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公开(公告)号:US07674539B2
公开(公告)日:2010-03-09
申请号:US11403407
申请日:2006-04-12
CPC分类号: B01D53/06 , B01D53/047 , B01D53/261 , B01D2253/102 , B01D2253/108 , B01D2256/16 , B01D2257/502 , B01D2257/80 , B01D2258/0208 , B01D2259/40001 , B01D2259/40005 , B01D2259/402 , B01D2259/4541 , C01B3/38 , C01B3/386 , C01B3/56 , C01B2203/00 , C01B2203/0233 , C01B2203/025 , C01B2203/0283 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0883 , C01B2203/1076 , C01B2203/1211 , C01B2203/1223 , C01B2203/1229 , C01B2203/1241 , C01B2203/1288 , C01B2203/146 , C01B2203/147 , C01B2203/82 , H01M8/04022 , H01M8/04029 , H01M8/04156 , H01M8/0612 , H01M8/0662 , Y02C10/08 , Y02P20/128 , Y02P20/129 , Y02P20/52
摘要: A process and system for providing a hydrogen-containing gas stream to a fuel cell anode that includes providing a hydrogen-containing gas stream that includes carbon monoxide, introducing the hydrogen-containing gas stream into a pressure swing adsorption module that includes at least one carbon monoxide-selective adsorbent to produce a purified hydrogen-containing gas stream, and introducing the purified hydrogen-containing gas stream to the fuel cell anode. The pressure swing adsorption module can also include a second adsorbent and/or catalyst. Also disclosed is a fuel cell system coupled to an internal combustion engine and a fuel cell system that utilizes fuel cell waste heat for vaporizing a hydrocarbon/water mixture.
摘要翻译: 一种用于向燃料电池阳极提供含氢气体流的方法和系统,其包括提供包含一氧化碳的含氢气体流,将含氢气流引入变压吸附模块,所述变压吸附模块包括至少一个碳 一氧化碳选择性吸附剂以产生纯化的含氢气流,并将纯化的含氢气体流引入燃料电池阳极。 变压吸附模块还可以包括第二吸附剂和/或催化剂。 还公开了一种联接到内燃机和燃料电池系统的燃料电池系统,其利用燃料电池废热来蒸发烃/水混合物。
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公开(公告)号:US07041272B2
公开(公告)日:2006-05-09
申请号:US10039552
申请日:2001-10-26
CPC分类号: B01D53/06 , B01D53/047 , B01D53/261 , B01D2253/102 , B01D2253/108 , B01D2256/16 , B01D2257/502 , B01D2257/80 , B01D2258/0208 , B01D2259/40001 , B01D2259/40005 , B01D2259/402 , B01D2259/4541 , C01B3/38 , C01B3/386 , C01B3/56 , C01B2203/00 , C01B2203/0233 , C01B2203/025 , C01B2203/0283 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0883 , C01B2203/1076 , C01B2203/1211 , C01B2203/1223 , C01B2203/1229 , C01B2203/1241 , C01B2203/1288 , C01B2203/146 , C01B2203/147 , C01B2203/82 , H01M8/04022 , H01M8/04029 , H01M8/04156 , H01M8/0612 , H01M8/0662 , Y02C10/08 , Y02P20/128 , Y02P20/129 , Y02P20/52
摘要: A process and system for providing a hydrogen-containing gas stream to a fuel cell anode that includes providing a hydrogen-containing gas stream that includes carbon monoxide, introducing the hydrogen-containing gas stream into a pressure swing adsorption module that includes at least one carbon monoxide-selective adsorbent to produce a purified hydrogen-containing gas stream, and introducing the purified hydrogen-containing gas stream to the fuel cell anode. The pressure swing adsorption module can also include a second adsorbent and/or catalyst. Also disclosed is a fuel cell system coupled to an internal combustion engine and a fuel cell system that utilizes fuel cell waste heat for vaporizing a hydrocarbon/water mixture.
