利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

18 条记录 (耗时 0.02 秒)

    SYNTHESIS OF FLUOROCARBOFUNCTIONAL SILSESQUIOXANES
    1.
    发明申请
    SYNTHESIS OF FLUOROCARBOFUNCTIONAL SILSESQUIOXANES 有权
    氟代官能团硅藻糖的合成

    公开(公告)号：US20120157702A1

    公开(公告)日：2012-06-21

    申请号：US13393380

    申请日：2010-08-16

    申请人： Bogdan Marciniec ,  Hieronim Maciejewski ,  Michal Dutkiewicz

    发明人： Bogdan Marciniec ,  Hieronim Maciejewski ,  Michal Dutkiewicz

    IPC分类号： C07F7/21

    CPC分类号： C08G77/045 ,  C08G77/38 ,  C08G77/385 ,  C08G77/46

    摘要： The subject of the invention is the method of synthesis of fluoracarbofunctional cage silsesquioxanes of the general formula in which • R1 stands for HCF2(CF2)n(CH2)mO(CH2)3Si(CH3)2O orHCF2(CF2)n(CH2)mO(CH2)3 group in which n=1-12, m=1-4; • R2, R3, R4, R5, R6, R7, R8 can be the same as R1 or different from it and stand all either for the (C1-C25) alkyl group or any aryl group, based on hydrosilylation of fluoroalkyl-allyl ether with an appropriate hydrogen-silsesquioxane in the presence of siloxide rhodium complex [{Rh(OSiMe3)(cod)}2] as a catalyst.

    摘要翻译： 本发明的主题是通式的氟代官能笼型倍半硅氧烷的合成方法，其中R1表示HCF2（CF2）n（CH2）mO（CH2）3Si（CH3）2O或HCF2（CF2）n（CH2） mO（CH 2）3基，其中n = 1-12，m = 1-4; R 2，R 3，R 4，R 5，R 6，R 7，R 8可以与R 1相同或不同，并且基于氟代烷基 - 烯丙基醚的氢化硅烷化，全部用于（C 1 -C 25）烷基或任何芳基 在合适的氢硅倍半氧烷存在下，作为催化剂存在硅氧烷铑络合物[{Rh（OSiMe 3）（cod）} 2]。

    SYNTHESIS OF FLUOROCARBOFUNCTIONAL ALKOXYSILANES AND CHLOROSILANES
    2.
    发明申请
    SYNTHESIS OF FLUOROCARBOFUNCTIONAL ALKOXYSILANES AND CHLOROSILANES 审中-公开
    氟代烷氧基硅烷和氯代硅烷的合成

    公开(公告)号：US20120165565A1

    公开(公告)日：2012-06-28

    申请号：US13393371

    申请日：2010-08-16

    申请人： Bogdan Marciniec ,  Hieronim Maciejewski ,  Michal Dutkiewicz ,  Izabela Dabek ,  Joanna Karasiewicz

    发明人： Bogdan Marciniec ,  Hieronim Maciejewski ,  Michal Dutkiewicz ,  Izabela Dabek ,  Joanna Karasiewicz

    IPC分类号： C07F7/18 ,  C07F7/12

    CPC分类号： C07F7/1876 ,  C07F7/14

    摘要： The subject of invention is the method of synthesis of fluorocarbofunctional alkoxysilanes and chlorosilanes of the general formula HCF2(CF2)n(CH2)mOC3H7SiR1R2R3 in which -n takes values from 1 to 12, m takes values from 1 to 4,—R1 stands for an alkoxy group or halogen, if R1 stands for an alkoxy group, then R2 and R3 can be the same or different and stand for an alkoxy group containing C=1-4, alkyl group containing C=1-12 or an aryl group, if R1 stands for a halogen, then R2 and R3 can be the same or different and stand for based on hydrosilylation of an appropriate fluoroalkyl-allyl ether with an appropriate trisubstituted silane of the general formula HSiR1R2R3 in the presence of siloxide rhodium complex [{Rh(OSiMe3)(cod)}2] as a catalyst.

