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公开(公告)号:US20180305216A1
公开(公告)日:2018-10-25
申请号:US16017823
申请日:2018-06-25
申请人: Board of Regents, The University of Texas System , Universidade Do Porto , LNEG-LABORATORIO NACIONAL DE ENEGIA E GEOLOGIA
发明人: John B. Goodenough , Maria Helena Sousa Soares De Oliveira Braga , Jose Jorge Do Amaral Ferreira , Preetam Singh
IPC分类号: C01B33/32 , H01G11/84 , H01M10/0562 , H01M8/124 , H01G11/56 , C03C4/18 , C03C1/00 , H01M10/36 , H01M8/1016 , C01B11/00 , C01B25/30 , C01B25/32 , C01B33/24 , C01F11/46 , C01D5/02 , H01G11/62
CPC分类号: C01B33/32 , C01B11/00 , C01B25/306 , C01B25/322 , C01B33/24 , C01D5/02 , C01F11/462 , C03C1/006 , C03C4/18 , H01G11/56 , H01G11/62 , H01G11/84 , H01M8/1016 , H01M8/124 , H01M10/0562 , H01M10/36 , H01M2300/0071 , H01M2300/008 , Y02E60/13 , Y02P70/56 , Y02T10/7022
摘要: The disclosure provides a water-solvated glass/amorphous solid that is an ionic conductor-an electronic insulator, and a dielectric as well as electrochemical devices and processes that use this material, such as batteries, including rechargeable batteries, fuel cells, capacitors, electrolysis cells, and electronic devices. The electrochemical devices and products use a combination of ionic and electronic conduction as well as internal electric dipoles.
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公开(公告)号:US09890048B2
公开(公告)日:2018-02-13
申请号:US15178228
申请日:2016-06-09
申请人: Board of Regents, The University of Texas System , Universidade Do Porto , LNEG-LABORATORIO NACIONAL DE ENEGIA E GEOLOGIA
发明人: John B. Goodenough , Maria Helena Sousa Soares De Oliveira Braga , Jose Jorge Do Amaral Ferreira , Preetam Singh
IPC分类号: H01G9/02 , C01B33/32 , H01G11/56 , H01M8/124 , H01M10/0562 , C01B11/00 , C01B25/30 , C01B25/32 , C01B33/24 , C01D5/02 , C01F11/46 , H01G11/62 , H01G11/84 , H01M8/1016 , H01M10/36 , C03C1/00 , C03C4/18
CPC分类号: C01B33/32 , C01B11/00 , C01B25/306 , C01B25/322 , C01B33/24 , C01D5/02 , C01F11/462 , C03C1/006 , C03C4/18 , H01G11/56 , H01G11/62 , H01G11/84 , H01M8/1016 , H01M8/124 , H01M10/0562 , H01M10/36 , H01M2300/0071 , H01M2300/008 , Y02E60/13 , Y02P70/56 , Y02T10/7022
摘要: The disclosure provides a water-solvated glass/amorphous solid that is an ionic conductor-an electronic insulator, and a dielectric as well as electrochemical devices and processes that use this material, such as batteries, including rechargeable batteries, fuel cells, capacitors, electrolysis cells, and electronic devices. The electrochemical devices and products use a combination of ionic and electronic conduction as well as internal electric dipoles.
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公开(公告)号:US20180127280A1
公开(公告)日:2018-05-10
申请号:US15868751
申请日:2018-01-11
申请人: Board of Regents, The University of Texas System , Universidade Do Porto , LNEG-LABORATORIO NACIONAL DE ENEGIA E GEOLOGIA
发明人: John B. Goodenough , Maria Helena Sousa Soares De Oliveira Braga , Jose Jorge Do Amaral Ferreira , Preetam Singh
IPC分类号: C01B33/32 , C01D5/02 , H01M10/0562 , H01M8/124 , H01G11/56 , C03C4/18 , C03C1/00 , H01M10/36 , H01G11/62 , H01G11/84 , H01M8/1016 , C01B11/00 , C01B25/30 , C01B25/32 , C01B33/24 , C01F11/46
CPC分类号: C01B33/32 , C01B11/00 , C01B25/306 , C01B25/322 , C01B33/24 , C01D5/02 , C01F11/462 , C03C1/006 , C03C4/18 , H01G11/56 , H01G11/62 , H01G11/84 , H01M8/1016 , H01M8/124 , H01M10/0562 , H01M10/36 , H01M2300/0071 , H01M2300/008 , Y02E60/13 , Y02P70/56 , Y02T10/7022
摘要: The disclosure provides a water-solvated glass/amorphous solid that is an ionic conductor-an electronic insulator, and a dielectric as well as electrochemical devices and processes that use this material, such as batteries, including rechargeable batteries, fuel cells, capacitors, electrolysis cells, and electronic devices. The electrochemical devices and products use a combination of ionic and electronic conduction as well as internal electric dipoles.
