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公开(公告)号:US07189280B2
公开(公告)日:2007-03-13
申请号:US10881775
申请日:2004-06-29
IPC分类号: B01D53/04
CPC分类号: B01D53/0423 , B01D53/0446 , B01D2256/16 , B01D2256/24 , B01D2257/502 , B01D2259/40086 , B01D2259/4146 , Y02E50/346
摘要: A method and system for adsorptive separation of a feed gas mixture provides for increased system efficiency and product recovery. The requirement for purge gas streams consuming desired product gas to regenerate adsorption beds is reduced through an inventive method for adsorbent selection and adsorption bed and process design.
摘要翻译: 用于进料气体混合物的吸附分离的方法和系统提供了提高的系统效率和产物回收率。 通过用于吸附剂选择和吸附床和工艺设计的本发明方法,减少了消耗所需产物气体以再生吸附床的吹扫气流的需求。
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公开(公告)号:US07645324B2
公开(公告)日:2010-01-12
申请号:US11326657
申请日:2006-01-06
申请人: Edward J. Rode , Andre J. J. Boulet , Aaron M. Pelman , Matthew L. Babicki , Bowie G. Keefer , James A. Sawada , Soheil Alizadeh-Khiavi , Surajit Roy , Andrea C. Gibbs , Steven M. Kuznicki
发明人: Edward J. Rode , Andre J. J. Boulet , Aaron M. Pelman , Matthew L. Babicki , Bowie G. Keefer , James A. Sawada , Soheil Alizadeh-Khiavi , Surajit Roy , Andrea C. Gibbs , Steven M. Kuznicki
IPC分类号: B01D53/02
CPC分类号: B01D53/02 , B01D53/0462 , B01D53/047 , B01D53/0473 , B01D2253/10 , B01D2253/108 , B01D2253/25 , B01D2253/304 , B01D2253/311 , B01D2256/10 , B01D2256/24 , B01D2257/504 , B01D2257/7022 , B01D2257/7025 , B01D2259/40005 , B01D2259/40007 , B01D2259/4148 , B01D2259/4575 , B01J20/28052 , Y02C10/08 , Y02C20/20
摘要: Improved adsorbent sheet based parallel passage adsorbent structures for enhancing the kinetic selectivity of certain kinetic-controlled adsorption processes, such as PSA, TSA and PPSA processes, and combinations thereof, are provided. The enhancements in kinetic selectivity made possible through the implementation of the present inventive improved adsorbent structures may unexpectedly enable significant intensification of selected kinetic adsorption processes relative to attainable performance with conventional adsorbent materials in beaded or extruded form. Such process intensification enabled by the present inventive adsorbent structures may provide for increased adsorption cycle frequencies, and increased gas flow velocities within the adsorbent beds, which may increase the productivity and/or recovery of a kinetic adsorption system incorporating the inventive adsorbent structures.
摘要翻译: 提供了改进的吸附片基平行通道吸附结构,用于增强某些动力学控制吸附过程(如PSA,TSA和PPSA方法)的动力学选择性及其组合。 通过实施本发明改进的吸附剂结构使得动力学选择性的增强可能出乎意料地能够使用常规的串联或挤出形式的吸附剂材料相对于可获得的性能而显着增强选定的动力学吸附过程。 通过本发明的吸附剂结构实现的这种过程强化可以提供增加的吸附循环频率和增加的吸附剂床内的气体流速,这可以增加并入本发明的吸附剂结构的动力学吸附系统的生产率和/或回收率。
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公开(公告)号:US20050284291A1
公开(公告)日:2005-12-29
申请号:US10881775
申请日:2004-06-29
CPC分类号: B01D53/0423 , B01D53/0446 , B01D2256/16 , B01D2256/24 , B01D2257/502 , B01D2259/40086 , B01D2259/4146 , Y02E50/346
摘要: A method and system for adsorptive separation of a feed gas mixture provides for increased system efficiency and product recovery. The requirement for purge gas streams consuming desired product gas to regenerate adsorption beds is reduced through an inventive method for adsorbent selection and adsorption bed and process design.
