公开(公告)号：US10682631B2

公开(公告)日：2020-06-16

申请号：US16250244

申请日：2019-01-17

Applicant: BASF SE

Inventor： Kazuhiko Amakawa ,  Christian Walsdorff ,  Klaus Joachim Mueller-Engel ,  Cornelia Katharina Dobner ,  Ulrich Hammon

IPC: B01J23/00 ,  B01J35/00 ,  B01J37/00 ,  C07C45/35 ,  B01J23/887 ,  C07C51/215 ,  B01J35/10 ,  B01J23/888 ,  B01J37/08 ,  B01J37/02 ,  C01G39/00 ,  B01J35/02 ,  B01J37/04 ,  C01B33/32

Abstract: Multimetal oxide composition comprising Mo, Bi, Fe, Cu and one or more than one of the elements Co and Ni and use thereof.

公开(公告)号：US09695099B2

公开(公告)日：2017-07-04

申请号：US14956800

申请日：2015-12-02

Applicant: BASF SE

Inventor： Yong Liu ,  Martin Dieterle ,  Nicolai Tonio Woerz ,  Andrei-Nicolae Parvulescu ,  Michael Lejkowski ,  Johannes Lieberknecht ,  Christian Walsdorff ,  Kazuhiko Amakawa

IPC: C07C51/353 ,  B01J27/198 ,  B01J37/08 ,  B01J37/02 ,  B01J23/00 ,  B01J27/199 ,  B01J35/02 ,  B01J37/00 ,  B01J29/70 ,  B01J38/02

CPC classification number: C07C51/353 ,  B01J23/002 ,  B01J27/198 ,  B01J27/199 ,  B01J29/7057 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0213 ,  B01J37/08 ,  B01J38/02 ,  B01J2523/00 ,  Y02P20/584 ,  C07C57/04 ,  B01J2523/41 ,  B01J2523/51 ,  B01J2523/54 ,  B01J2523/55 ,  B01J2523/69

Abstract: The present invention relates to a process for preparing acrylic acid from acetic acid and formaldehyde, which comprises (a) provision of a stream S1 comprising acetic acid and formaldehyde, where the molar ratio of acetic acid to formaldehyde in the stream S1 is in the range from 0.5:1 to 2:1; (b) contacting of the stream S1 with an aldol condensation catalyst comprising vanadium, phosphorus and oxygen to give a stream S2 comprising acrylic acid, where, in (b), the space velocity WHSV is in the range from 0.35 to 7.0 kg/kg/h.

公开(公告)号：US09540305B2

公开(公告)日：2017-01-10

申请号：US14724244

申请日：2015-05-28

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Armin Lange De Oliveira ,  Stephan A. Schunk ,  Nicolai Tonio Woerz ,  Marco Hartmann ,  Kazuhiko Amakawa ,  Michael Goebel ,  Yong Liu ,  Michael Lejkowski

IPC: C07C51/347 ,  C07C51/353 ,  B01J29/82 ,  B01J29/84 ,  B01J29/83 ,  B01J29/85

CPC classification number: C07C51/347 ,  B01J29/82 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  C07C51/353 ,  C07C2529/82 ,  C07C2529/83 ,  C07C2529/84 ,  C07C2529/85 ,  C07C57/04

Abstract: A process for preparing acrylic acid, comprising (i) providing a stream S4 comprising a formaldehyde source and acetic acid; (ii) contacting stream S4 with an aldol condensation catalyst comprising a zeolitic material comprising aluminum in the framework structure to obtain a stream S6 comprising acrylic acid, the framework structure of the zeolitic material in (ii) comprising YO2 and Al2O3, and Y being a tetravalent element; where the total content of alkali metal and alkaline earth metal in the zeolitic material in (ii), calculated as alkali metal oxide and alkaline earth metal oxide, is from 0% to 0.1% by weight, based in each case on the total weight of the zeolitic material, and where the aldol condensation catalyst in (ii) comprises, outside the framework structure of the zeolitic material present therein, from 0% to 1% by weight of vanadium, based on vanadium as vanadium(V) oxide.

Abstract translation: 一种制备丙烯酸的方法，包括（i）提供包含甲醛源和乙酸的料流S4; （ii）使流体S4与包含框架结构中包含铝的沸石材料的醛醇缩合催化剂接触以获得包含丙烯酸的流S6，（ii）中的沸石材料的框架结构包含YO 2和Al 2 O 3，Y是 四价元素 其中（ii）中的沸石材料中的碱金属和碱土金属的总含量以碱金属氧化物和碱土金属氧化物计算为0〜0.1重量％，基于每种情况下的总重量 沸石材料，并且其中（ii）中的醛醇缩合催化剂在其中存在的沸石材料的骨架结构外包含以钒为氧化钒（V）的钒为0至1重量％的钒。

公开(公告)号：US09446390B2

公开(公告)日：2016-09-20

申请号：US14724204

申请日：2015-05-28

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Armin Lange De Oliveira ,  Michael Lejkowski ,  Nicolai Tonio Woerz ,  Marco Hartmann ,  Kazuhiko Amakawa ,  Michael Goebel ,  Ulrich Mueller ,  Mathias Feyen ,  Yong Liu

IPC: B01J29/70 ,  B01J29/40 ,  C07C51/353

CPC classification number: B01J29/7088 ,  B01J29/405 ,  B01J29/7007 ,  B01J29/7038 ,  B01J29/7057 ,  C07C51/353 ,  C07C57/04

Abstract: The present invention relates to a process for preparing acrylic acid comprising (i) providing a stream comprising a formaldehyde source and acetic acid and (ii) contacting this stream with an aldol condensation catalyst comprising a zeolitic material, wherein the framework structure of the zeolitic material in (ii) includes Si and O, and has a molar Al:Si ratio of 0:1 to 0.001:1, and wherein the framework structure of the zeolitic material in (ii), in addition to Si and any Al, comprises one or more elements selected from the group consisting of tetravalent elements Y other than Si and trivalent elements X other than Al.

Abstract translation: 本发明涉及一种制备丙烯酸的方法，其包括（i）提供包含甲醛源和乙酸的流，和（ii）使该流与包含沸石材料的醛醇缩合催化剂接触，其中沸石材料的骨架结构 在（ii）中包括Si和O，并且具有0:1至0.001:1的摩尔Al:Si比，并且其中除了Si和任何Al之外，（ii）中的沸石材料的骨架结构包含一个 或更多选自除Si以外的四价元素Y和除Al以外的三价元素X的元素。