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公开(公告)号：US09864273B2
公开(公告)日：2018-01-09
申请号：US14394575
申请日：2013-05-06
申请人： BASF SE
IPC分类号： G03F7/031 , C07D209/86 , G02B5/20 , G03F7/027 , C07D209/88 , G03F7/00 , G03F7/30 , G03F7/20
CPC分类号： G03F7/027 , C07D209/86 , C07D209/88 , C08F122/20 , C09D135/02 , G02B5/20 , G03F7/0007 , G03F7/031 , G03F7/033 , G03F7/20 , G03F7/2002 , G03F7/2037 , G03F7/26 , G03F7/30
摘要： Oxime ester compounds of the formula I, II, III, IV or V, wherein Z is for example (formula A); Z1 for is NO2, unsubstituted or substituted C7-C20aroyl or unsubstituted or substituted C4-C20heteroaroyl; provided that at least one Z1 is other than NO2; Z2 is for example unsubstituted or substituted C7-C20aroyl; R1, R2, R3, R4, R5 and R6 for example are hydrogen, halogen, or unsubstituted or substituted C1-C20alkyl, unsubstituted or substituted C6-C20aryl, or unsubstituted or substituted C4-C20heteroaryl; R9, R10, R11, R12 and R13 for example are hydrogen, halogen, OR16, unsubstituted or substituted C1-C20alkyl; provided that R9 and R13 are neither hydrogen nor fluorine; R14 is for example unsubstituted or substituted C6-C20aryl or C3-C20heteroaryl Q is for example C6-C20arylene or C3-C20heteroarylene; Q1 is —C1-C20alkylene-CO—; Q2 is naphthoylene; Q3 is for example phenylene; L is for example O-alkylene-O—; R15 is for example hydrogen or C1-C20alkyl; R20 is for example hydrogen, or unsubstituted or substituted C1-C20alkyl; are effective photoinitiators.
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公开(公告)号：US11209733B2
公开(公告)日：2021-12-28
申请号：US16563982
申请日：2019-09-09
申请人： BASF SE
IPC分类号： G03F7/031 , G03F7/027 , G03F7/00 , C07D209/88 , G03F7/20 , G03F7/30 , C07D209/86 , C08F122/20 , C09D135/02 , G02B5/20 , G03F7/033 , G03F7/26
摘要： Oxime ester compounds of the formula I, II, III, IV or V wherein Z is for example Z1 for is NO2, unsubstituted or substituted C7-C20aroyl or unsubstituted or substituted C4-C20heteroaroyl; provided that at least one Z1 is other than NO2; Z2 is for example unsubstituted or substituted C7-C20aroyl; R1, R2, R3, R4, R5 and R6 for example are hydrogen, halogen, or unsubstituted or substituted C1-C20alkyl, unsubstituted or substituted C6-C20aryl, or unsubstituted or substituted C4-C20heteroaryl; R9, R10, R11, R12 and R13 for example are hydrogen, halogen, OR16, unsubstituted or substituted C1-C20alkyl; provided that R9 and R13 are neither hydrogen nor fluorine; R14 is for example unsubstituted or substituted C6-C20aryl or C3-C20heteroaryl Q is for example C6-C20arylene or C3-C20heteroarylene; Q1 is —C1-C20alkylene-CO—; Q2 is naphthoylene; Q3 is for example phenylene; L is for example O-alkylene-O—; R15 is for example hydrogen or C1-C20alkyl; R20 is for example hydrogen, or unsubstituted or substituted C1-C20alkyl; are effective photoinitiators.