摘要翻译: 用于进料气体混合物的吸附分离的方法和系统提供了提高的系统效率和产物回收率。 通过用于吸附剂选择和吸附床和工艺设计的本发明方法,减少了消耗所需产物气体以再生吸附床的吹扫气流的需求。
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公开(公告)号:US20050129952A1
公开(公告)日:2005-06-16
申请号:US10954251
申请日:2004-09-29
CPC分类号: B01J20/28035 , B01D53/02 , B01D53/0462 , B01D53/047 , B01D2253/102 , B01D2253/11 , B01D2253/25 , B01D2253/3425 , B01J20/18 , B01J20/20 , B01J20/28011 , B01J20/28033 , Y10T428/31
摘要: High density adsorbent structures may be constructed in parallel passage contactor configurations using improved high density adsorbent sheets. Improved high density adsorbent sheets may be formed using adsorptively active support or substrate materials upon which adsorbent material is applied, such as by coating processes, so that in the resulting high density adsorbent structure both the substrate and the coated adsorbent material are active in adsorption processes. Alternatively, improved high density adsorbent sheets may be formed comprising precursor materials, such as certain clays, which may be coated onto known support materials and thereafter converted to active adsorbent materials using known conversion techniques. This produces high-density adsorbent sheets comprising adsorbent material without inert binder material fractions. Improved self-supporting adsorbent sheets also may be formed without using support material, resulting in higher adsorbent densities relative to known adsorbent sheets.
摘要翻译: 高密度吸附剂结构可以使用改进的高密度吸附片材在平行通道接触器构造中构造。 改进的高密度吸附片材可以使用吸附性活性载体或其上施加吸附剂材料的基底材料,例如通过涂布方法形成,使得在所得到的高密度吸附剂结构中,基底和涂覆的吸附剂材料在吸附过程中是有活性的 。 或者,可以形成改进的高密度吸附片,其包含前体材料,例如某些粘土,其可涂覆在已知的载体材料上,然后使用已知的转化技术转化为活性吸附剂材料。 这产生了高密度吸附片材,其包括不含惰性粘合剂材料部分的吸附材料。 也可以在不使用载体材料的情况下形成改进的自支撑吸附片,导致相对于已知的吸附片材具有更高的吸附剂密度。
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公开(公告)号:US20060169142A1
公开(公告)日:2006-08-03
申请号:US11326657
申请日:2006-01-06
申请人: Edward Rode , Andre Boulet , Aaron Pelman , Matthew Babicki , Bowie Keefer , James Sawada , Soheil Alizadeh-Khiavi , Surajit Roy , Andrea Gibbs , Steven Kuznicki
发明人: Edward Rode , Andre Boulet , Aaron Pelman , Matthew Babicki , Bowie Keefer , James Sawada , Soheil Alizadeh-Khiavi , Surajit Roy , Andrea Gibbs , Steven Kuznicki
IPC分类号: B01D53/02
CPC分类号: B01D53/02 , B01D53/0462 , B01D53/047 , B01D53/0473 , B01D2253/10 , B01D2253/108 , B01D2253/25 , B01D2253/304 , B01D2253/311 , B01D2256/10 , B01D2256/24 , B01D2257/504 , B01D2257/7022 , B01D2257/7025 , B01D2259/40005 , B01D2259/40007 , B01D2259/4148 , B01D2259/4575 , B01J20/28052 , Y02C10/08 , Y02C20/20
摘要: Improved adsorbent sheet based parallel passage adsorbent structures for enhancing the kinetic selectivity of certain kinetic-controlled adsorption processes, such as PSA, TSA and PPSA processes, and combinations thereof, are provided. The enhancements in kinetic selectivity made possible through the implementation of the present inventive improved adsorbent structures may unexpectedly enable significant intensification of selected kinetic adsorption processes relative to attainable performance with conventional adsorbent materials in beaded or extruded form. Such process intensification enabled by the present inventive adsorbent structures may provide for increased adsorption cycle frequencies, and increased gas flow velocities within the adsorbent beds, which may increase the productivity and/or recovery of a kinetic adsorption system incorporating the inventive adsorbent structures.
