Abstract:
The present invention relates to an ethylene polymer composition comprising: (A) an ethylene polymer comprising epoxy-groups, and (B) a cross-linking agent comprising: (B1) an organo-metallic Lewis acid, and at least one of: (B2) a compound comprising at least one amino group; and (B3) a compound comprising at least one hydroxyl group.
Abstract:
The present invention relates to a cross-linkable polyolefin composition comprising a first olefin polymer (A) comprising a first comonomer comprising epoxy groups, and a second olefin polymer (B) comprising a second comonomer comprising carboxylic acid groups and/or precursor thereof.
Abstract:
A polyethylene composition comprising a polyethylene comprising hydrolysable silane groups and a silanol condensation catalyst that can be crosslinked. The crosslinkable polyethylene comprises trimethoxy silane and/or triethoxy silane groups and the silanol condensation catalyst comprises an inorganic tin compound in which a tin atom has no covalent bond to a carbon atom. The crosslinked composition can be used in a cable, such as an insulation layer.
Abstract:
The present invention refers to a method for improving the storage stability and/or transport stability of polymer (A) comprising the following steps: a) providing polymer (A) selected from the group consisting of copolymers of ethylene and a C4C12 alpha olefin comonomer, copolymers of propylene and mixtures thereof containing additionally comonomer units comprising hydrolysable silane groups; b) providing a stabilizer (B) selected from the group consisting of sterically hindered phenols, alkyltri-alkoxysilanes, alkenyltrialkoxysilanes and mixtures thereof; c) mixing polymer (A) and stabilizer (B) to obtain a stabilized polymer composition (I); and d) transferring the stabilized polymer composition (I) obtained in step c) in a container comprising at least one barrier layer. In addition, the present invention relates to the use of stabilizer (B) for improving the storage stability and/or transport stability of polymer (A) stored and/or transported in a container having a barrier layer.
Abstract:
The invention provides a polymer composition comprising (i) an LDPE; (ii) polyolefin (A) comprising epoxy groups; and (iii) polyolefin (B) comprising carboxylic acid groups and/or precursor thereof.
Abstract:
The invention provides a polymer composition comprising (i) an LDPE; (ii) a polypropylene; (iii) polyolefin (A) comprising epoxy groups; and (iii) polyolefin (B) comprising carboxylic acid groups and/or precursor thereof.
Abstract:
The invention provides a polyolefin composition comprising (i) a polyolefin (A) comprising epoxy groups; and (ii) a polyolefin (B) comprising carboxylic acid groups and/or precursors thereof, with the proviso that at least one of (A) and (B) is polyethylene. Preferably one of (A) and (B) is a low density polyethylene (LDPE) and the other is a polypropylene.
Abstract:
The present invention discloses a process for providing a cross-linked composition, the process comprising the steps of (a) providing an ethylene-α-olefin plastomer having—a density of from 850 kg/m3 to 900 kg/m3; and—an melt flow rate (ISO 1133, 2.16 kg, 190° C.) of 0.3 to 50 g/10 min; (b) grafting the ethylene-α-olefin plastomer with silane crosslinker such that the content of silane crosslinker is in the range of 0.1 to 10.0 wt.-% with respect to the grafted ethylene-α-olefin plastomer; (c) contacting said grafted ethylene-α-olefin plastomer with 2 to 8 wt.-% of a tin-free silane crosslinking catalyst with respect to the resulting mixture of grafted ethylene-α-olefin plastomer and tin-freesilane crosslinking catalyst, wherein said tin-free catalyst comprises a Brönsted acid at 23° C. and 50% relative humidity for at least 15 minutes thus forming a cross-linked composition, wherein gel content of said cross-linked composition after 15 min is at least 60%.
Abstract:
The present invention relates to silane crosslinking catalyst comprising: —75 to 85 wt.-% of an olefin acrylate interpolymer and—15 to 25 wt.-% of a hindered amine light stabilizer (HALS) having a number average molecular weight Mn of 1500 to 4000 g/mol; and—optionally up to 5 wt.-% wax, wherein the silane crosslinking catalyst is free of tin, carboxylic acid(s) and sulphonic acid(s), all weight percentages with respect to the total weight of the silane crosslinking catalyst.