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公开(公告)号:US20160368777A1
公开(公告)日:2016-12-22
申请号:US15178228
申请日:2016-06-09
申请人: Board of Regents, The University of Texas System , Universidade Do Porto , LNEG-LABORATORIO NACIONAL DE ENEGIA E GEOLOGIA
发明人: John B. Goodenough , Maria Helena Sousa Soares De Oliveira Braga , Jose Jorge Do Amaral Ferreira , Preetam Singh
IPC分类号: C01B33/32 , H01M10/36 , H01G11/62 , H01G11/84 , C01B33/24 , C01D5/02 , C01F11/46 , C01B25/30 , C01B25/32 , H01M8/1016 , C01B11/00
CPC分类号: C01B33/32 , C01B11/00 , C01B25/306 , C01B25/322 , C01B33/24 , C01D5/02 , C01F11/462 , C03C1/006 , C03C4/18 , H01G11/56 , H01G11/62 , H01G11/84 , H01M8/1016 , H01M8/124 , H01M10/0562 , H01M10/36 , H01M2300/0071 , H01M2300/008 , Y02E60/13 , Y02P70/56 , Y02T10/7022
摘要: The disclosure provides a water-solvated glass/amorphous solid that is an ionic conductor-an electronic insulator, and a dielectric as well as electrochemical devices and processes that use this material, such as batteries, including rechargeable batteries, fuel cells, capacitors, electrolysis cells, and electronic devices. The electrochemical devices and products use a combination of ionic and electronic conduction as well as internal electric dipoles.
摘要翻译: 本公开提供了一种水溶性玻璃/无定形固体,其是离子导体 - 电子绝缘体,以及电介质以及使用该材料的电化学装置和工艺,例如电池,包括可再充电电池,燃料电池,电容器,电解 电池和电子设备。 电化学装置和产品使用离子和电子传导以及内部电偶极子的组合。
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公开(公告)号:US20190148763A1
公开(公告)日:2019-05-16
申请号:US16243792
申请日:2019-01-09
申请人: BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEM , UNIVERSIDADE DO PORTO , LNEG-LABORATORIO NACIONAL DE ENERGIA E GEOLOGIA
发明人: John B. Goodenough , Maria Helena Sousa Soares De Oliveira Braga , Jose Jorge Do Amaral Ferreira , Joana Cassilda Rodrigues Espain De Oliveira , Andrew Murchison
IPC分类号: H01M10/054 , H01M10/052 , H01M4/38 , H01M10/0562 , H01M4/62
摘要: The present disclosure provides an electrochemical cell including a solid glass electrolyte including an alkali metal working ion that is conducted by the electrolyte, and a dipole, an anode having an effective anode chemical potential μA, and a cathode having an effective cathode chemical potential μC. One or both of the cathode and anode substantially lack the working ion prior to an initial charge or discharge of the electrochemical cell. At open-circuit prior to an initial charge or discharge, an electric double-layer capacitor is formed at one or both of an interface between the solid glass electrolyte and the anode and an interface between the solid glass electrolyte and the cathode due to a difference between μA and μC.
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公开(公告)号:US10446845B2
公开(公告)日:2019-10-15
申请号:US16045953
申请日:2018-07-26
IPC分类号: H01M4/505 , H01M10/0562 , H01M4/131 , H01M4/525 , H01M4/134 , H01M4/38 , H01M4/62 , H01G11/56 , H01G11/50 , H01G11/48 , H01G11/28 , H01G11/32 , H01M10/0525
摘要: The present disclosure provides a rechargeable electrochemical cell including an electrolyte side, a cathode side, and a polymer/plasticizer. The electrolyte side includes a solid glass electrolyte including an electrolyte mobile cation and electric dipoles, as well as an anode including a metal of the electrolyte mobile cation and contacting the solid glass electrolyte at an anode:solid glass electrolyte interface. The cathode side includes a cathode including a cathode active material into which a cathode guest cation is reversibly extracted/inserted. The cathode active material has a voltage versus lithium (Li) metal of between 3V and 15V. The polymer/plasticizer contacts the solid glass electrolyte at a solid glass electrolyte:polymer/plasticizer interface and the cathode at a polymer/plasticizer:cathode interface such that the cathode guest cation is confined to the cathode side and the electrolyte mobile cation is confined to the anode side during charge and discharge of the electrochemical cell.