摘要翻译: 提供了改进的吸附片基平行通道吸附结构,用于增强某些动力学控制吸附过程(如PSA,TSA和PPSA方法)的动力学选择性及其组合。 通过实施本发明改进的吸附剂结构使得动力学选择性的增强可能出乎意料地能够使用常规的串联或挤出形式的吸附剂材料相对于可获得的性能而显着增强选定的动力学吸附过程。 通过本发明的吸附剂结构实现的这种过程强化可以提供增加的吸附循环频率和增加的吸附剂床内的气体流速,这可以增加并入本发明的吸附剂结构的动力学吸附系统的生产率和/或回收率。
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公开(公告)号:US07041272B2
公开(公告)日:2006-05-09
申请号:US10039552
申请日:2001-10-26
CPC分类号: B01D53/06 , B01D53/047 , B01D53/261 , B01D2253/102 , B01D2253/108 , B01D2256/16 , B01D2257/502 , B01D2257/80 , B01D2258/0208 , B01D2259/40001 , B01D2259/40005 , B01D2259/402 , B01D2259/4541 , C01B3/38 , C01B3/386 , C01B3/56 , C01B2203/00 , C01B2203/0233 , C01B2203/025 , C01B2203/0283 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0883 , C01B2203/1076 , C01B2203/1211 , C01B2203/1223 , C01B2203/1229 , C01B2203/1241 , C01B2203/1288 , C01B2203/146 , C01B2203/147 , C01B2203/82 , H01M8/04022 , H01M8/04029 , H01M8/04156 , H01M8/0612 , H01M8/0662 , Y02C10/08 , Y02P20/128 , Y02P20/129 , Y02P20/52
摘要: A process and system for providing a hydrogen-containing gas stream to a fuel cell anode that includes providing a hydrogen-containing gas stream that includes carbon monoxide, introducing the hydrogen-containing gas stream into a pressure swing adsorption module that includes at least one carbon monoxide-selective adsorbent to produce a purified hydrogen-containing gas stream, and introducing the purified hydrogen-containing gas stream to the fuel cell anode. The pressure swing adsorption module can also include a second adsorbent and/or catalyst. Also disclosed is a fuel cell system coupled to an internal combustion engine and a fuel cell system that utilizes fuel cell waste heat for vaporizing a hydrocarbon/water mixture.
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公开(公告)号:US07828877B2
公开(公告)日:2010-11-09
申请号:US11667041
申请日:2005-11-07
申请人: James A. Sawada , Matthew L. Babicki , Amy Chiu , Andre Boulet , Surajit Roy , Edward J. Rode
发明人: James A. Sawada , Matthew L. Babicki , Amy Chiu , Andre Boulet , Surajit Roy , Edward J. Rode
IPC分类号: B01D53/02
摘要: An inventive adsorptive gas separation process is provided capable of producing a purified methane product gas as a light non-adsorbed product gas as opposed to a heavy desorbed exhaust gas component, from a feed gas mixture comprising at least methane, and carbon dioxide. In an embodiment of the invention, the feed gas mixture may comprise at least about 10% carbon dioxide, and the purified methane product gas may be desirably purified to contain less than about 5000 ppm carbon dioxide. In another embodiment of the invention, the feed gas mixture may comprise at least about 50% carbon dioxide, and the purified methane product gas may be desirably purified to contain less than about 5000 ppm carbon dioxide.
摘要翻译: 提供了本发明的吸附气体分离方法,其能够从至少包含甲烷的进料气体混合物和二氧化碳中产生作为轻质非吸附产物气体的纯化的甲烷产物气体,而不是重质解吸的废气组分。 在本发明的一个实施方案中,进料气体混合物可以包含至少约10%的二氧化碳,并且纯化的甲烷产物气体可以期望地被纯化以含有小于约5000ppm的二氧化碳。 在本发明的另一个实施方案中,进料气体混合物可以包含至少约50%的二氧化碳,并且纯化的甲烷产物气体可以期望地被纯化以含有小于约5000ppm的二氧化碳。
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公开(公告)号:US07674539B2
公开(公告)日:2010-03-09
申请号:US11403407
申请日:2006-04-12
CPC分类号: B01D53/06 , B01D53/047 , B01D53/261 , B01D2253/102 , B01D2253/108 , B01D2256/16 , B01D2257/502 , B01D2257/80 , B01D2258/0208 , B01D2259/40001 , B01D2259/40005 , B01D2259/402 , B01D2259/4541 , C01B3/38 , C01B3/386 , C01B3/56 , C01B2203/00 , C01B2203/0233 , C01B2203/025 , C01B2203/0283 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0883 , C01B2203/1076 , C01B2203/1211 , C01B2203/1223 , C01B2203/1229 , C01B2203/1241 , C01B2203/1288 , C01B2203/146 , C01B2203/147 , C01B2203/82 , H01M8/04022 , H01M8/04029 , H01M8/04156 , H01M8/0612 , H01M8/0662 , Y02C10/08 , Y02P20/128 , Y02P20/129 , Y02P20/52
摘要: A process and system for providing a hydrogen-containing gas stream to a fuel cell anode that includes providing a hydrogen-containing gas stream that includes carbon monoxide, introducing the hydrogen-containing gas stream into a pressure swing adsorption module that includes at least one carbon monoxide-selective adsorbent to produce a purified hydrogen-containing gas stream, and introducing the purified hydrogen-containing gas stream to the fuel cell anode. The pressure swing adsorption module can also include a second adsorbent and/or catalyst. Also disclosed is a fuel cell system coupled to an internal combustion engine and a fuel cell system that utilizes fuel cell waste heat for vaporizing a hydrocarbon/water mixture.
