Abstract:
The invention relates to a process for the preparation of a crosslinkable propylene polymer composition comprising melt mixing and reacting, preferably in an extruder, a heterophasic propylene copolymer composition A, at least one crosslinkable grafting component B represented by the formula R1SiR2qY3-q and a radical initiator C. The invention also relates to the moisture cross-linkable polypropylene polymer composition obtainable by the process, to a cross-linked polypropylene polymer composition, to the use of the cross-linkable composition for the manufacture of adhesives, sealants, films, foams, coatings or shaped articles and the use of the crosslinked propylene polymer composition in food packaging, medical devices, textile packaging, technical films and protection films.
Abstract:
The invention relates to an amorphous ethylene-propylene copolymer with an intrinsic viscosity (iV) measured in decalin at 135° C. of at least 2.0 and having at least one of the following properties: (i) more than 1 internal vinylidene unsaturation per chain; and (ii) more than 2 long chain branches per chain.
Abstract:
Catalyst system for producing ethylene copolymers in a high temperature solution process, the catalyst system comprising (i) a metallocene complex of formula (I) wherein M is Hf X is a sigma ligand, L is a bridge of the formula —SiR82—, wherein each R8 is independently a C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl n is 0, 1 or 2 R1 and R1′ are the same or can be different and can be a linear or branched C1-C6-alkyl group, R2 and R2′ are the same or are different and are a CH2—R9 group, with R9 being H or linear or branched C1-C6-alkyl group R5 and R5′ are the same or are different and can be H or a linear or branched C1-C6-alkyl group or a OR group, wherein R is a C1-C6-alkyl group R6 and R6′ are the same or are different and can be H or a C(R10)3 group, with R10 being the same or different and R10 can be H or a linear or branched C1-C6-alkyl group or R5 and R6 and/or R5′ and R6′ taken together form an unsubstituted 4-7 membered ring condensed to the benzene ring of the indenyl moiety, and R7 and R7′ can be the same or are different and can be H or a linear or branched C1-C6-alkyl group (ii) an aluminoxane cocatalyst and/or (iii) a boron containing cocatalyst and (iv) optionally an aluminium alkyl compound.