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公开(公告)号:US07645324B2
公开(公告)日:2010-01-12
申请号:US11326657
申请日:2006-01-06
申请人: Edward J. Rode , Andre J. J. Boulet , Aaron M. Pelman , Matthew L. Babicki , Bowie G. Keefer , James A. Sawada , Soheil Alizadeh-Khiavi , Surajit Roy , Andrea C. Gibbs , Steven M. Kuznicki
发明人: Edward J. Rode , Andre J. J. Boulet , Aaron M. Pelman , Matthew L. Babicki , Bowie G. Keefer , James A. Sawada , Soheil Alizadeh-Khiavi , Surajit Roy , Andrea C. Gibbs , Steven M. Kuznicki
IPC分类号: B01D53/02
CPC分类号: B01D53/02 , B01D53/0462 , B01D53/047 , B01D53/0473 , B01D2253/10 , B01D2253/108 , B01D2253/25 , B01D2253/304 , B01D2253/311 , B01D2256/10 , B01D2256/24 , B01D2257/504 , B01D2257/7022 , B01D2257/7025 , B01D2259/40005 , B01D2259/40007 , B01D2259/4148 , B01D2259/4575 , B01J20/28052 , Y02C10/08 , Y02C20/20
摘要: Improved adsorbent sheet based parallel passage adsorbent structures for enhancing the kinetic selectivity of certain kinetic-controlled adsorption processes, such as PSA, TSA and PPSA processes, and combinations thereof, are provided. The enhancements in kinetic selectivity made possible through the implementation of the present inventive improved adsorbent structures may unexpectedly enable significant intensification of selected kinetic adsorption processes relative to attainable performance with conventional adsorbent materials in beaded or extruded form. Such process intensification enabled by the present inventive adsorbent structures may provide for increased adsorption cycle frequencies, and increased gas flow velocities within the adsorbent beds, which may increase the productivity and/or recovery of a kinetic adsorption system incorporating the inventive adsorbent structures.
摘要翻译: 提供了改进的吸附片基平行通道吸附结构,用于增强某些动力学控制吸附过程(如PSA,TSA和PPSA方法)的动力学选择性及其组合。 通过实施本发明改进的吸附剂结构使得动力学选择性的增强可能出乎意料地能够使用常规的串联或挤出形式的吸附剂材料相对于可获得的性能而显着增强选定的动力学吸附过程。 通过本发明的吸附剂结构实现的这种过程强化可以提供增加的吸附循环频率和增加的吸附剂床内的气体流速,这可以增加并入本发明的吸附剂结构的动力学吸附系统的生产率和/或回收率。
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公开(公告)号:US06902602B2
公开(公告)日:2005-06-07
申请号:US10389539
申请日:2003-03-14
申请人: Bowie G. Keefer , Matthew L. Babicki , Andre Jason Joseph Boulet , Aaron M. Pelman , Brian G. Sellars , Surajit Roy
发明人: Bowie G. Keefer , Matthew L. Babicki , Andre Jason Joseph Boulet , Aaron M. Pelman , Brian G. Sellars , Surajit Roy
IPC分类号: B01D53/04 , B01D53/047 , B01D53/06 , H01M8/06
CPC分类号: B01D53/06 , B01D53/0431 , B01D53/0462 , B01D53/047 , B01D2256/16 , B01D2257/504 , B01D2259/40043 , B01D2259/40056 , Y02C10/08
摘要: The present disclosure relates to systems and processes for adsorptive gas separations where a first gas mixture including components A and B is to be separated so that a first product of the separation is enriched in component A, while component B is mixed with a third gas component C contained in a displacement purge stream to form a second gas mixture including components B and C, and with provision to prevent cross contamination of component C into the first product containing component A, or of component A into the second gas mixture containing component C. The invention may be applied to hydrogen (component A) enrichment from syngas mixtures, where dilute carbon dioxide (component B) is to be rejected such as directly to the atmosphere, and with preferably nitrogen-enriched air as the displacement purge stream containing residual oxygen (component C).
