摘要:
Reactive dyes of the formula ##STR1## in which D is the radical of a dye of the monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide series, R.sub.1 and R.sub.2, independently of each other, are each hydrogen or the radical of an unsubstituted or substituted hydrocarbon, A is an unsubstituted or substituted aliphatic or aromatic bridge member, n is 0 or 1, Y is a --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 --X radical, X is an inorganic or organic radical detachable under alkaline conditions, Z is a radical of the formula ##STR2## and Hal is chlorine or bromine, and if n is 1 Z must not be either of the two radicals mentioned at the end for Z, are suitable for dyeing or printing cellulose fibre materials and produce lightfast and wetfast dyeings or prints.
摘要:
STYRYL DYESTUFFS CONTAINING AT LEAST ONE GROUP OF FORMULA -X-CO-NR-SO2-ALKYL, WHEREIN R IS HYDROGEN ALKYL OR CYCLOALKYL AND X IS AN OXYGEN OR SULPHUR ATOM OR A GROUP OF FORMULA -NR1-, WHEREIN R1 IS A HYDROGEN ALKYL OR CYCLOALKYL. THE DYESTUFF DYE POLYESTER FIBERS IN FAST SHADES.
摘要:
Disclosed are reactive dyes, and the use thereof, according to the formula(R--U).sub.n D--(X).sub.r,in which D is the radical of a monoazo, polyazo or metal complex azo dye; U is --CO-- or --SO.sub.2 --; R is a radical of the formula ##STR1## Z is sulfatoethyl, .beta.-thiosultafoethyl, .beta.-phosphatoethyl, .beta.-acetoxyethyl, .beta.-halogenoethyl or vinyl; alk is straight-chained or branched C.sub.1 -C.sub.6 -alkylene; Y is hydrogen, chlorine, bromine, fluorine, hydroxyl, sulfato, C.sub.1 -C.sub.4 -alkanoyloxy, cyano, carboxyl, alkoxycarbonyl having 1 to 5 C-atoms, carbamoyl or a radical --SO.sub.2 --Z in which Z is as defined above; V is hydrogen or C.sub.1 -C.sub.4 -alkyl unsubstituted or substituted by carboxyl, sulfo, C.sub.1 -C.sub.2 -alkoxy, halogen or hydroxyl or is a radical ##STR2## in which Z, alk and Y are as defined above; R.sub.1 is hydrogen or C.sub.1 -C.sub.6 -alkyl; alk' are independently of each other straight-chained or branched C.sub.2 -C.sub.6 -alkylene; n is 1 or 2, r is 1 or 2, m is 1 to 6, p is 1 to 6, q is 1 to 6; and X is a reactive radical comprising a halogenotriazine, halogenopyrimidine, halogenoacryloyl, halogenopropionyl, .beta.-halogenoethylsulfonyl, .beta.-sulfatoethylsulfonyl or vinylsulfonyl group, with the proviso that if D is a monoazo dye X must comprise a halogenotriazine or halogenopyrimidine group.
WHEREIN D is an optionally substituted phenyl group, X1 is -OH or -NH2, X is an oxygen atom or an optionally substituted, nitrogen atom R is hydrogen, alkyl, or aryl, R2 is aryl, and WHEREIN THE PRYAZOLE RING MAY BE OPTIONALLY SUBSTITUTED IN THE 3-POSITION. The dyestuffs of this invention are free of sulfonic acid groups and are sparingly soluble or insoluble in water. The dyestuffs are especially useful for dyeing and printing synthetic fibers particularly polyester fibers in fast yellow shades with excellent fastness to light, and to sublimation.
摘要:
Reactive dyes useful for dyeing or printing hydroxyl- or nitrogen-containing substrates have the formula ##STR1## where Rg is a radical of the formula ##STR2## Ar is the radical of a benzene or naphthalene ring, Z.sup.1 and Z.sup.2 are each hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl, substituted or unsubstituted phenyl, C.sub.1 -C.sub.4 -alkoxy, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, cyano, halogen or hydroxysulfonyl,Z.sup.3, Z.sup.4 and Z.sup.5 are each hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl or substituted or unsubstituted phenyl,U is a group which is detachable under alkaline reaction conditions,X is in case a) the radical of a chromophore or in case b) the radical of a coupling component to which may additionally be attached, via an azo bridge, the radical of a diazo component and which may have additional reactive groups, andL is in case a) a bridge member or in case b) an azo bridge.