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公开(公告)号：US09365515B2
公开(公告)日：2016-06-14
申请号：US14361113
申请日：2012-12-03
申请人： BASF SE
IPC分类号： C07D209/00 , G03F7/031 , C07D209/80 , G03F7/00 , C07D403/12 , C07D209/86 , C07D409/04 , C07D409/14 , C08F2/50 , G02B5/20 , G03F7/20
CPC分类号： C07D209/80 , C07D209/86 , C07D403/12 , C07D409/04 , C07D409/14 , C08F2/50 , G02B5/201 , G03F7/0007 , G03F7/20
摘要： Oxime ester compounds of formula (I), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 independently of each other are hydrogen, C1-C20alkyl, (A), COR14, NO2, or OR15; provided that at least one of R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 is (A), and provided that at least one of the remaining R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 is COR14 or NO2; R11 is for example C1-C20alkyl, M or (B); X and X1 are for example a direct bond; R12 and R′12 are for example hydrogen or C1-C20alkyl; R13 and R′13 are for example C6-C20aryl or C3-C20heteroaryl; M is (X), (Y) or (Z); X3 is O, S or NR19; R14 and R15 are for example phenyl; R20, R21, R22, R23, R24, or R25 for example are hydrogen, COR14, NO2, or (B); provided that at least two oxime ester groups are present in the molecule; are useful as photoinitiators.
摘要翻译： 式（I）的肟酯化合物，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9和R 10彼此独立地是氢，C 1 -C 20烷基，（A），COR 14，NO 2或 OR15; 条件是R1，R2，R3，R4，R5，R6，R7，R8，R9和R10中的至少一个是（A），并且条件是剩余的R1，R2，R3，R4，R5， R6，R7，R8，R9和R10是COR14或NO2; R 11例如为C 1 -C 20烷基，M或（B）; X和X1例如是直接键; R 12和R 12如氢或C 1 -C 20烷基; R 13和R 13如C 6 -C 20芳基或C 3 -C 20杂芳基; M为（X），（Y）或（Z）; X3是O，S或NR19; R 14和R 15例如为苯基; R 20，R 21，R 22，R 23，R 24或R 25例如是氢，COR 14，NO 2或（B）; 条件是分子中存在至少两个肟酯基团; 作为光引发剂是有用的。
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公开(公告)号：US20150064624A1
公开(公告)日：2015-03-05
申请号：US14394575
申请日：2013-05-06
申请人： BASF SE
CPC分类号： G03F7/027 , C07D209/86 , C07D209/88 , C08F122/20 , C09D135/02 , G02B5/20 , G03F7/0007 , G03F7/031 , G03F7/033 , G03F7/20 , G03F7/2002 , G03F7/2037 , G03F7/26 , G03F7/30
摘要： Oxime ester compounds of the formula I, II, III, IV or V, wherein Z is for example (formula A); Z1 for is NO2, unsubstituted or substituted C7-C20aroyl or unsubstituted or substituted C4-C20heteroaroyl; provided that at least one Z1 is other than NO2; Z2 is for example unsubstituted or substituted C7-C20aroyl; R1, R2, R3, R4, R5 and R6 for example are hydrogen, halogen, or unsubstituted or substituted C1-C20alkyl, unsubstituted or substituted C6-C20aryl, or unsubstituted or substituted C4-C20heteroaryl; R9, R10, R11, R12 and R13 for example are hydrogen, halogen, OR16, unsubstituted or substituted C1-C20alkyl; provided that R9 and R13 are neither hydrogen nor fluorine; R14 is for example unsubstituted or substituted C6-C20aryl or C3-C20heteroaryl Q is for example C6-C20arylene or C3-C20heteroarylene; Q1 is —C1-C20alkylene-CO—; Q2 is naphthoylene; Q3 is for example phenylene; L is for example O-alkylene-O—; R15 is for example hydrogen or C1-C20alkyl; R20 is for example hydrogen, or unsubstituted or substituted C1-C20alkyl; are effective photoinitiators.
