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    Absorbent for selective removal of hydrogen sulfide from a fluid stream
    2.
    发明授权
    Absorbent for selective removal of hydrogen sulfide from a fluid stream 有权

    公开(公告)号：US11369919B2

    公开(公告)日：2022-06-28

    申请号：US16556903

    申请日：2019-08-30

    Applicant: BASF SE

    Inventor： Gerald Vorberg ,  Ralf Notz ,  Thomas Ingram ,  Georg Sieder ,  Torsten Katz

    IPC: B01D53/52 ,  B01D53/14 ,  B01D53/78 ,  B01D53/96 ,  C07C217/08 ,  C07C217/28 ,  C07C217/42 ,  C10L3/10

    Abstract: An absorbent for selective removal of hydrogen sulfide over carbon dioxide from a fluid stream comprises an aqueous solution of a) a tertiary amine, b) a sterically hindered secondary amine of the general formula (I) in which R1 and R2 are each independently selected from C1-4-alkyl and C1-4-hydroxyalkyl; R3, R4, R5 and R6 are each independently selected from hydrogen, C1-4-alkyl and C1-4-hydroxyalkyl, with the proviso that at least one R4 and/or R5 radical on the carbon atom bonded directly to the nitrogen atom is C1-4-alkyl or C1-4-hydroxyalkyl when R3 is hydrogen; x and y are integers from 2 to 4 and z is an integer from 1 to 4; where the molar ratio of b) to a) is in the range from 0.05 to 1.0, and c) an acid in an amount, calculated as neutralization equivalent relative to the protonatable nitrogen atoms in a) and b), of 0.05 to 15.0%. One preferred amine of the formula I is 2-(2-tert-butylaminoethoxy)ethanol. The absorbent allows a defined H2S selectivity to be set at pressures of the kind typical in natural gas processing.

    Premix for producing an absorption agent for removing acid gases from a fluid flow
    4.
    发明授权
    Premix for producing an absorption agent for removing acid gases from a fluid flow 有权

    公开(公告)号：US11045759B2

    公开(公告)日：2021-06-29

    申请号：US16093731

    申请日：2017-04-06

    Applicant: BASF SE

    Inventor： Thomas Ingram ,  Gerald Vorberg ,  Georg Sieder

    IPC: B01D53/14 ,  C10L3/10

    Abstract: A premixture for producing an absorbent for removing acid gases from a fluid stream containing a) at least a tertiary amine and/or a sterically hindered secondary amine; b) a dicarboxylic acid in an amount, calculated as neutralization equivalent based on the protonatable nitrogen atoms in a), of at least 30%, wherein the dicarboxylic acid has a solubility in water at a temperature of 20° C. of not more than 15 g of dicarboxylic acid per 100 g of water; and c) 20 to 80 wt % of water. Also described is a process for producing an absorbent from the premixture. The premixture is a transportable and readily handleable solution of a dicarboxylic acid having poor solubility in water for producing an absorbent for removing acid gases from a fluid stream.

    Removal of hydrogen sulphide and carbon dioxide from a stream of fluid
    6.
    发明授权
    Removal of hydrogen sulphide and carbon dioxide from a stream of fluid 有权

    公开(公告)号：US10207217B2

    公开(公告)日：2019-02-19

    申请号：US15506635

    申请日：2015-08-20

    Applicant: BASF SE

    Inventor： Thomas Ingram ,  Ralf Notz ,  Gerald Vorberg ,  Georg Sieder

    IPC: B01D53/14 ,  B01D53/52 ,  B01D53/78 ,  B01D53/96 ,  C07C217/08 ,  C07C217/28 ,  C07C217/42

    Abstract: A process for removing hydrogen sulfide and carbon dioxide from a fluid stream comprises a) an absorption step in which the fluid stream is contacted with an absorbent comprising an aqueous solution (i) of an amine of the general formula (I) in which R1, R2 and R3 are each independently selected from C1-4-alkyl and C1-4-hydroxyalkyl; each R4 is independently selected from hydrogen, C1-4-alkyl and C1-4-hydroxyalkyl; each R5 is independently selected from hydrogen, C1-4-alkyl and C1-4-hydroxyalkyl; X is OH or NH(CR1R2R3); m is 2, 3, 4 or 5; n is 2, 3, 4 or 5; and o is 0 or 1; and optionally (ii) at least one tertiary amine, where the molar ratio of (i) to (ii) is greater than 0.05; wherein at least 90% of the hydrogen sulfide is removed from the fluid stream and selectivity for hydrogen sulfide over carbon dioxide is not greater than 8, wherein a CO2- and H2S-laden absorbent is obtained; b) a regeneration step in which at least a substream of the CO2- and H2S-laden absorbent is regenerated and a regenerated absorbent is obtained; and c) a recycling step in which at least a substream of the regenerated absorbent is recycled into the absorption step a). The process allows a high level of hydrogen sulfide removal with a simultaneously high coabsorption of carbon dioxide.

    Absorbent and process for selectively removing hydrogen sulfide
    7.
    发明授权
    Absorbent and process for selectively removing hydrogen sulfide 有权

    公开(公告)号：US11458433B2

    公开(公告)日：2022-10-04

    申请号：US16643665

    申请日：2018-08-30

    Applicant: BASF SE ,  ExxonMobil Research and Engineering Company

    Inventor： Martin Ernst ,  Gerald Vorberg ,  Thomas Ingram ,  Georg Sieder ,  Carla Pereira

    IPC: B01D53/14

    Abstract: An absorbent for the selective removal of hydrogen sulfide over carbon dioxide from a fluid stream, wherein the absorbent contains an aqueous solution, comprising an amine of formula (I) and/or an amine of formula (II) wherein U—V—W is CH—O—CHR5, N—CO—CHR5 or N—CO—NR5; U′—V′—W is C—O—CR5; R1 is independently C1-C5-alkyl; R2 is selected from hydrogen and C1-C5-alkyl; R3 is independently selected from hydrogen and C1-C5-alkyl; R4 is independently selected from hydrogen and C1-C5-alkyl; R5 is selected from hydrogen, C1-C5-alkyl, (C1-C5-alkoxy)-C1-C5-alkyl, and hydroxy-C1-C5-alkyl; and x is an integer from 1 to 10. The absorbent has a reduced tendency for phase separation at temperatures falling within the usual range of regeneration temperatures for the aqueous amine mixtures and a low volatility in aqueous solvents.

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