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公开(公告)号：US20170369789A1
公开(公告)日：2017-12-28
申请号：US15195553
申请日：2016-06-28
CPC分类号： C10G3/47 , C10G1/06 , C10G3/50 , C10G2300/1014 , C10G2300/202 , Y02P30/20
摘要： Embodiments of a method for producing bio-oil include hydrothermal liquefaction of a biomass (e.g., a lignocellulosic biomass) feedstock to provide a process stream comprising crude oil and an aqueous fraction. The process stream is catalytically upgraded by contact with a sulfided-ruthenium catalyst, in the absence of added hydrogen, at a temperature and pressure effective to reduce an oxygen content of the crude oil, reduce a nitrogen content of the crude oil, reduce a total acid number of the crude oil, increase a H:C mole ratio of the crude oil, reduce a density of the crude oil, reduce a moisture content of the crude oil, reduce viscosity of the crude oil, or any combination thereof, thereby producing an upgraded oil and an upgraded aqueous fraction, which are subsequently separated. The catalytic upgrading process may be a plug-flow process and/or may be performed at or near liquefaction conditions.
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2.发明申请公开(公告)号：US20140054507A1
公开(公告)日：2014-02-27
申请号：US14069333
申请日：2013-10-31
发明人： Douglas C. Elliott , James R. Oyler
CPC分类号： B01J19/14 , B01J21/18 , B01J23/462 , B01J23/75 , B01J23/78 , B01J39/02 , B09B3/00 , B09B3/0083 , C10B53/02 , C10J3/78 , C10J2300/0916 , C10J2300/0923 , C10J2300/0979 , C10L3/08 , C10L5/44 , C10L9/086 , Y02E50/10 , Y02E50/14 , Y02E50/30 , Y02P20/145 , Y02P20/52
摘要： Processing of wet biomass feedstock by liquid-phase catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a pre-treatment temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent removal of soluble sulfate contaminants, or combinations thereof. Processing further includes reacting the soluble sulfate contaminants with cations present in the feedstock material to yield a sulfate-containing precipitate and separating the inorganic precipitates and/or the sulfate-containing precipitates out of the wet feedstock. Having removed much of the inorganic wastes and the sulfate contaminants that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification.
摘要翻译： 通过液相催化水热气化处理湿生物质原料必须解决催化剂污染和中毒问题。 一种解决方案可以包括用加热单元将湿生物质加热到足以使原料中的有机成分分解的预处理温度，用于沉淀无机废物以形成，用于预热湿原料以备后续除去可溶性硫酸盐污染物 ，或其组合。 处理进一步包括使可溶性硫酸盐污染物与原料中存在的阳离子反应以产生含硫酸盐的沉淀物，并将无机沉淀物和/或硫酸盐沉淀物从湿原料中分离出来。 除去大量无机废物和可能引起中毒和结垢的硫酸盐污染物，湿生物质原料可暴露于非均相催化剂进行气化。
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公开(公告)号：US12012552B2
公开(公告)日：2024-06-18
申请号：US17875269
申请日：2022-07-27
CPC分类号： C10B49/16 , C10G1/06 , C10G1/065 , C10G3/40 , C10G3/50 , C10J3/00 , C10L3/08 , C10L9/08 , C10L9/086 , C10J2200/06 , C10J2300/0916 , C10J2300/0973 , C10J2300/1681 , Y02E50/10 , Y02P20/145 , Y02P30/20
摘要： A combined hydrothermal liquefaction (HTL) and catalytic hydrothermal gasification (CHG) system and process are described that convert various biomass-containing sources into separable bio-oils and aqueous effluents that contain residual organics. Bio-oils may be converted to useful bio-based fuels and other chemical feedstocks. Residual organics in HTL aqueous effluents may be gasified and converted into medium-BTU product gases and directly used for process heating or to provide energy.
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公开(公告)号：US11407946B2
公开(公告)日：2022-08-09
申请号：US16179495
申请日：2018-11-02
摘要： A combined hydrothermal liquefaction (HTL) and catalytic hydrothermal gasification (CHG) system and process are described that convert various biomass-containing sources into separable bio-oils and aqueous effluents that contain residual organics. Bio-oils may be converted to useful bio-based fuels and other chemical feedstocks. Residual organics in HTL aqueous effluents may be gasified and converted into medium-BTU product gases and directly used for process heating or to provide energy.
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公开(公告)号：US20190071606A1
公开(公告)日：2019-03-07
申请号：US16179495
申请日：2018-11-02
摘要： A combined hydrothermal liquefaction (HTL) and catalytic hydrothermal gasification (CHG) system and process are described that convert various biomass-containing sources into separable bio-oils and aqueous effluents that contain residual organics. Bio-oils may be converted to useful bio-based fuels and other chemical feedstocks. Residual organics in HTL aqueous effluents may be gasified and converted into medium-BTU product gases and directly used for process heating or to provide energy.