摘要翻译： 式I，II，III，IV或V的肟酯化合物，其中Z为例如（式A）; Z1为NO2，未取代或取代的C7-二芳基或未取代或取代的C4-C20杂芳酰基; 条件是至少一个Z1不是NO 2; Z2为例如未取代或取代的C7-碳酰基; R 1，R 2，R 3，R 4，R 5和R 6例如是氢，卤素或未取代或取代的C 1 -C 20烷基，未取代或取代的C 6 -C 20芳基，或未取代或取代的C 4 -C 20杂芳基; R 9，R 10，R 11，R 12和R 13例如是氢，卤素，OR 16，未取代或取代的C 1 -C 20烷基; 条件是R 9和R 13既不是氢也不是氟; R 14例如为未取代或取代的C 6 -C 20芳基或C 3 -C 20杂芳基Q为例如C 6 -C 20亚芳基或C 3 -C 20杂芳基; Q1是-C1-C20亚烷基-CO-; Q2是亚萘基; Q3例如为亚苯基; L是例如O-亚烷基-O-; R 15是例如氢或C 1 -C 20烷基; R 20是例如氢，或未取代或取代的C 1 -C 20烷基; 是有效的光引发剂。
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公开(公告)号：US11209734B2
公开(公告)日：2021-12-28
申请号：US16563984
申请日：2019-09-09
申请人： BASF SE
IPC分类号： G03F7/031 , G03F7/027 , G03F7/00 , C07D209/88 , G03F7/20 , G03F7/30 , C07D209/86 , C08F122/20 , C09D135/02 , G02B5/20 , G03F7/033 , G03F7/26
摘要： Oxime ester compounds of the formula I, II, III, IV or V wherein Z is for example Z1 for is NO2, unsubstituted or substituted C7-C20aroyl or unsubstituted or substituted C4-C20heteroaroyl; provided that at least one Z1 is other than NO2; Z2 is for example unsubstituted or substituted C7-C20aroyl; R1, R2, R3, R4, R5 and R6 for example are hydrogen, halogen, or unsubstituted or substituted C1-C20alkyl, unsubstituted or substituted C6-C20aryl, or unsubstituted or substituted C4-C20heteroaryl; R9, R10, R11, R12 and R13 for example are hydrogen, halogen, OR16, unsubstituted or substituted C1-C20alkyl; provided that R9 and R13 are neither hydrogen nor fluorine; R14 is for example unsubstituted or substituted C6-C20aryl or C3-C20heteroaryl Q is for example C6-C20arylene or C3-C20heteroarylene; Q1 is —C1-C20alkylene-CO—; Q2 is naphthoylene; Q3 is for example phenylene; L is for example O-alkylene-O—; R15 is for example hydrogen or C1-C20alkyl; R20 is for example hydrogen, or unsubstituted or substituted C1-C20alkyl; are effective photoinitiators.
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公开(公告)号：US11204554B2
公开(公告)日：2021-12-21
申请号：US16563980
申请日：2019-09-09
申请人： BASF SE
IPC分类号： G03F7/031 , G03F7/027 , G03F7/00 , C07D209/88 , G03F7/20 , G03F7/30 , C07D209/86 , C08F122/20 , C09D135/02 , G02B5/20 , G03F7/033 , G03F7/26
摘要： Oxime ester compounds of the formula I, II, III, IV or V wherein Z is for example Z1 for is NO2, unsubstituted or substituted C7-C20 aroyl or unsubstituted or substituted C4-C20heteroaroyl; provided that at least one Z1 is other than NO2; Z2 is for example unsubstituted or substituted C7-C20aroyl; R1, R2, R3, R4, R5 and R6 for example are hydrogen, halogen, or unsubstituted or substituted C1-C20alkyl, unsubstituted or substituted C6-C20aryl, or unsubstituted or substituted C4-C20heteroaryl; R9, R10, R11, R12 and R13 for example are hydrogen, halogen, OR16, unsubstituted or substituted C1-C20alkyl; provided that R9 and R13 are neither hydrogen nor fluorine; R14 is for example unsubstituted or substituted C6-C20aryl or C3-C20heteroaryl Q is for example C6-C20arylene or C3-C20heteroarylene; Q1 is —C1-C20alkylene-CO—; Q2 is naphthoylene; Q3 is for example phenylene; L is for example O-alkylene-O—; R15 is for example hydrogen or C1-C20alkyl; R20 is for example hydrogen, or unsubstituted or substituted C1-C20alkyl; are effective photoinitiators.