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公开(公告)号:US10361454B2
公开(公告)日:2019-07-23
申请号:US15795469
申请日:2017-10-27
IPC分类号: H01M10/0562 , H01M10/0561 , H01M4/66 , H01M6/18 , H01M10/056 , H01M4/02
摘要: The present disclosure provides an electrochemical storage cell including a battery. The battery includes an alkali metal anode having an anode Fermi energy, an electronically insulating, amorphous, dried solid electrolyte able to conduct alkali metal, having the general formula A3-xHxOX, in which 0≤x≤1, A is the alkali metal, and X is at least one halide, and a cathode including a cathode current collector having a cathode Fermi energy lower than the anode Fermi energy. During operation of the electrochemical storage cell, the alkali metal plates dendrite-free from the solid electrolyte onto the alkali metal anode. Also during operation of the electrochemical storage cell, the alkali metal further plates on the cathode current collector.
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公开(公告)号:US20190115162A1
公开(公告)日:2019-04-18
申请号:US15782443
申请日:2017-10-12
摘要: The present disclosure provides a heat energy-powered electrochemical cell including an anode, a cathode, and a solid metal polymer/glass electrolyte. The solid metal polymer/glass electrolyte includes between 1% and 50% metal polymer by weight as compared to total solid metal polymer/glass electrolyte weight and between 50% and 90% solid glass electrolyte by weight as compared to the total solid metal polymer/glass electrolyte weight. The solid glass electrolyte includes a working cation and an electric dipole. The heat energy-powered electrochemical cells may be used to capture heat from a variety of sources, including solar hear, waste heat, and body heat. The heat energy-powered electrochemical cells may be fabricated at large-area, thin cells.
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公开(公告)号:US20180342733A1
公开(公告)日:2018-11-29
申请号:US16045953
申请日:2018-07-26
IPC分类号: H01M4/505 , H01G11/32 , H01G11/28 , H01G11/48 , H01G11/50 , H01G11/56 , H01M4/62 , H01M4/38 , H01M4/134 , H01M4/525 , H01M4/131 , H01M10/0562 , H01M10/0525
摘要: The present disclosure provides a rechargeable electrochemical cell including an electrolyte side, a cathode side, and a polymer/plasticizer. The electrolyte side includes a solid glass electrolyte including an electrolyte mobile cation and electric dipoles, as well as an anode including a metal of the electrolyte mobile cation and contacting the solid glass electrolyte at an anode:solid glass electrolyte interface. The cathode side includes a cathode including a cathode active material into which a cathode guest cation is reversibly extracted/inserted. The cathode active material has a voltage versus lithium (Li) metal of between 3V and 15V. The polymer/plasticizer contacts the solid glass electrolyte at a solid glass electrolyte:polymer/plasticizer interface and the cathode at a polymer/plasticizer:cathode interface such that the cathode guest cation is confined to the cathode side and the electrolyte mobile cation is confined to the anode side during charge and discharge of the electrochemical cell.
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公开(公告)号:US20180102569A1
公开(公告)日:2018-04-12
申请号:US15795469
申请日:2017-10-27
IPC分类号: H01M10/0562 , H01M10/056 , H01M4/66 , H01M4/02
CPC分类号: H01M10/0562 , H01M4/661 , H01M6/182 , H01M6/185 , H01M10/056 , H01M2004/028
摘要: The present disclosure provides an electrochemical storage cell including a battery. The battery includes an alkali metal anode having an anode Fermi energy, an electronically insulating, amorphous, dried solid electrolyte able to conduct alkali metal, having the general formula A3-xHxOX, in which 0≦x≦1, A is the alkali metal, and X is at least one halide, and a cathode including a cathode current collector having a cathode Fermi energy lower than the anode Fermi energy. During operation of the electrochemical storage cell, the alkali metal plates dendrite-free from the solid electrolyte onto the alkali metal anode. Also during operation of the electrochemical storage cell, the alkali metal further plates on the cathode current collector.
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