摘要翻译: 本公开涉及吸附气体分离的系统和方法,其中包括组分A和B的第一气体混合物将被分离,使得分离的第一产物富含组分A,而组分B与第三气体组分 C包含在位移吹扫流中以形成包含组分B和C的第二气体混合物,并且用于防止组分C交叉污染第一产物含有组分A或组分A进入含有组分C的第二气体混合物中。 本发明可以应用于来自合成气混合物的氢(组分A)富集,其中将稀释的二氧化碳(组分B)直接排到大气中,并且优选富氮空气作为含有残余氧的置换吹扫流 (组分C)。
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公开(公告)号:US06565635B2
公开(公告)日:2003-05-20
申请号:US09963236
申请日:2001-09-25
申请人: Bowie G. Keefer , Matthew Babicki , Brian Sellars , Ian Spencer Parker , David G. Doman , Alain Carel , Surajit Roy
发明人: Bowie G. Keefer , Matthew Babicki , Brian Sellars , Ian Spencer Parker , David G. Doman , Alain Carel , Surajit Roy
IPC分类号: B01D5306
CPC分类号: C01B3/56 , B01D53/0431 , B01D53/047 , B01D53/0476 , B01D53/053 , B01D53/06 , B01D53/261 , B01D2253/108 , B01D2256/10 , B01D2256/12 , B01D2256/16 , B01D2257/102 , B01D2257/80 , B01D2259/40005 , B01D2259/40015 , B01D2259/40022 , B01D2259/40024 , B01D2259/4003 , B01D2259/40032 , B01D2259/40033 , B01D2259/40037 , B01D2259/40052 , B01D2259/40062 , B01D2259/40067 , B01D2259/40069 , B01D2259/40073 , B01D2259/40081 , B01D2259/402 , B01D2259/403 , B01D2259/4062 , B01D2259/4068 , B01D2259/4145 , C01B13/0259 , C01B21/045 , C01B2203/043 , C01B2210/0046
摘要: Disclosed embodiments of the apparatus address the challenges of rotary PSA systems, both axial and radial flow, with M>1 by providing interpenetrating, layered manifolds to accommodate all of the steps of a complex PSA cycle, suitable with equal compactness for any value of “M”. This approach extends readily to accommodate a plurality of rotary PSA modules and their cooperating compression machinery within a single layered manifold assembly for a single PSA plant train. Described embodiments of the rotary PSA apparatus include stators that define fluid ports. In particular embodiments of the described apparatus, a second stator defines pressure swing adsorption cycle sectors, each sector being defined by a light product delivery port, light product withdrawal ports, and light reflux return ports. The adsorber elements may directly contact one or more of the stators in a fluidly sealing manner (i.e., have a clearance gap of from about 0 to about 50 microns) using described reinforced adsorbers. The method comprises providing an embodiment of the described apparatus and then supplying at least one feed fluid to pressurize an adsorber element of the adsorber sets to substantially a higher pressure to initiate a pressure swing adsorption cycle.
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公开(公告)号:US08015808B2
公开(公告)日:2011-09-13
申请号:US11506562
申请日:2006-08-17
IPC分类号: F01B29/10
CPC分类号: F02B43/10 , F02G1/043 , F17C11/005 , H01M8/04007 , H01M8/04089 , H01M8/04119 , H01M8/0662 , Y02T10/16 , Y02T10/166 , Y02T10/32
摘要: Power plant systems and processes are described that enable recovery of at least a portion of the fuel storage energy associated with a storage system for supplying fuel to the power plant systems. A first embodiment of an energy-recovery power plant system includes at least one fuel storage container and at least one expander that can receive fuel from the fuel storage container at a first pressure and provide the fuel to the power plant at a second pressure that is lower than the first pressure. A second embodiment of an energy-recovery power plant system includes a first conduit fluidly coupling the fuel storage container and the power plant for delivering fuel from the fuel storage container to the power plant and at least one regenerative thermodynamic cycle engine thermally coupled to the first conduit such that heat may be exchanged between the fuel and a working fluid for the regenerative thermodynamic cycle engine.
摘要翻译: 描述了能够恢复与用于向发电厂系统供应燃料的存储系统相关联的燃料储存能量的至少一部分的发电厂系统和过程。 能量回收发电厂系统的第一实施例包括至少一个燃料储存容器和至少一个膨胀器,其能够在第一压力下从燃料储存容器接收燃料,并在第二压力下将燃料提供给发电厂 低于第一压力。 能量回收发电厂系统的第二实施例包括将燃料储存容器和发电厂流体耦合的第一导管,用于将燃料从燃料储存容器输送至发电厂,以及至少一个热耦合到第一 导管,使得可以在燃料和用于再生热力循环发动机的工作流体之间交换热量。
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公开(公告)号:US07189280B2
公开(公告)日:2007-03-13
申请号:US10881775
申请日:2004-06-29
IPC分类号: B01D53/04
CPC分类号: B01D53/0423 , B01D53/0446 , B01D2256/16 , B01D2256/24 , B01D2257/502 , B01D2259/40086 , B01D2259/4146 , Y02E50/346
摘要: A method and system for adsorptive separation of a feed gas mixture provides for increased system efficiency and product recovery. The requirement for purge gas streams consuming desired product gas to regenerate adsorption beds is reduced through an inventive method for adsorbent selection and adsorption bed and process design.