    摘要翻译： 本发明的主题是通式为HCF2（CF2）n（CH2）mOC3H7SiR1R2R3的氟代官能团烷氧基硅烷和氯硅烷的合成方法，其中-n取值为1至12，m取值为1至4，-R 1表示 烷氧基或卤素，如果R1代表烷氧基，则R2和R3可以相同或不同，代表含C = 1-4的烷氧基，含C = 1-12的烷基或芳基， 如果R1代表卤素，则R2和R3可以相同或不同，并且基于合适的氟代烷基 - 烯丙基醚与适当的三取代硅烷通式为HSiR1R2R3在硅氧烷铑络合物[{Rh （OSiMe 3）（cod）} 2]作为催化剂。

    Synthesis of fluorocarbofunctional silsesquioxanes
    3.
    发明授权
    Synthesis of fluorocarbofunctional silsesquioxanes 有权
    氟代官能团倍半硅氧烷的合成

    公开(公告)号：US08816117B2

    公开(公告)日：2014-08-26

    申请号：US13393380

    申请日：2010-08-16

    申请人： Bogdan Marciniec ,  Hieronim Maciejewski ,  Michal Dutkiewicz

    发明人： Bogdan Marciniec ,  Hieronim Maciejewski ,  Michal Dutkiewicz

    IPC分类号： C07F7/21 ,  C08G77/04 ,  C08G77/38

    CPC分类号： C08G77/045 ,  C08G77/38 ,  C08G77/385 ,  C08G77/46

    摘要： The subject of the invention is the method of synthesis of fluoracarbofunctional cage silsesquioxanes of the general formula in which•R1 stands for HCF2(CF2)n(CH2)mO(CH2)3Si(CH3)2O or HCF2(CF2)n(CH2)mO(CH2)3 group in which n=1-12, m=1-4;•R2, R3, R4, R5, R6, R7, R8 can be the same as R1 or different from it and stand all either for the (C1-C25) alkyl group or any aryl group, based on hydrosilylation of fluoroalkyl-allyl ether with an appropriate hydrogen-silsesquioxane in the presence of siloxide rhodium complex [{Rh(OSiMe3)(cod)}2] as a catalyst.

    摘要翻译： 本发明的主题是通式的氟代官能笼型倍半硅氧烷的合成方法，其中R1表示HCF2（CF2）n（CH2）mO（CH2）3Si（CH3）2O或HCF2（CF2）n（CH2） mO（CH 2）3基，其中n = 1-12，m = 1-4;•R 2，R 3，R 4，R 5，R 6，R 7，R 8可以与R 1相同或不同， （C 1 -C 25）烷基或任何芳基，基于氟烷基 - 烯丙基醚与合适的氢倍半硅氧烷在硅化铑络合物[{Rh（OSiMe 3）（cod）} 2]的存在下作为催化剂的氢化硅烷化。

    Synthesis of fluorosilicones and their derivatives
    4.
    发明授权
    Synthesis of fluorosilicones and their derivatives 有权
    氟硅氧烷及其衍生物的合成

    公开(公告)号：US08841473B2

    公开(公告)日：2014-09-23

    申请号：US13393389

    申请日：2010-08-16

    申请人： Bogdan Marciniec ,  Hieronim Maciejewski ,  Izabela Dabek ,  Joanna Karasiewicz

    发明人： Bogdan Marciniec ,  Hieronim Maciejewski ,  Izabela Dabek ,  Joanna Karasiewicz

    IPC分类号： C07F7/12 ,  C08G77/385 ,  C08G77/04 ,  C07F7/08 ,  C08G77/14 ,  C08G77/12

    CPC分类号： C08G77/385 ,  C07F7/0879 ,  C08G77/045 ,  C08G77/12 ,  C08G77/14 ,  Y02P20/582

    摘要： The subject of invention is the method of synthesis of fluorosilicone co-polymers of arbitrary topology and general formula 1 in which among others if A stands for CH—O(CH2)m(CF2)nCF2H group, then the method is based on hydrosilylation reaction of appropriate fluoroalkyl-allyl ether with polyhydrosiloxanes containing at least one Si—H group, catalyzed by siloxide rhodium complex. If A stands for in which Z stands for divalent group either then the method is based on the reaction of nucleophilic opening of oxirane ring in appropriate epoxyfunctional co-polysiloxanes, in acidic environment.

