公开(公告)号：US3894060A

公开(公告)日：1975-07-08

申请号：US29359072

申请日：1972-09-29

Applicant: BAYER AG

Inventor： HEDERICH VOLKER ,  DIETERICH DIETER ,  REIFF HELMUT ,  GEHRKE GUNTER

IPC: C09B1/14 ,  C09B1/54 ,  C09B1/58 ,  C09B1/56

CPC classification number: C09B1/545 ,  C09B1/22 ,  C09B1/36 ,  C09B1/50 ,  C09B1/58

Abstract: New anthraquinone compounds of the formulae

AND

IN WHICH X1 denotes a hydroxyl or amino group, X2 denotes a hydroxyl, amino, alkylamino, cycloalkylamino, arylamino, acylamino, alkylmercapto or arylmercapto group, Y represents hydrogen, halogen, alkylmercapto or arylmercapto radicals, R represents an alkyl radical, Hal represents chlorine, bromine or iodine and Z represents hydrogen or an acyl radical, AS WELL AS THEIR MANUFACTURE AND USE FOR DYEING AND PRINTING SYNTHETIC FIBRE MATERIALS.

Abstract translation: 新的蒽醌化合物，其中X1表示羟基或氨基，X2表示羟基，氨基，烷基氨基，环烷基氨基，芳基氨基，酰氨基，烷基巯基或芳基巯基，Y表示氢，卤素，烷基巯基或芳基巯基，R表示 烷基，Hal代表氯，溴或碘，Z代表氢或酰基，以及它们的制造和用途，用于染色和印刷合成纤维材料。

公开(公告)号：US3642835A

公开(公告)日：1972-02-15

申请号：US3642835D

申请日：1968-11-26

Applicant: BAYER AG

Inventor： HEDERICH VOLKER ,  GEHRKE GUNTER

IPC: C09B1/54

CPC classification number: C09B1/545 ,  C09B1/503

Abstract: 1-(H2N-),2-(R1-O-B(-O-R2)-O-),4-(HO-)ANTHRAQUINONE

IN WHICH B STANDS FOR THE RADICAL

-CH2-CH(-)-CH2-

OR FOR THE RADICAL

-CH(-CH2-)2

WHEREIN R1 STANDS FOR HYDROGEN OR FOR AN OPTIONALLY SUBSTITUTED ARYL RADICAL, AND R2 STANDS FOR AN OPTIONALLY SUBSTITUTED ARYL RADICAL OR FOR AN OPTIONALLY SUBSTITUTED HYDROAROMATIC RADICAL.

SYNTHETIC FIBER MATERIALS, PARTICULARLY POLYESTERS, MAY BE DYED AND PRINTED WITH ANTHRAQUINONE DYESTUFFS CORRESPONDING TO THE FORMULA:

公开(公告)号：US3532723A

公开(公告)日：1970-10-06

申请号：US3532723D

申请日：1966-07-21

Applicant: BAYER AG

Inventor： HEDERICH VOLKER ,  GEHRKE GUNTER ,  OERTZEN KLAUS VON

IPC: C09B1/503 ,  C09B1/514 ,  C09B1/515 ,  C09B1/516 ,  C09B1/50 ,  C09B1/52

CPC classification number: C09B1/516 ,  C09B1/503 ,  C09B1/514 ,  C09B1/515

公开(公告)号：US3642425A

公开(公告)日：1972-02-15

申请号：US3642425D

申请日：1970-08-21

Applicant: BAYER AG

Inventor： GEHRKE GUNTER ,  HEDERICH VOLKER

IPC: C09B1/58 ,  C09B1/473 ,  C09B1/60 ,  D06P1/90 ,  D06P1/20

CPC classification number: D06P1/908 ,  C09B1/36 ,  C09B1/473 ,  C09B1/60 ,  Y10S8/938

Abstract: Process for the continuous dyeing of synthetic fiber materials from organic solvents, characterized in that the fiber materials are impregnated with dyestuffs liquors which contain anthraquinone dyestuffs of formula IN WHICH R represents a C1-C18-alkyl radical and R1 denotes a C1-C18-alkyl, cycloalkyl or aralkyl radical or an optionally substituted phenyl radical, with the provisco that the sum of the carbon atoms present in total in R and R1 is at least 6 and at most 36, and that the fiber materials are subsequently subjected to a heat treatment. The dyeings obtained are distinguished by high dyestuff yield, very good buildup and excellent fastness properties, especially very good fastness to thermofixing, washing, rubbing and light.