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公开(公告)号：US10138426B2
公开(公告)日：2018-11-27
申请号：US15693354
申请日：2017-08-31
摘要： A combined hydrothermal liquefaction (HTL) and catalytic hydrothermal gasification (CHG) system and process are described that convert various biomass-containing sources into separable bio-oils and aqueous effluents that contain residual organics. Bio-oils may be converted to useful bio-based fuels and other chemical feedstocks. Residual organics in HTL aqueous effluents may be gasified and converted into medium-BTU product gases and directly used for process heating or to provide energy.
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公开(公告)号：US20180023003A1
公开(公告)日：2018-01-25
申请号：US15693354
申请日：2017-08-31
CPC分类号： C10B49/16 , C10G1/06 , C10G1/065 , C10G3/40 , C10G3/50 , C10J3/00 , C10J2200/06 , C10J2300/0916 , C10J2300/0973 , C10J2300/1681 , C10L3/08 , C10L9/08 , C10L9/086 , Y02E50/14 , Y02P20/145 , Y02P30/20
摘要： A combined hydrothermal liquefaction (HTL) and catalytic hydrothermal gasification (CHG) system and process are described that convert various biomass-containing sources into separable bio-oils and aqueous effluents that contain residual organics. Bio-oils may be converted to useful bio-based fuels and other chemical feedstocks. Residual organics in HTL aqueous effluents may be gasified and converted into medium-BTU product gases and directly used for process heating or to provide energy.
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8.发明授权公开(公告)号：US08877098B2
公开(公告)日：2014-11-04
申请号：US14069333
申请日：2013-10-31
发明人： Douglas C. Elliott , James R. Oyler
IPC分类号： C01B3/38 , B09B3/00 , C10L3/08 , C10L5/44 , B01J39/02 , C10B53/02 , C10J3/78 , C10L9/08 , B01J19/14 , B01J23/46 , B01J21/18 , B01J23/78 , B01J23/75
CPC分类号： B01J19/14 , B01J21/18 , B01J23/462 , B01J23/75 , B01J23/78 , B01J39/02 , B09B3/00 , B09B3/0083 , C10B53/02 , C10J3/78 , C10J2300/0916 , C10J2300/0923 , C10J2300/0979 , C10L3/08 , C10L5/44 , C10L9/086 , Y02E50/10 , Y02E50/14 , Y02E50/30 , Y02P20/145 , Y02P20/52
摘要： Processing of wet biomass feedstock by liquid-phase catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a pre-treatment temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent removal of soluble sulfate contaminants, or combinations thereof. Processing further includes reacting the soluble sulfate contaminants with cations present in the feedstock material to yield a sulfate-containing precipitate and separating the inorganic precipitates and/or the sulfate-containing precipitates out of the wet feedstock. Having removed much of the inorganic wastes and the sulfate contaminants that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification.
摘要翻译： 通过液相催化水热气化处理湿生物质原料必须解决催化剂污染和中毒问题。 一种解决方案可以包括用加热单元将湿生物质加热到足以使原料中的有机成分分解的预处理温度，用于沉淀无机废物以形成，用于预热湿原料以备后续除去可溶性硫酸盐污染物 ，或其组合。 处理进一步包括使可溶性硫酸盐污染物与原料中存在的阳离子反应以产生含硫酸盐的沉淀物，并将无机沉淀物和/或硫酸盐沉淀物从湿原料中分离出来。 除去大量无机废物和可能引起中毒和结垢的硫酸盐污染物，湿生物质原料可暴露于非均相催化剂进行气化。
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公开(公告)号：US10167430B2
公开(公告)日：2019-01-01
申请号：US15195553
申请日：2016-06-28
摘要： Embodiments of a method for producing bio-oil include hydrothermal liquefaction of a biomass (e.g., a lignocellulosic biomass) feedstock to provide a process stream comprising crude oil and an aqueous fraction. The process stream is catalytically upgraded by contact with a sulfided-ruthenium catalyst, in the absence of added hydrogen, at a temperature and pressure effective to reduce an oxygen content of the crude oil, reduce a nitrogen content of the crude oil, reduce a total acid number of the crude oil, increase a H:C mole ratio of the crude oil, reduce a density of the crude oil, reduce a moisture content of the crude oil, reduce viscosity of the crude oil, or any combination thereof, thereby producing an upgraded oil and an upgraded aqueous fraction, which are subsequently separated. The catalytic upgrading process may be a plug-flow process and/or may be performed at or near liquefaction conditions.
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公开(公告)号：US09758728B2
公开(公告)日：2017-09-12
申请号：US13893011
申请日：2013-05-13
CPC分类号： C10B49/16 , C10G1/06 , C10G1/065 , C10G3/40 , C10G3/50 , C10J3/00 , C10J2200/06 , C10J2300/0916 , C10J2300/0973 , C10J2300/1681 , C10L3/08 , C10L9/08 , C10L9/086 , Y02E50/14 , Y02P20/145 , Y02P30/20
摘要： A combined hydrothermal liquefaction (HTL) and catalytic hydrothermal gasification (CHG) system and process are described that convert various biomass-containing sources into separable bio-oils and aqueous effluents that contain residual organics. Bio-oils may be converted to useful bio-based fuels and other chemical feedstocks. Residual organics in HTL aqueous effluents may be gasified and converted into medium-BTU product gases and directly used for process heating or to provide energy.
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