    摘要翻译： 本发明的主题是合成任意拓扑结构和通式1的氟硅氧烷共聚物的方法，其中如果A代表CH-O（CH 2）m（CF 2）n CF 2 H基团，则该方法基于氢化硅烷化反应 的合适的氟烷基 - 烯丙基醚与含有至少一个Si-H基团的聚氢硅氧烷，由硅化铑络合物催化。 如果A代表其中Z代表二价基团，则该方法基于在酸性环境中环氧乙烷环在适当的环氧官能共聚硅氧烷中的亲核性开环的反应。

    SYNTHESIS OF FLUOROSILICONES AND THEIR DERIVATIVES
    5.
    发明申请
    SYNTHESIS OF FLUOROSILICONES AND THEIR DERIVATIVES 有权
    氟化物及其衍生物的合成

    公开(公告)号：US20120157703A1

    公开(公告)日：2012-06-21

    申请号：US13393389

    申请日：2010-08-16

    申请人： Bogdan Marciniec ,  Hieronim Maciejewski ,  Izabela Dabek ,  Joanna Karasiewicz

    发明人： Bogdan Marciniec ,  Hieronim Maciejewski ,  Izabela Dabek ,  Joanna Karasiewicz

    IPC分类号： C07F7/12

    CPC分类号： C08G77/385 ,  C07F7/0879 ,  C08G77/045 ,  C08G77/12 ,  C08G77/14 ,  Y02P20/582

    摘要： The subject of invention is the method of synthesis of fluorosilicone co-polymers of arbitrary topology and general formula 1 in which among others if A stands for CH—O(CH2)m(CF2)nCF2H group, then the method is based on hydrosilylation reaction of appropriate fluoroalkyl-allyl ether with polyhydrosiloxanes containing at least one Si—H group, catalyzed by siloxide rhodium complex. If A stands for in which Z stands for divalent group either then the method is based on the reaction of nucleophilic opening of oxirane ring in appropriate epoxyfunctional co-polysiloxanes, in acidic environment.

    摘要翻译： 本发明的主题是合成任意拓扑结构和通式1的氟硅氧烷共聚物的方法，其中如果A代表CH-O（CH 2）m（CF 2）n CF 2 H基团，则该方法基于氢化硅烷化反应 的合适的氟烷基 - 烯丙基醚与含有至少一个Si-H基团的聚氢硅氧烷，由硅化铑络合物催化。 如果A代表其中Z代表二价基团，则该方法基于在酸性环境中环氧乙烷环在适当的环氧官能共聚硅氧烷中的亲核性开环的反应。

    Heterogenized rhodium complexes, methods of their synthesis and application as hydrosilylation catalysts
    6.
    发明授权
    Heterogenized rhodium complexes, methods of their synthesis and application as hydrosilylation catalysts 有权
    杂化铑配合物，其合成方法和作为氢化硅烷化催化剂的应用

    公开(公告)号：US08049024B2

    公开(公告)日：2011-11-01

    申请号：US12310967

    申请日：2007-09-12

    申请人： Bogdan Marciniec ,  Ryszard Fiedorow ,  Karol Szubert ,  Ireneusz Kownacki ,  Adrian Franczyk ,  Michal Dutkiewicz ,  Kinga Leszczak

    发明人： Bogdan Marciniec ,  Ryszard Fiedorow ,  Karol Szubert ,  Ireneusz Kownacki ,  Adrian Franczyk ,  Michal Dutkiewicz ,  Kinga Leszczak

    IPC分类号： C07F7/08

    CPC分类号： B01J31/1633 ,  B01J31/2295 ,  B01J31/24 ,  B01J2231/323 ,  B01J2531/822 ,  C08G77/38

    摘要： The subjects of the invention are new heterogenized rhodium complexes, the methods of their synthesis and their application as catalysts for synthesis of organosilicon compounds by hydrosilylation. The subject of the invention are new siloxide rhodium(I) complexes immobilised on the silica surface, of the general formula 1. [(≡SiO)(L)Rh(diene)] The second subject of the invention is the method of synthesis of the new rhodium complexes of the general formula 1. The third subject of the invention is the method of obtaining the organosilicon compounds in the reaction of hydrosilylation between the selected alkenes or functionalised alkenes containing the terminal C═C bond and the appropriate compounds containing the Si═H bond selected from silanes, (poly)siloxanes and (poly)carbosiloxanes, in the presence of heterogenized rhodium catalysts, of the general formula 1.

