摘要:
The present invention relates to comb (block) copolymers obtainable by reactingI at least one (block) copolymer comprising polymerised, optionally substituted styrene and maleic anhydride units, which copolymer has been obtained by living, free-radical polymerisation, with II at least one polyalkylene oxide monoamine comprising a primary amino end group at a reaction temperature of ≧150° C. and by subsequent salification of at least 25 mol % of the free carboxyl groups of the reaction product at a reaction temperature of
摘要:
The present invention relates to comb (block) copolymers obtainable by reacting I at least one (block) copolymer comprising polymerized, optionally substituted styrene and maleic anhydride units, which copolymer has been obtained by living, free-radical polymerization, with II at least one polyalkylene oxide monoamine comprising a primary amino end group at a reaction temperature of ≧150° C. and by subsequent salification of at least 25 mol % of the free carboxyl groups of the reaction product at a reaction temperature of
摘要:
Low-VOC mixture of at least partially salified copolymers of at least one ethylenically unsaturated, phenyl-group-containing monomer and at least one α,β-unsaturated monocarboxylic acid and/or at least one α,β-unsaturated dicarboxylic acid, of at least one water-soluble polyether, esterification products of at least one water-soluble polyether and an aliphatic dicarboxylic acid, and of a star polymer obtainable by esterifying a carboxylic acid containing at least 3 carboxyl groups with at least one water-soluble polyether, and use thereof as a wetting and dispersing agent, preferably for producing low-VOC pigment pastes or low-VOC paint systems.
摘要:
Low-VOC mixture of at least partially salified copolymers of at least one ethylenically unsaturated, phenyl-group-containing monomer and at least one α,β-unsaturated monocarboxylic acid and/or at least one α,β-unsaturated dicarboxylic acid, of at least one water-soluble polyether, esterification products of at least one water-soluble polyether and an aliphatic dicarboxylic acid, and of a star polymer obtainable by esterifying a carboxylic acid containing at least 3 carboxyl groups with at least one water-soluble polyether, and use thereof as a wetting and dispersing agent, preferably for producing low-VOC pigment pastes or low-VOC paint systems.
摘要:
Addition compound suitable as wetting and dispersing agent, obtainable from the reaction of A) polyepoxides with B) at least one primary polyoxyalkyleneamine C) at least one other aliphatic and/or araliphatic primary amine and D) at least one modified isocyanate.
摘要:
Addition compound suitable as wetting and dispersing agent, obtainable from the reaction of A) polyepoxides with B) at least one primary polyoxyalkyleneamine C) at least one other aliphatic and/or araliphatic primary amine and D) at least one modified isocyanate.
摘要:
Addition compound suitable as a wetting and dispersing agent and obtainable from the reaction of A) polyepoxides with B) at least one aliphatic and/or araliphatic primary amine of the general formula I H2N—R I where R is alkyl, cycloalkyl, aryl and aralkyl, and where the primary amine may also carry further functional groups selected from —OH, tertiary amine or carboxyl, and subsequent addition reaction of C) at least one modified isocyanate of the general formula IIa and/or IIb where R3 is alkyl, cycloalkyl, aryl or aralkyl, R1 and R2 independently of one another are H, alkyl and/or aryl, X is alkylene, cycloalkylene and/or aralkylene, Y is alkylene and/or cycloalkylene and n and m are independent of one another, the sum n+m being ≧2, to form a urethane.
摘要:
Reaction products of polyepoxides with amines followed by reaction with polyalkyleneoxide modified and/or polyester-modified and/or polyether-polyester-modified isocyanates give comblike aminic polymers, and their salts. The compounds are useful as wetting and dispersing agents for organic and inorganic pigments, and as fillers for aqueous and solvent-borne systems.
摘要:
A process for preparing a randomly branched copolymer, by reacting the components (a) 10-98.9 mol % of at least one acrylic ester of a straight-chain, branched or cyclic C1-C22-alkyl monoalcohol, (b) 0.1-10 mol % of at least one polyethylenically unsaturated monomer and (c) optionally one or more monoethylenically unsaturated monomers other than acrylic esters of straight-chain, branched or cyclic C1-C22-alkyl monoalcohols and other than compounds of the formula (I), in the presence of (d) 1-10 mol % of at least one compound of the formula (I) H3C—CRaRc—CH2—CRa—CH2 (I) where Ra, Rb are each independently aryl, CN or COOR1 where R1═H, alkyl, aryl or aralkyl, and Rc=alkyl, aryl or aralkyl, and is the presence of at least one initiator of free-radical polymerization in a free-radical polymerization, where the stated molar proportions of components (a), (b), (c) and (d) add up to 100 mol %, and where the molar proportion of component (b) does not exceed the molar proportion of component (d), Copolymers obtainable by the process and use thereof as levelling agents in coating substances.
摘要:
The invention relates to copolymers comprising three segments of different ion density, the fraction of the ionic monomers in each segment being from 1 to 100 mol %, the second and third segment containing ethylenically unsaturated monomers of the respectively preceding segment, and the copolymers being preparable by means of a monofunctional initiator by way of NMP or RAFT. The invention further relates to a process for preparing copolymers and to their use as dispersants.