A CROSSLINKABLE PROPYLENE POLYMER COMPOSITION

    公开(公告)号:US20200095360A1

    公开(公告)日:2020-03-26

    申请号:US16614252

    申请日:2018-05-30

    Applicant: BOREALIS AG

    Abstract: The invention relates to a process for the preparation of a crosslinkable propylene polymer composition comprising melt mixing and reacting, preferably in an extruder, a heterophasic propylene copolymer composition A, at least one crosslinkable grafting component B represented by the formula R1SiR2qY3-q and a radical initiator C. The invention also relates to the moisture cross-linkable polypropylene polymer composition obtainable by the process, to a cross-linked polypropylene polymer composition, to the use of the cross-linkable composition for the manufacture of adhesives, sealants, films, foams, coatings or shaped articles and the use of the crosslinked propylene polymer composition in food packaging, medical devices, textile packaging, technical films and protection films.

    NEW CATALYST SYSTEM FOR PRODUCING POLYETHYLENE COPOLYMERS IN A HIGH TEMPERATURE SOLUTION POLYMERIZATION PROCESS
    3.
    发明申请
    NEW CATALYST SYSTEM FOR PRODUCING POLYETHYLENE COPOLYMERS IN A HIGH TEMPERATURE SOLUTION POLYMERIZATION PROCESS 审中-公开
    用于在高温溶液聚合方法中生产聚乙烯共聚物的新型催化剂体系

    公开(公告)号:US20170037164A1

    公开(公告)日:2017-02-09

    申请号:US15304629

    申请日:2015-04-15

    Applicant: BOREALIS AG

    Abstract: Catalyst system for producing ethylene copolymers in a high temperature solution process, the catalyst system comprising (i) a metallocene complex of formula (I) wherein M is Hf X is a sigma ligand, L is a bridge of the formula —SiR82—, wherein each R8 is independently a C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl n is 0, 1 or 2 R1 and R1′ are the same or can be different and can be a linear or branched C1-C6-alkyl group, R2 and R2′ are the same or are different and are a CH2—R9 group, with R9 being H or linear or branched C1-C6-alkyl group R5 and R5′ are the same or are different and can be H or a linear or branched C1-C6-alkyl group or a OR group, wherein R is a C1-C6-alkyl group R6 and R6′ are the same or are different and can be H or a C(R10)3 group, with R10 being the same or different and R10 can be H or a linear or branched C1-C6-alkyl group or R5 and R6 and/or R5′ and R6′ taken together form an unsubstituted 4-7 membered ring condensed to the benzene ring of the indenyl moiety, and R7 and R7′ can be the same or are different and can be H or a linear or branched C1-C6-alkyl group (ii) an aluminoxane cocatalyst and/or (iii) a boron containing cocatalyst and (iv) optionally an aluminium alkyl compound.

    Abstract translation: 用于在高温溶液方法中生产乙烯共聚物的催化剂体系,所述催化剂体系包含(i)式(I)的茂金属络合物,其中MisHf X是σ配体,L是式-SiR 8 2 - 的桥,其中 每个R 3独立地为C 1 -C 20 - 烃基,三(C 1 -C 20 - 烷基)甲硅烷基,C 6 -C 20 - 芳基,C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基n 是0,1或2,R 1和R 1'相同或不同,可以是直链或支链C 1 -C 6 - 烷基,R 2和R 2'相同或不同,为 CH 2 -R 9基团,其中R 9为H或直链或支链C 1 -C 6烷基R 5和R 5'相同或不同,并且可以是H或直链或支链C 1 -C 6 - 烷基或OR基团,其中R是C 1 -C 6 - 烷基基团R 6和R 6'相同或不同,并且可以是H或C(R 10)3基团,其中R 10是 相同或不同,R 10可以是H或直链或支链C 1 -C 6烷基或R 5和R 6和/或R 5'和 R 6'一起形成未被取代的4-7元环稠合至茚基部分的苯环,R 7和R 7'可以相同或不同,可以是H或直链或支链C 1 -C (ii)铝氧烷助催化剂和/或(iii)含硼助催化剂和(iv)任选的烷基铝化合物。

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