , Rainer Klostermann , Torben Kaminsky , Bernd Lohaus , Jürgen Ahlers , Bernhard Schmied , Peter Gutmann , Klaus Hahn , Frank Prissok , Elke Marten , Christian Däschlein
IPC分类号: B29C47/00
CPC分类号: B29C47/0011 , B29B9/065 , B29B9/12 , B29B9/14 , B29B9/16 , B29C44/3461 , B29K2075/00 , B29L2031/00 , C08G18/0895 , C08G18/6674 , C08G18/7671 , C08J9/122 , C08J9/141 , C08J9/16 , C08J9/34 , C08J2201/03 , C08J2203/06 , C08J2203/14 , C08J2203/182 , C08J2300/22 , C08J2367/00 , C08J2375/04 , C08J2377/00
摘要: The invention relates to a process for production of expanded pellets from a polymer melt comprising a blowing agent, said process comprising the steps of: a) pressing the polymer melt comprising a blowing agent through a perforated disk controlled to a temperature between 150° C. and 280° C. and into a pelletizing chamber, b) using a cutting device to comminute the polymer melt pressed through the temperature-controlled perforated disk into individual expanding pellets, c) discharging the pellets from the pelletizing chamber using a liquid stream, wherein the blowing agent comprises CO2 or N2 or a combination of CO2 and N2 and the pelletizing chamber is traversed by a stream of liquid which is controlled to a temperature between 10° C. and 60° C. and the pressure of which is from 0.7 bar to 20 bar above ambient pressure, the pressure and temperature for the liquid in the pelletizing chamber and also the temperature for the perforated disk being chosen such that the pellets are expanded in the pressurized liquid by the blowing agent they contain so as to produce expanded pellets having an uninterrupted skin.
摘要翻译: 本发明涉及一种由包含发泡剂的聚合物熔体制备发泡颗粒的方法,所述方法包括以下步骤:a)将包含发泡剂的聚合物熔体通过控制在150℃之间的多孔板压制 和280℃,并且进入造粒室,b)使用切割装置将通过温度控制的多孔盘压制的聚合物熔体粉碎成单独的膨胀颗粒,c)使用液体流将颗粒从造粒室排出,其中 发泡剂包括CO 2或N 2或CO 2和N 2的组合,并且造粒室通过液体流穿过,该液流被控制在10℃和60℃之间的温度,其压力为0.7巴 在环境压力以上20巴以下,选择造粒室中的液体的压力和温度以及多孔盘的温度,使得颗粒为exp 通过它们包含的发泡剂将其加压在加压液体中以产生具有不间断皮肤的发泡颗粒。
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公开(公告)号:US11142625B2
公开(公告)日:2021-10-12
申请号:US15029686
申请日:2014-10-17
申请人: BASF SE
发明人: Peter Gutmann , Christian Däschlein , Jürgen Ahlers , Elke Marten , Torben Kaminsky , Dirk Kempfert
IPC分类号: C08J9/34 , C08J9/12 , C08J9/14 , B29C44/34 , C08J9/00 , C08J9/16 , B29B7/88 , B29B9/12 , C08G18/66 , C08G18/76 , B29B9/06
摘要: The invention relates to a process for production of expanded thermoplastic elastomer, said process comprising the steps of: (e) adding monomers and/or oligomers used for producing the thermoplastic elastomer with or without further starting materials into a first stage of a polymer-processing machine, (f) mixing the monomers and/or oligomers and also the optionally added further starting materials and reacting the monomers and/or oligomers to give a polymer melt in the first stage of the polymer-processing machine, (g) passing the polymer melt into a second stage of a polymer-processing machine and adding a physical blowing agent with or without further starting materials to obtain a polymer melt comprising a blowing agent, (h) molding the polymer melt comprising a blowing agent into an expanded thermoplastic elastomer.
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公开(公告)号:US10392488B2
公开(公告)日:2019-08-27
申请号:US15028259
申请日:2014-10-09
申请人: BASF SE
IPC分类号: C08J9/16 , B29C44/00 , C08J9/18 , B29C44/34 , C08J9/12 , C08J9/232 , C08J9/236 , B29C44/08 , B29K9/06 , B29K19/00 , B29K67/00 , B29K75/00 , B29K77/00 , B29K96/04 , B29K105/00 , B29K105/04
摘要: A process for production of expanded thermoplastic elastomer beads in the presence of a gaseous medium that surrounds thermoplastic elastomer beads. The process comprises a) an impregnating step, in which the gaseous medium has an impregnating temperature Ta, and the absolute pressure of the gaseous medium is greater than ambient pressure, the thermoplastic elastomer beads impregnated with a blowing agent, b) an expanding step, in which the thermoplastic elastomer beads expand as they are exposed to a pressure reduction at a first expanding temperature Tb, and c) optionally a fusing step, in which the expanded thermoplastic elastomer beads are fused together at a fusing temperature Tc to form at least one shaped part.
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公开(公告)号:US10005218B2
公开(公告)日:2018-06-26
申请号:US14391870
申请日:2013-04-12
申请人: BASF SE
发明人: Hans Rudolph , Rainer Klostermann , Torben Kaminsky , Bernd Lohaus , Jürgen Ahlers , Bernhard Schmied , Peter Gutmann , Klaus Hahn , Frank Prissok , Elke Marten , Christian Däschlein
IPC分类号: B29C47/00 , B29B9/06 , C08G18/66 , C08G18/76 , C08J9/12 , C08G18/08 , B29C44/34 , B29B9/12 , B29B9/14 , B29B9/16 , C08J9/14 , C08J9/16 , C08J9/34 , B29K75/00 , B29L31/00
摘要: The invention relates to a process for production of expanded pellets from a polymer melt comprising a blowing agent, said process comprising the steps of: a) pressing the polymer melt comprising a blowing agent through a perforated disk controlled to a temperature between 150° C. and 280° C. and into a pelletizing chamber, b) using a cutting device to comminute the polymer melt pressed through the temperature-controlled perforated disk into individual expanding pellets, c) discharging the pellets from the pelletizing chamber using a liquid stream, wherein the blowing agent comprises CO2 or N2 or a combination of CO2 and N2 and the pelletizing chamber is traversed by a stream of liquid which is controlled to a temperature between 10° C. and 60° C. and the pressure of which is from 0.7 bar to 20 bar above ambient pressure, the pressure and temperature for the liquid in the pelletizing chamber and also the temperature for the perforated disk being chosen such that the pellets are expanded in the pressurized liquid by the blowing agent they contain so as to produce expanded pellets having an uninterrupted skin.
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