    摘要翻译： 本发明的主题是新的异质化铑络合物，其合成方法及其作为通过氢化硅烷化合成有机硅化合物的催化剂的应用。 本发明的主题是通式1固定在二氧化硅表面上的新的硅氧烷铑（I）络合物。[（≡SiO）（L）Rh（二烯）]本发明的第二个主题是合成 本发明的第三个主题是在所选择的烯烃或含末端C = C键的官能化烯烃和含有Si的适当化合物之间的氢化硅烷化反应中获得有机硅化合物的方法 在通式1的异构铑催化剂的存在下，选自硅烷，（聚）硅氧烷和（聚）碳硅氧烷的≡H键。

    New Heterogenized Rhodium Complexes, Methods of their Synthesis and Application as Hydrosilylation Catalysts
    7.
    发明申请
    New Heterogenized Rhodium Complexes, Methods of their Synthesis and Application as Hydrosilylation Catalysts 有权
    新型异质化铑络合物，其合成方法和作为氢化硅烷化催化剂的应用

    公开(公告)号：US20100048932A1

    公开(公告)日：2010-02-25

    申请号：US12310967

    申请日：2007-09-12

    申请人： Bogdan Marciniec ,  Ryszard Fiedorow ,  Karol Szubert ,  Ireneusz Kownacki ,  Adrian Franczyk ,  Michal Dutkiewicz ,  Kinga Leszczak

    发明人： Bogdan Marciniec ,  Ryszard Fiedorow ,  Karol Szubert ,  Ireneusz Kownacki ,  Adrian Franczyk ,  Michal Dutkiewicz ,  Kinga Leszczak

    IPC分类号： C07F7/08

    CPC分类号： B01J31/1633 ,  B01J31/2295 ,  B01J31/24 ,  B01J2231/323 ,  B01J2531/822 ,  C08G77/38

    摘要： The subjects of the invention are new heterogenized rhodium complexes, the methods of their synthesis and their application as catalysts for synthesis of organosilicon compounds by hydrosilylation. The subject of the invention are new siloxide rhodium(I) complexes immobilised on the silica surface, of the general formula 1. [(≡SiO)(L)Rh(diene)] The second subject of the invention is the method of synthesis of the new rhodium complexes of the general formula 1. The third subject of the invention is the method of obtaining the organosilicon compounds in the reaction of hydrosilylation between the selected alkenes or functionalised alkenes containing the terminal C═C bond and the appropriate compounds containing the Si═H bond selected from silanes, (poly)siloxanes and (poly)carbosiloxanes, in the presence of heterogenized rhodium catalysts, of the general formula 1.

    摘要翻译： 本发明的主题是新的异质化铑络合物，其合成方法及其作为通过氢化硅烷化合成有机硅化合物的催化剂的应用。 本发明的主题是通式1固定在二氧化硅表面上的新的硅氧烷铑（I）络合物。[（≡SiO）（L）Rh（二烯）]本发明的第二个主题是合成 本发明的第三个主题是在所选择的烯烃或含末端C = C键的官能化烯烃和含有Si的适当化合物之间的氢化硅烷化反应中获得有机硅化合物的方法 在通式1的异构铑催化剂的存在下，选自硅烷，（聚）硅氧烷和（聚）碳硅氧烷的≡H键。

    Functionalized MQ resin as an adhesion enhancing additive
    8.
    发明授权
    Functionalized MQ resin as an adhesion enhancing additive 有权
    功能化的MQ树脂作为增粘添加剂

    公开(公告)号：US06262188B1

    公开(公告)日：2001-07-17

    申请号：US09454935

    申请日：1999-12-03

    申请人： Frank S. Burkus, II ,  Slawomir Rubinsztajn ,  Jacek Gulinski ,  Bogdan Marciniec

    发明人： Frank S. Burkus, II ,  Slawomir Rubinsztajn ,  Jacek Gulinski ,  Bogdan Marciniec

    IPC分类号： C08L8305

    CPC分类号： C08G77/50 ,  C08G77/12 ,  C08G77/14 ,  C08L83/00 ,  C09J183/04

    摘要： Compositions, comprising functionalized resins having the formula MxHMyRQ  (I) wherein x+y is in the range from 0.5 to 4 and the ratio x:y is in the range from 1:10 to 10:1; Q is SiO{fraction (4/2)} MH is R1R2HSiO½ MR is R1R2RSiO½ wherein each R1 and R2 is independently an alkyl, fluoroalkyl, or aryl group having from 1 to about 18 carbons, and R can be the same or different and is selected from the group consisting of the formulas (II), (III) and (IV): —CH2BOC(O)Ar  (II) wherein Ar is a phenyl or substituted phenyl group, B is a branched or straight-chain alkylene group having from 1 to 12 carbon atoms; —CH2CH2Ep  (III) wherein Ep is an organic radical containing an epoxy functional; and —A1—C(O)O—A2—Si(OR1)3  (IV) wherein A1 a branched or straight-chain alkylene group having from 2 to 12 carbon atoms, A2 is a branched or straight-chain alkylene group having from 1 to 16 carbon atoms and R1 is as previously defined.