Abstract translation: 用于从有机溶剂中连续染色合成纤维材料的方法，其特征在于纤维材料用含有式IN的蒽醌染料的染料浸渍，其中R代表C1-C18-烷基，R1表示C1-C18-烷基 ，环烷基或芳烷基或任选取代的苯基，其特征在于总共存在于R和R 1中的碳原子总数至少为6且至多36，并且随后对纤维材料进行热处理 。

公开(公告)号：US3505362A

公开(公告)日：1970-04-07

申请号：US3505362D

申请日：1966-04-25

Applicant: BAYER AG

Inventor： HEDERICH VOLKER ,  GEHRKE GUNTER ,  BIEN HANS-SAMUEL

IPC: C09B1/503 ,  C09B1/50

CPC classification number: C09B1/503 ,  Y10S8/922

公开(公告)号：US3467681A

公开(公告)日：1969-09-16

申请号：US3467681D

申请日：1968-02-14

Applicant: BAYER AG

Inventor： HEDERICH VOLKER ,  GEHRKE GUNTER

IPC: C09B1/54 ,  C09B1/52 ,  D06P3/52

CPC classification number: C09B1/547 ,  C09B1/36 ,  Y10S8/922

Abstract: The invention comprises anthraquinone dyes of the general formula in which X is a halogen atom or an alkyl, hydroxyalkyl, alkoxy, hydroxyalkoxy, or alkylmercapto radical, R is a substituted or unsubstituted aryl radical and n has the values 0, 1, 2 or 3. The dyes may be made by reacting 1 - amino - 4 - aryl - sulphonamido - anthraquinones having exchangeable groups in the 2-position, e.g. sulphonic acid or halogen groups, with substituted or unsubstituted phenols, or by reacting 1,4 - diamino - 2 - phenoxy-anthraquinones with aryl-sulphohalides. R above is preferably a p-toluyl radical. The reaction using phenols is generally effected in the presence of a strong alkali, e.g. potassium or sodium hydroxides or carbonates and at temperatures of 100-180 DEG C. whilst the reaction employing sulphohalides, especially chloro and bromo derivatives, is effected in a solvent at 100-150 DEG C. optionally in the presence of an acid binding agent, solvents referred to being toluene, chlorobenzene, nitrobenzene, pyridine and dioxan. The following compounds as well as the general class of compounds above are claimed per se. 1 - amino - 2 - phenoxy - 4-p - toluene - sulphonamido - anthraquinone; 1 - amino - 2 - (41 - methoxy - phenoxy) - 4 - p-toluene - sulphonamido - anthraquinone; 1-amino - 2 - (31 - chlorophenoxy) - 4 - p - toluene-sulphonamido anthraquinone; 1 - amino - 2-phenoxy - 4 - p - chlorobenzene - sulphonamido - anthraquinone; 1 - amino - 2 - phenoxy-4 - (31,41 - dichlorobenzene -sulphonamido-anthraquinone; 1 - amino - 2 - phenoxy - 4-p - nitrobenzene - sulphonamido - anthraquinone; 1 - amino - 2 - phenoxy - 4 - (31-nitrobenzene - sulphonamido) - anthraquinone; 1 - amino - 2 - phenoxy - 4 - benzene - sulphonamido - anthraquinone; 1 - amino - 2 - phenoxy-4 - o - toluene - sulphonamido - anthraquinone; 1 - amino - 2 (41 - methyl-mercapto -phenoxy)-4-p-toluene-sulphonamido-anthraquinone.ALSO:Polyester materials are dyed using dyes of general formula in which X is halogen, alkyl, hydroxyalkyl, alkoxy, hydroxyalkoxy, or alkyl mercapto, R is a substituted or unsubstituted aryl group and n has the values O, 1, 2 or 3. The dyeing is effected in the presence of carriers at 100 DEG C. or preferably at 110-130 DEG C. under pressure. The dyes are also suitable for use in the thermosol process by which the dyes are fixed by heating at temperature of about 200 DEG C.