Functionalized polymers, articles prepared therefrom, and methods for making the same
    5.
    发明授权
    Functionalized polymers, articles prepared therefrom, and methods for making the same 有权
    官能化聚合物,由其制备的制品及其制备方法

    公开(公告)号:US09000099B2

    公开(公告)日:2015-04-07

    申请号:US12669194

    申请日:2008-07-10

    Abstract: The invention provides compositions comprising at least one propylene-based polymer, at least one peroxide and at least one coagent. In a preferred example, a composition comprising at least one propylene-based polymer, at least one peroxide, at least one grafting agent, and at least one coagent, and wherein the at least one coagent has a substituted carbon-carbon double bond structure selected from the group consisting of structures (I), (II), (III), (IV) and (V) as follows, including cis and trans isomers wherein D1, D2, D3 and D4 are each, independently, one of the following: (a) a hydrocarbon substituent containing a heteroatom with a nonbonding pair of electrons, and where the heteroatom with the nonbonding pair is directly attached to the carbon-carbon double bond, or (b) a hydrocarbon substituent containing a carbon-carbon pi bonding pair, and where the first carbon of the carbon-carbon pi bonding pair is directly bonded to the carbon-carbon double bond; and wherein the R1, R2 and R3 are each, independently, H, a hydrocarbon substituent, or a substituted hydrocarbon substituent; and wherein R1, R2 and R3, each, independently, does not have the same chemical structure as D1, D2, D3 or D4; and wherein the molar ratio of the “coagent(s)” to “free radicals formed from the peroxide(s)” is from 0.5:1 to 5:1; and wherein the coagent selected from structures (I)-(V) does not contain only one phenyl group, or does not contain only one furyl group.

    Abstract translation: 本发明提供了包含至少一种基于丙烯的聚合物,至少一种过氧化物和至少一种助剂的组合物。 在优选实例中,包含至少一种基于丙烯的聚合物,至少一种过氧化物,至少一种接枝剂和至少一种助剂的组合物,并且其中所述至少一种助剂具有取代的碳 - 碳双键结构 包括由以下结构(I),(II),(III),(IV)和(V)组成的组,包括顺式和反式异构体,其中D1,D2,D3和D4各自独立地为以下之一 (a)含有具有非键合电子对的杂原子的烃取代基,其中与非键合对的杂原子直接连接到碳 - 碳双键上,或(b)含有碳 - 碳键的烃取代基 并且其中碳 - 碳π键合对的第一个碳直接键合到碳 - 碳双键上; 并且其中R 1,R 2和R 3各自独立地为H,烃取代基或取代的烃取代基; 并且其中R1,R2和R3各自独立地不具有与D1,D2,D3或D4相同的化学结构; 并且其中“助剂”与“由过氧化物形成的自由基”的摩尔比为0.5:1至5:1; 并且其中选自结构(I) - (V)的助剂不仅含有一个苯基,或不含有一个呋喃基。

    METHOD FOR PRODUCING OLEFIN BLOCK POLYMER USING GROUP 4 TRANSITION METAL COMPLEX
    8.
    发明申请
    METHOD FOR PRODUCING OLEFIN BLOCK POLYMER USING GROUP 4 TRANSITION METAL COMPLEX 有权
    使用4族过渡金属络合物生产烯烃嵌段聚合物的方法

    公开(公告)号:US20140163173A1

    公开(公告)日:2014-06-12

    申请号:US14176537

    申请日:2014-02-10

    Abstract: A method for producing an olefin block polymer, the method including: polymerizing olefins using a polymerization catalyst (X) and an organometallic compound (C) containing an atom of any of Groups 2, 12, and 13 of the periodic table of the elements, the organometallic compound (C) excluding an activating co-catalyst agent (B), wherein the polymerization catalyst (X) is formed by bringing a transition metal compound (A) into contact with the activating co-catalyst agent (B), the transition metal compound (A) is represented by the following general formula (1), and the activating co-catalyst agent (B) is selected from among an organoaluminumoxy compound (B-1), an organoboron compound (B-2), a zinc co-catalyst component (B-3), and ion-exchange layered silicate (B-4).

    Abstract translation: 一种制备烯烃嵌段聚合物的方法,该方法包括:使用聚合催化剂(X)和含有元素周期表第2,12和13族中任一个的原子的有机金属化合物(C)使烯烃聚合, 除活性助催化剂(B)以外的有机金属化合物(C),其中通过使过渡金属化合物(A)与活化助催化剂(B)接触而形成聚合催化剂(X),过渡 金属化合物(A)由以下通式(1)表示,活化助催化剂(B)选自有机铝氧化合物(B-1),有机硼化合物(B-2),锌 助催化剂组分(B-3)和离子交换层状硅酸盐(B-4)。

    ADHESIVE COMPOSITION AND THERMALLY ADHESIVE MEMBER USING SAME
    10.
    发明申请
    ADHESIVE COMPOSITION AND THERMALLY ADHESIVE MEMBER USING SAME 有权
    粘合组合物和使用该粘合剂组合物和热粘合会员

    公开(公告)号:US20130338284A1

    公开(公告)日:2013-12-19

    申请号:US13996858

    申请日:2011-12-02

    Abstract: The purpose of the present invention is to provide an adhesive composition leading to sufficient adhesive strength when used for bonding to a polyolefin resin molded article that bonds poorly with other members. Another purpose of the present invention is to provide an adhesive composition having excellent heat resistance (heat resistant adhesion) in the bonded part of a composite body obtained by joining a polyolefin resin-formed body and other member. This adhesive composition contains an organic solvent, a carboxyl group-containing polyolefin resin which is dissolved in this organic solvent and which has a melt flow rate of 5 to 40 g/10 min when measured at 130° C., and a polyfunctional isocyanate compound. This adhesive composition may further contain a carboxyl group-containing polyolefin resin having a melting point of 120° C. to 170° C.

    Abstract translation: 本发明的目的是提供一种粘合剂组合物,当粘合到与其它构件不良粘合的聚烯烃树脂模塑制品时,导致足够的粘合强度。 本发明的另一个目的是提供一种通过将聚烯烃树脂成形体与其它构件接合而获得的复合体的接合部分具有优异的耐热性(耐热粘合性)的粘合剂组合物。 该粘合剂组合物含有溶解于该有机溶剂中的有机溶剂,含羧基的聚烯烃树脂,在130℃下测定时的熔体流动速率为5〜40g / 10min,多官能异氰酸酯化合物 。 该粘合剂组合物还可以含有熔点为120〜170℃的含羧基的聚烯烃树脂。

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