    摘要翻译： 包含具有式（Ⅳ）的官能化树脂的组合物的x + y为0.5至4，x:y的比例为1:10至10:1;其中每个R 1和R 2独立地为烷基，氟代烷基， 或具有1至约18个碳的芳基，R可以相同或不同，并且选自式（II），（III）和（IV）：其中Ar是苯基或取代的苯基 B是具有1至12个碳原子的支链或直链亚烷基;其中Ep是含有环氧官能团的有机基团; 并且其中A1为具有2至12个碳原子的支链或直链亚烷基，A2为具有1至16个碳原子的支链或直链亚烷基，R 1如前所定义。

    (E)-styryl-alkynylsubstituted silicon compounds and method of obtaining (E)-styryl-alkynylsubstituted silicon compounds
    9.
    发明授权
    (E)-styryl-alkynylsubstituted silicon compounds and method of obtaining (E)-styryl-alkynylsubstituted silicon compounds 有权
    （E） - 苯乙烯基 - 炔基取代的硅化合物和获得（E） - 苯乙烯基 - 炔基取代的硅化合物的方法

    公开(公告)号：US08680310B2

    公开(公告)日：2014-03-25

    申请号：US13395196

    申请日：2010-08-20

    申请人： Bogdan Marciniec ,  Beata Dudziec ,  Monika Rzonsowska

    发明人： Bogdan Marciniec ,  Beata Dudziec ,  Monika Rzonsowska

    IPC分类号： C07F7/02 ,  C07F7/04

    CPC分类号： C07F7/10 ,  C07F7/0838 ,  C07F7/1804 ,  C07F7/30

    摘要： New (E)-styryl-alkynylsubstituted silicon compounds having the generalized formula 1 and A new method of obtaining (E)-styryl-alkynylsubstituted silicon compounds having the generalized formula 1. A denotes: phenylmethylsilyl, 1,4-bis(dimethylsilyl)benzene, 1,2-bis(dimethylsilyl)ethane, 1,1,3,3-tetramethyldisilazane, 1,1,3,3-tetramethyldisiloxane, R′ denotes: tri(isopropyl)silyl, 1-pentyl, 2-(trimethylsiloxy)-2-butyl, 1-(trimethylsiloxy)-1-cyclohexyl, triethylgermyl, R′ denotes: H or Cl and when A denotes phenylmethylsilyl then R″ denotes also methyl or a methoxy group. A method of obtaining (E)-styrylalkynylsubstituted silicon compounds having the generalized formula 1 where A, R′ and R″ denote the same as stated above by way of a silylative coupling reaction between a suitable substituted styrene and a suitable vinyl-alkynylsubstituted silicon compound in the presence of a ruthenium(II) complex as catalyst.

    摘要翻译： 具有通式1的新的（E） - 苯乙烯基 - 炔基取代的硅化合物和获得具有通式1的（E） - 苯乙烯基 - 炔基取代的硅化合物的新方法.A表示：苯基甲基甲硅烷基，1,4-双（二甲基甲硅烷基）苯 ，1,2-双（二甲基甲硅烷基）乙烷，1,1,3,3-四甲基二硅氮烷，1,1,3,3-四甲基二硅氧烷，R'表示三（异丙基）甲硅烷基，1-戊基，2-（三甲基甲硅烷氧基） 2-丁基，1-（三甲基甲硅烷氧基）-1-环己基，三乙基锗烷基，R'表示：H或Cl，当A表示苯基甲基甲硅烷基时，R“也表示甲基或甲氧基。 一种获得具有通式1的（E） - 苯乙烯基炔基取代的硅化合物的方法，其中A，R'和R“表示与上述相同，通过合适的取代的苯乙烯和合适的乙烯基 - 炔基取代的硅化合物之间的甲硅烷基偶联反应 在作为催化剂的钌（II）络合物的存在下。