摘要翻译: 用于进料气体混合物的吸附分离的方法和系统提供了提高的系统效率和产物回收率。 通过用于吸附剂选择和吸附床和工艺设计的本发明方法,减少了消耗所需产物气体以再生吸附床的吹扫气流的需求。
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公开(公告)号:US07828877B2
公开(公告)日:2010-11-09
申请号:US11667041
申请日:2005-11-07
申请人: James A. Sawada , Matthew L. Babicki , Amy Chiu , Andre Boulet , Surajit Roy , Edward J. Rode
发明人: James A. Sawada , Matthew L. Babicki , Amy Chiu , Andre Boulet , Surajit Roy , Edward J. Rode
IPC分类号: B01D53/02
摘要: An inventive adsorptive gas separation process is provided capable of producing a purified methane product gas as a light non-adsorbed product gas as opposed to a heavy desorbed exhaust gas component, from a feed gas mixture comprising at least methane, and carbon dioxide. In an embodiment of the invention, the feed gas mixture may comprise at least about 10% carbon dioxide, and the purified methane product gas may be desirably purified to contain less than about 5000 ppm carbon dioxide. In another embodiment of the invention, the feed gas mixture may comprise at least about 50% carbon dioxide, and the purified methane product gas may be desirably purified to contain less than about 5000 ppm carbon dioxide.
摘要翻译: 提供了本发明的吸附气体分离方法,其能够从至少包含甲烷的进料气体混合物和二氧化碳中产生作为轻质非吸附产物气体的纯化的甲烷产物气体,而不是重质解吸的废气组分。 在本发明的一个实施方案中,进料气体混合物可以包含至少约10%的二氧化碳,并且纯化的甲烷产物气体可以期望地被纯化以含有小于约5000ppm的二氧化碳。 在本发明的另一个实施方案中,进料气体混合物可以包含至少约50%的二氧化碳,并且纯化的甲烷产物气体可以期望地被纯化以含有小于约5000ppm的二氧化碳。
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公开(公告)号:US20050284291A1
公开(公告)日:2005-12-29
申请号:US10881775
申请日:2004-06-29
CPC分类号: B01D53/0423 , B01D53/0446 , B01D2256/16 , B01D2256/24 , B01D2257/502 , B01D2259/40086 , B01D2259/4146 , Y02E50/346
摘要: A method and system for adsorptive separation of a feed gas mixture provides for increased system efficiency and product recovery. The requirement for purge gas streams consuming desired product gas to regenerate adsorption beds is reduced through an inventive method for adsorbent selection and adsorption bed and process design.
摘要翻译: 用于进料气体混合物的吸附分离的方法和系统提供了提高的系统效率和产物回收率。 通过用于吸附剂选择和吸附床和工艺设计的本发明方法,减少了消耗所需产物气体以再生吸附床的吹扫气流的需求。
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公开(公告)号:US20070261551A1
公开(公告)日:2007-11-15
申请号:US11667041
申请日:2005-11-07
申请人: James Sawada , Matthew Babicki , Amy Chiu , Andre Boulet , Surajit Roy , Edward Rode
发明人: James Sawada , Matthew Babicki , Amy Chiu , Andre Boulet , Surajit Roy , Edward Rode
IPC分类号: B01D53/02
摘要: An inventive adsorptive gas separation process is provided capable of producing a purified methane product gas as a light non-adsorbed product gas as opposed to a heavy desorbed exhaust gas component, from a feed gas mixture comprising at least methane, and carbon dioxide. In an embodiment of the invention, the feed gas mixture may comprise at least about 10% carbon dioxide, and the purified methane product gas may be desirably purified to contain less than about 5000 ppm carbon dioxide. In another embodiment of the invention, the feed gas mixture may comprise at least about 50% carbon dioxide, and the purified methane product gas may be desirably purified to contain less than about 5000 ppm carbon dioxide.
摘要翻译: 提供了本发明的吸附气体分离方法,其能够从至少包含甲烷的进料气体混合物和二氧化碳中产生作为轻质非吸附产物气体的纯化的甲烷产物气体,而不是重质解吸的废气组分。 在本发明的一个实施方案中,进料气体混合物可以包含至少约10%的二氧化碳,并且纯化的甲烷产物气体可以期望地被纯化以含有小于约5000ppm的二氧化碳。 在本发明的另一个实施方案中,进料气体混合物可以包含至少约50%的二氧化碳,并且纯化的甲烷产物气体可以期望地被纯化以含有小于约5000ppm的二氧化碳。
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