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7.发明授权公开(公告)号：US09917260B2
公开(公告)日：2018-03-13
申请号：US14913817
申请日：2014-08-14
申请人： BASF SE
发明人： Sudhakar Sundarraj , Christian Eickhoff , Sheeja Bahulayan , Robert Send , Yuichi Nishimae , Helmut Reichelt , Junichi Tanabe , Peter Erk
CPC分类号： H01L51/0068 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1029 , C09K2211/1037 , C09K2211/104 , C09K2211/1088 , C09K2211/1092 , H01L51/0046 , H01L51/0052 , H01L51/0053 , H01L51/0065 , H01L51/0067 , H01L51/0069 , H01L51/0071 , H01L51/0072 , H01L51/0074 , H01L51/424 , H05B33/10
摘要： The present invention relates to a photoactive material comprising a donor substance and an acceptor substance, wherein the donor substance comprises or consists of one or more compounds of formula (I) described herein, or the acceptor substance comprises or consists of one or more compounds of formula (I) described herein, or the donor substance comprises or consists of a first compound of formula (I) described herein and the acceptor substance comprises a second compound of formula (I) described herein with the proviso that the first and second compound are not the same, as well as to an organic solar cell comprising said photoactive material. The present invention also relates to a photoelectric conversion device comprising or consisting of two or more organic solar cells comprising said photoactive material and to compounds of formula (I) as described herein for use as donor substance or as acceptor substance in a photoactive material, Further, the present invention relates to the use of a compound of formula (III) as described herein in the synthesis of a compound of formula (I)as described herein.
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公开(公告)号：US20140334027A1
公开(公告)日：2014-11-13
申请号：US14361113
申请日：2012-12-03
申请人： BASF SE
IPC分类号： C07D209/80 , C07D209/86 , G02B5/20 , C07D409/04 , C08F2/50 , G03F7/20 , C07D409/14
CPC分类号： C07D209/80 , C07D209/86 , C07D403/12 , C07D409/04 , C07D409/14 , C08F2/50 , G02B5/201 , G03F7/0007 , G03F7/20
摘要： Oxime ester compounds of formula (I), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 independently of each other are hydrogen, C1-C20alkyl, (A), COR14, NO2, or OR15; provided that at least one of R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 is (A), and provided that at least one of the remaining R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 is COR14 or NO2; R11 is for example C1-C20alkyl, M or (B); X and X1 are for example a direct bond; R12 and R′12 are for example hydrogen or C1-C20alkyl; R13 and R′13 are for example C6-C20aryl or C3-C20heteroaryl; M is (X), (Y) or (Z); X3 is O, S or NR19; R14 and R15 are for example phenyl; R20, R21, R22, R23, R24, or R25 for example are hydrogen, COR14, NO2, or (B); provided that at least two oxime ester groups are present in the molecule; are useful as photoinitiators.
摘要翻译： 式（I）的肟酯化合物，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9和R 10彼此独立地是氢，C 1 -C 20烷基，（A），COR 14，NO 2或 OR15; 条件是R1，R2，R3，R4，R5，R6，R7，R8，R9和R10中的至少一个是（A），并且条件是剩余的R1，R2，R3，R4，R5， R6，R7，R8，R9和R10是COR14或NO2; R 11例如为C 1 -C 20烷基，M或（B）; X和X1例如是直接键; R 12和R 12如氢或C 1 -C 20烷基; R 13和R 13如C 6 -C 20芳基或C 3 -C 20杂芳基; M为（X），（Y）或（Z）; X3是O，S或NR19; R 14和R 15例如为苯基; R 20，R 21，R 22，R 23，R 24或R 25例如是氢，COR 14，NO 2或（B）; 条件是分子中存在至少两个肟酯基团; 作为光引发剂是有用的。
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