摘要翻译: 一种用于向燃料电池阳极提供含氢气体流的方法和系统,其包括提供包含一氧化碳的含氢气体流,将含氢气流引入变压吸附模块,所述变压吸附模块包括至少一个碳 一氧化碳选择性吸附剂以产生纯化的含氢气流,并将纯化的含氢气体流引入燃料电池阳极。 变压吸附模块还可以包括第二吸附剂和/或催化剂。 还公开了一种联接到内燃机和燃料电池系统的燃料电池系统,其利用燃料电池废热来蒸发烃/水混合物。
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9.
公开(公告)号:US06902602B2
公开(公告)日:2005-06-07
申请号:US10389539
申请日:2003-03-14
申请人: Bowie G. Keefer , Matthew L. Babicki , Andre Jason Joseph Boulet , Aaron M. Pelman , Brian G. Sellars , Surajit Roy
发明人: Bowie G. Keefer , Matthew L. Babicki , Andre Jason Joseph Boulet , Aaron M. Pelman , Brian G. Sellars , Surajit Roy
IPC分类号: B01D53/04 , B01D53/047 , B01D53/06 , H01M8/06
CPC分类号: B01D53/06 , B01D53/0431 , B01D53/0462 , B01D53/047 , B01D2256/16 , B01D2257/504 , B01D2259/40043 , B01D2259/40056 , Y02C10/08
摘要: The present disclosure relates to systems and processes for adsorptive gas separations where a first gas mixture including components A and B is to be separated so that a first product of the separation is enriched in component A, while component B is mixed with a third gas component C contained in a displacement purge stream to form a second gas mixture including components B and C, and with provision to prevent cross contamination of component C into the first product containing component A, or of component A into the second gas mixture containing component C. The invention may be applied to hydrogen (component A) enrichment from syngas mixtures, where dilute carbon dioxide (component B) is to be rejected such as directly to the atmosphere, and with preferably nitrogen-enriched air as the displacement purge stream containing residual oxygen (component C).
摘要翻译: 本公开涉及吸附气体分离的系统和方法,其中包括组分A和B的第一气体混合物将被分离,使得分离的第一产物富含组分A,而组分B与第三气体组分 C包含在位移吹扫流中以形成包含组分B和C的第二气体混合物,并且用于防止组分C交叉污染第一产物含有组分A或组分A进入含有组分C的第二气体混合物中。 本发明可以应用于来自合成气混合物的氢(组分A)富集,其中将稀释的二氧化碳(组分B)直接排到大气中,并且优选富氮空气作为含有残余氧的置换吹扫流 (组分C)。
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公开(公告)号:US20070261551A1
公开(公告)日:2007-11-15
申请号:US11667041
申请日:2005-11-07
申请人: James Sawada , Matthew Babicki , Amy Chiu , Andre Boulet , Surajit Roy , Edward Rode
发明人: James Sawada , Matthew Babicki , Amy Chiu , Andre Boulet , Surajit Roy , Edward Rode
IPC分类号: B01D53/02
摘要: An inventive adsorptive gas separation process is provided capable of producing a purified methane product gas as a light non-adsorbed product gas as opposed to a heavy desorbed exhaust gas component, from a feed gas mixture comprising at least methane, and carbon dioxide. In an embodiment of the invention, the feed gas mixture may comprise at least about 10% carbon dioxide, and the purified methane product gas may be desirably purified to contain less than about 5000 ppm carbon dioxide. In another embodiment of the invention, the feed gas mixture may comprise at least about 50% carbon dioxide, and the purified methane product gas may be desirably purified to contain less than about 5000 ppm carbon dioxide.
摘要翻译: 提供了本发明的吸附气体分离方法,其能够从至少包含甲烷的进料气体混合物和二氧化碳中产生作为轻质非吸附产物气体的纯化的甲烷产物气体,而不是重质解吸的废气组分。 在本发明的一个实施方案中,进料气体混合物可以包含至少约10%的二氧化碳,并且纯化的甲烷产物气体可以期望地被纯化以含有小于约5000ppm的二氧化碳。 在本发明的另一个实施方案中,进料气体混合物可以包含至少约50%的二氧化碳,并且纯化的甲烷产物气体可以期望地被纯化以含有小于约5000ppm的二氧化碳。
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